Synthesis, characterisation and aquatic ecotoxicity of the UV filter hexyl 2-(4-diethylamino-2-hydroxybenzoyl)benzoate (DHHB) and its chlorinated by-products

2016 ◽  
Vol 13 (1) ◽  
pp. 119 ◽  
Author(s):  
Gorica Grbović ◽  
Olga Malev ◽  
Darko Dolenc ◽  
Roberta Sauerborn Klobučar ◽  
Želimira Cvetković ◽  
...  
Keyword(s):  
Chemical Properties ◽  
Transformation Products ◽  
Model Organisms ◽  
Uv Filters ◽  
Uv Filter ◽  
Starting Compound ◽  
Similar Range ◽  
Set Up ◽  
Toxic Potential ◽  
By Products

Environmental context Various UV-filtering chemicals are added to sunscreens in order to protect humans from the harmful effects of the sun. As a consequence of disinfection processes in swimming pools, sunscreen components may be chlorinated and change their structure and properties, leading to derivatives with higher toxicity. The safety of sunscreen components as well as that of their transformation products during their use requires further study. Abstract In this work is presented a synthesis pathway for the UV filter hexyl 2-(4-diethylamino-2-hydroxybenzoyl)benzoate (DHHB) and its chlorinated by-products in order to investigate the transformation behaviour and toxicity changes of DHHB during chlorination disinfection treatment. Acute toxicity was measured using standardised tests with aquatic model organisms. The potency of DHHB was compared with other benzophenone-like UV filters tested in the same experimental set-up. The toxicity of chlorinated compounds tested with photobacteria was found to be in a similar range to that of the starting compound. Microalgae were more sensitive to DHHB than to its chlorinated by-products, whereas daphnids were affected more by DHHB’s chlorinated products. The comparative toxicity data showed DHHB and even more its chlorinated by-products as more highly biologically potent to daphnids than other tested UV filters. The toxic potential of benzophenone-like UV filters should be interpreted together with data on their chemical properties, chlorination effects and affected organisms.

Bacterial communities inhabiting toxic industrial wastewater generated during nitrocellulose production

Biologia ◽  
2016 ◽  
Vol 71 (1) ◽  
Author(s):  
Elvira E. Ziganshina ◽  
Emil M. Ibragimov ◽  
Olga N. Ilinskaya ◽  
Ayrat M. Ziganshin
Keyword(s):  
Bacterial Communities ◽  
Industrial Wastewater ◽  
Chemical Properties ◽  
Industrial Wastes ◽  
Test Results ◽  
Powder Particles ◽  
Wastewater Samples ◽  
Toxic Potential ◽  
By Products ◽  
Bioremediation Processes

AbstractInvestigating the microbial community structure and composition of toxic industrial wastes contaminated with nitrocellulose and various by-products is crucial for understanding the fate of these pollutants in the environment and for the development and application of efiective bioremediation processes. In this study, we investigated the chemical properties and toxic potential of wastewater generated during nitrocellulose production. The analyzed wastewater from settling pond contained nitrocellulose powder particles as well as increased ammonium (570–760 mg/L), sulfate (1625– 2045 mg/L) and sulfite (864–1014 mg/L) concentrations. The toxicity test results demonstrated that the wastewater samples present acute toxicity for

INVESTIGATION OF EROSION RESISTANCE OF GRAY-BROWN SOILS IN THE SOUTHEASTERN SLOPES OF THE GREATER CAUCASUS

2020 ◽  
pp. 47-49
Author(s):  
Aliyev Z.H.
Keyword(s):  
Erosion Resistance ◽  
Preventive Measures ◽  
Chemical Properties ◽  
Anthropogenic Factors ◽  
Erosion Process ◽  
Greater Caucasus ◽  
Sloping Lands ◽  
Set Up ◽  
Physical And Chemical ◽  
And Chemical Properties

In recent years, sharp changes have occurred in the state of sloping lands of Azerbaijan. There was tension from the influence of the anthropogenic factors on the mountain slopes. The fact that the erosion process is rein-forced in the research site. Due to lack of agrotechnical measures on the slopes erosion process has been strength-ened, soil flooded with soil, physical and chemical properties of the soil have deteriorated, nutritional elements are reduced, vegetation is reduced and destruction limit. For some reason, the purpose of the research was Aqsu, two land cuts were set up to determine the degree of actual erosion in the Qizmeydan village. prevent erosion intensity, take preventive measures to take and implement appropriate measures.

scholarly journals Lignans of Sesame (Sesamum indicum L.): A Comprehensive Review

Molecules ◽  
2021 ◽  
Vol 26 (4) ◽  
pp. 883
Author(s):  
Mebeaselassie Andargie ◽  
Maria Vinas ◽  
Anna Rathgeb ◽  
Evelyn Möller ◽  
Petr Karlovsky
Keyword(s):  
Biological Activities ◽  
Chemical Properties ◽  
Transformation Products ◽  
Extensive Literature ◽  
Controversial Issues ◽  
Sesame Seeds ◽  
Historical Texts ◽  
Health Promoting ◽  
Processed Products

