Laser Assisted Collisions of Electrons with Metal Vapours

Three separate experiments are described which use laser radiation to probe the details of electron scattering processes from metal vapour targets. Results from superelastic scattering experiments from calcium are presented. The experiments were carried out at incident energies of 25�7 and 45 eV referred to the ground state. Scattering amplitudes derived from these experiments demonstrate that current theories are inadequate. The coherence of the excitation process has been studied by measuring the total polarisation. It is shown that the excitation process is coherent over the whole kinematic range. Preliminary results from a study of superelastic electron scattering from lithium are discussed where it is shown that a quantum electrodynamical model can be used to describe the optical pumping process in 6Li and 7Li. In addition the first superelastic electron spectrum is presented for experiments on lithium. A stepwise excitation technique is described with which cross sections for the electron impact excitation of the 3d9 4s2 2D state in copper can be measured. The experiments are complicated by the presence of D states in the incident copper beam. The origin of these D states is described as is a modification of the technique which leads to their removal.