The redox speciation of iron in two lakes

2001 ◽  
Vol 52 (6) ◽  
pp. 885 ◽  
Author(s):  
Annette P. Aldrich ◽  
Constant M. G. van den Berg ◽  
Hansjörg Thies ◽  
Ulrike Nickus

The redox speciation of iron was determined by voltammetry in two lakes (Blelham Tarn, a lowland lake, and Gossenköllesee (GKS), a mountain lake). The reactive iron (FeR) concentration was ~40 nM in the epilimnion of Blelham Tarn, and up to 37% of this occurred as iron(II). In contrast, the FeR concentration in GKS was much lower at ~1 nM, similar to concentrations found in the open ocean. Under ice cover the iron(II) concentration peaked in GKS just below the Chl-a maximum, amounting to 50% of FeR. In July, the Chl-a concentration was lower, and iron(II) was present throughout the water column at ~30% of FeR. This work has demonstrated that iron occurs to a large extent as iron(II) in lake waters, of greatly differing conditions, in spite of the presence of oxygen; the main cause for this is not clear because the iron(II) may have been produced biologically or photochemically (or both). This, and the unexpectedly low reactive-iron concentrations in the transparent mountain-lake waters, warrant further work to evaluate their importance to the microorganisms in the lakes.

2015 ◽  
Vol 61 (230) ◽  
pp. 1207-1212 ◽  
Author(s):  
Iwona Kurzyca ◽  
Adam Choiński ◽  
Joanna Pociask-Karteczka ◽  
Agnieszka Lawniczak ◽  
Marcin Frankowski

AbstractWe discuss the results of an investigation of the chemical composition of the ice cover on the high-mountain lake Morskie Oko in the Tatra Mountains, Carpathians, Poland. In the years 2007–13, the ice cover was characterized by an average duration of 6 months, a thickness range of 0.40–1.14 m, and a multilayered structure with water or slush inclusion. In water from the melted ice cover, chloride (max. 69%) and sulphate (max. 51%) anions and ammonium (max. 66%) and calcium (max. 78%) cations predominated. Different concentrations of ions (F−, Cl−, NO3−, SO42−, Na+, K+, Mg2+, Ca2+, NH4+) in the upper, middle and bottom layers of ice were observed, along with long-term variability and spatial diversification within the ice layer over the lake. Snowpack lying on the ice and the water body under the ice were also investigated, and the influence on the ice cover of certain ions in elevated concentrations was observed (e.g. Cl− in the upper ice cover and the snowpack, and Ca2+ in the bottom ice cover and water body).


2001 ◽  
Vol 30 (4) ◽  
pp. 1286-1295 ◽  
Author(s):  
Rosa Vilanova ◽  
Pilar Fernández ◽  
Carolina Martínez ◽  
Joan O. Grimalt

Author(s):  
Władysława Wojciechowska ◽  
Tomasz Lenard

AbstractThe research was carried out in a mesotrophic and dimictic lake during winters with ice cover. In the last forty years, the development of phytoplankton was analyzed in five extreme winter seasons. The studies of phytoplankton characteristics in the water column took into account values of biomass, concentration of chlorophyll-a and species composition, including dominant species. Differences in the vertical distribution of flagellate and non-flagellate species belonging to cyanobacteria and algae were analyzed in the gradient of light and thermal conditions. The phytoplankton biomass was low and vertically differentiated, with the lowest values at the deeper part of the water column. Flagellate species from the group of Cryptophyceae, Chrysophyceae and Dinophyceae were most abundant. Species biodiversity was low but every winter the dominant species represented different taxonomic groups. In some periods, larger non-motile phytoplankton species from green or blue-green algae dominated. The research proved that the development of phytoplankton under the ice cover was limited mainly by light and, to a lesser extent, by temperature.


2016 ◽  
Vol 121 (8) ◽  
pp. 2064-2081 ◽  
Author(s):  
Stephen R. Parker ◽  
Robert F. West ◽  
Eric S. Boyd ◽  
Jayme Feyhl-Buska ◽  
Christopher H. Gammons ◽  
...  

2005 ◽  
Vol 37 (4) ◽  
pp. 626-635 ◽  
Author(s):  
R. Thompson ◽  
D. Price ◽  
N. Cameron ◽  
V. Jones ◽  
C. Bigler ◽  
...  

