Changes in soils irrigated with saline groundwater containing excess bicarbonate
Changes in soil properties caused by irrigation with saline groundwater (approx. 2 dS/m) containing excess bicarbonate were measured on Vertosols and Sodosols in the West Wimmera, Victoria, Australia. Irrigation caused soil pH to increase, and where this had risen sufficiently (approx. 8.0), the sodium absorption ratio (SAR) of 1 : 5 soil extracts also increased, presumably due to precipitation of calcium and magnesium carbonates. Salt only accumulated when the SAR of 1 : 5 soil extracts was high. In contrast to previous studies, SAR of the soil extracts was not correlated with exchangeable sodium percentage (ESP) of the exchange complex, nor with soil pH. SAR values rose with irrigation once pH exceeded 8, suggesting that carbonate formation was incomplete due to insufficient bicarbonate. The results imply that gypsum application may ameliorate soil properties even if amounts applied are not sufficient to alter ESP.