2018 ◽  
Vol 30 (0) ◽  
Author(s):  
Herika Cavalcante ◽  
Fabiana Araújo ◽  
Vanessa Becker

Abstract Aim To verify the vertical distribution of phosphorus in the water and to identify the predominant forms of P in the water column for understand the phosphorus dynamics in tropical semiarid reservoirs during a prolonged drought period. Methods Two reservoirs from the semiarid region of Rio Grande do Norte were analysed during the period from May 2015 to June 2016. Were analysed: Suspended solids (SS), chlorophyll a (Chl-a), dissolved oxygen (OD) and temperature. Vertical profiles were plotted for total phosphorus (PT), total dissolved phosphorus (PTD), particulate phosphorus (PP), dissolved organic phosphorus (POD) and soluble reactive phosphorus (FRS). Results The phosphorus values distributed in the water column were high for both reservoirs, presenting the highest values during the periods with lower depth. Gargalheiras presented greater predominance of PT and PP, while Cruzeta had the highest values of FRS. Chl-a and SS values were also consistent with phosphorus values: Chl-a was higher in Gargalheiras, while SS, mainly inorganic, were higher in Cruzeta. Gargalheiras presented anoxic conditions close to the sediment from May 2015 to December 2015, which may induce the release of phosphorus from the sediment to the water column. Values that are too high during the shallower months, especially in Cruzeta, may have been influenced by the release of P from sediment through wind resuspension. Conclusions The amounts and predominant types of phosphorus in the water column are of great importance to understand the phosphorus dynamics and will support restoration plans for the studied environments. In this study it was possible to verify that the reservoirs are susceptible to the release of P from the sediment due to the environmental conditions, mainly low depths, resuspension of the wind and anoxia in the hypolimnion.


2009 ◽  
Vol 6 (4) ◽  
pp. 7853-7896 ◽  
Author(s):  
M. Roy-Barman

Abstract. The "boundary scavenging" box model is a cornerstone of our understanding of the particle-reactive radionuclide fluxes between the open ocean and the ocean margins. However, it does not describe the radionuclide profiles in the water column. Here, I present the transport-reaction equations for radionuclides transported vertically by reversible scavenging on settling particles and laterally by horizontal currents between the margin and the open ocean. Analytical solutions of these equations are compared with existing data. In the Pacific Ocean, the model produces "almost" linear 230Th profiles (as observed in the data) despite lateral transport. However, omitting lateral transport biased the 230Th based particle flux estimates by as much as 50%. 231Pa profiles are well reproduced in the whole water column of the Pacific Margin and from the surface down to 3000 m in the Pacific subtropical gyre. Enhanced bottom scavenging or inflow of 231Pa-poor equatorial water may account for the model-data discrepancy below 3000 m. The lithogenic 232Th is modelled using the same transport parameters as 230Th but a different source function. The main source of 232Th scavenged in the open Pacific is advection from the ocean margin, whereas a net flux of 230Th produced in the open Pacific is advected and scavenged at the margin, illustrating boundary exchange. In the Arctic Ocean, the model reproduces 230Th measured profiles that the uni-dimensional scavenging model or the scavenging-ventilation model failed to explain. Moreover, if lateral transport is ignored, the 230Th based particle settling speed may by underestimated by a factor 4 at the Arctic Ocean margin. The very low scavenging rate in the open Arctic Ocean combined with the enhanced scavenging at the margin accounts for the lack of high 231Pa/230Th ratio in arctic sediments.


2019 ◽  
Author(s):  
Jhon F. Mojica ◽  
Daiane Faller ◽  
Diana Francis ◽  
Clare Eayrs ◽  
David Holland

Abstract. During 2017 Austral winter, an open ocean polynya appeared in the Lazarev Sea, centered over Maud Rise. The vertical structure of the water column presented temporal and spatial variability with a weak stratification during the period of observations from January 2015 to January 2019. While over the Northern Maud Rise area, a highly stratified layer was identified between 80–180 m depth. This layer works as a thermal barrier where the energy from summer months is stored, preventing the warm sub-surface waters from mixing with the shallow waters. So far, a complete description of the polynya formation and maintenance processes is still lacking. To characterize the internal structure of the ocean during the 2017 Maud Rise polynya event we use in situ observations and ocean model reanalysis data. The obtained results revealed that the incidence of thermobaric convection, diapycnal and isopycnal mixing processes over the Maud Rise drives the exchange of energy in the water column. We highlight three relevant factors that contribute to the energy flux for the open-ocean polynya preconditioning: level of instability, pycnocline fluctuation, and bathymetric influence. Another remarkable feature is the warmer summer surface layer over the Maud Rise, which transfers heat to intermediate layers accumulating energy for almost four months. Energy storage at the thermal barrier is evaluated based on heat flux calculations to quantify the exchange of energy between the different water layers. These processes together operate as an ocean preconditioning to the formation and maintenance of an open-ocean polynya event.


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