Major lignans of sesame sesamin and sesamolin are benzodioxol--substituted furofurans. Sesamol, sesaminol, its epimers, and episesamin are transformation products found in processed products. Synthetic routes to all lignans are known but only sesamol is synthesized industrially. Biosynthesis of furofuran lignans begins with the dimerization of coniferyl alcohol, followed by the formation of dioxoles, oxidation, and glycosylation. Most genes of the lignan pathway in sesame have been identified but the inheritance of lignan content is poorly understood. Health-promoting properties make lignans attractive components of functional food. Lignans enhance the efficiency of insecticides and possess antifeedant activity, but their biological function in plants remains hypothetical. In this work, extensive literature including historical texts is reviewed, controversial issues are critically examined, and errors perpetuated in literature are corrected. The following aspects are covered: chemical properties and transformations of lignans; analysis, purification, and total synthesis; occurrence in Seseamum indicum and related plants; biosynthesis and genetics; biological activities; health-promoting properties; and biological functions. Finally, the improvement of lignan content in sesame seeds by breeding and biotechnology and the potential of hairy roots for manufacturing lignans in vitro are outlined.

scholarly journals Electrospinning: A promising technique for drug delivery systems

2020 ◽  
Vol 59 (1) ◽  
pp. 441-454
Author(s):  
Carlos A. Martínez-Pérez
Keyword(s):  
Drug Delivery ◽  
Drug Delivery Systems ◽  
Chemical Properties ◽  
Delivery Systems ◽  
Extrinsic Factor ◽  
Promising Technique ◽  
Physical Chemical ◽  
Set Up ◽  
Final System ◽  
Intense Research

AbstractIn the last years, electrospinning has become a technique of intense research to design and fabricate drug delivery systems (DDS), during this time a vast variety of DDS with mainly electrospun polymers and many different active ingredient(s) have been developed, many intrinsic and extrinsic factor have influence in the final system, there are those that can be attributed to the equipment set up and that to the physical-chemical properties of the used materials in the fabrication of DDS. After all, this intense research has generated a great amount of DDS loaded with one or more drugs. In this manuscript a review with the highlights of different kind of systems for drug delivery systems is presented, it includes the basic concepts of electrospinning, types of equipment set up, polymer/drug systems, limitations and challenges that need to be overcome for clinical applications.

scholarly journals Investigation of Biotransformation Products of p-Methoxymethylamphetamine and Dihydromephedrone in Wastewater by High-Resolution Mass Spectrometry

Metabolites ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 66
Author(s):  
Juliet Kinyua ◽  
Aikaterini K. Psoma ◽  
Nikolaos I. Rousis ◽  
Maria-Christina Nika ◽  
Adrian Covaci ◽  
...  
Keyword(s):  
Mass Spectrometry ◽  
Wastewater Treatment Plants ◽  
High Resolution Mass Spectrometry ◽  
Transformation Products ◽  
New Psychoactive Substances ◽  
Batch Reactors ◽  
Flight Mass Spectrometry ◽  
Detection And Identification ◽  
Wastewater Samples ◽  
Set Up

There is a paucity of information on biotransformation and stability of new psychoactive substances (NPS) in wastewater. Moreover, the fate of NPS and their transformation products (TPs) in wastewater treatment plants is not well understood. In this study, batch reactors seeded with activated sludge were set up to evaluate biotic, abiotic, and sorption losses of p-methoxymethylamphetamine (PMMA) and dihydromephedrone (DHM) and identify TPs formed during these processes. Detection and identification of all compounds was performed with target and suspect screening approaches using liquid chromatography quadrupole-time-of-flight mass spectrometry. Influent and effluent 24 h composite wastewater samples were collected from Athens from 2014 to 2020. High elimination rates were found for PMMA (80%) and DHM (97%) after a seven-day experiment and degradation appeared to be related to biological activity in the active bioreactor. Ten TPs were identified and the main reactions were O- and N-demethylation, oxidation, and hydroxylation. Some TPs were reported for the first time and some were confirmed by reference standards. Identification of some TPs was enhanced by the use of an in-house retention time prediction model. Mephedrone and some of its previously reported human metabolites were formed from DHM incubation. Retrospective analysis showed that PMMA was the most frequently detected compound.

Effects of Injection of Protein Solutions Prepared from Fish By-products on Yield and Chemical Properties of Chilled and Frozen Saithe (Pollachius virens) Fillets

2013 ◽  
Vol 22 (3) ◽  
pp. 258-269
Author(s):  
Qiancheng Zhao ◽  
Irek Klonowski ◽  
Magnea G. Karlsdottir ◽  
Sigurjon Arason ◽  
Kristin A. Thorarinsdottir
Keyword(s):  
Chemical Properties ◽  
Protein Solutions ◽  
By Products ◽  
And Chemical Properties

TO THE QUESTION OF INDUSTRIAL AEROSOL CONTROL IN THE PROCESSING OF BLISTER COPPER

2021 ◽  
Author(s):  
O.G. Drugova ◽  
◽  
A.A. Fedoruk ◽  
T.N. Shtin
Keyword(s):  
Chemical Properties ◽  
The Body ◽  
Industrial Control ◽  
Silicon Iron ◽  
Carcinogenic Effect ◽  
Copper Zinc ◽  
Toxic Potential ◽  
Physical And Chemical ◽  
Industrial Aerosol ◽  
And Chemical Properties

Abstract. Due to the predominance of PM1 particles in the air samples, the following metals were found in the aerosol: copper, zinc, silicon, iron, lead, sulfur, arsenic, aluminum, antimony, tin, magnesium, cadmium and several other metals. The content of sulfates was significantly noted. These physical and chemical properties show a considerable toxic potential of industrial aerosol. The MPC of lead, sulfur and silicon dioxides, as well as nitrogen oxides and formaldehyde were detected in the working air. Meanwhile, copper, zinc, and iron did not exceed their MPC. Moreover, an underestimation of the aerosol was observed within the framework of industrial control. It has been found that the aerosol components may have an irritating, reprotoxic, allergenic, and carcinogenic effect on the body. Further consideration of the dispersed and chemical composition of the aerosol is required to determine the concentration of identified substances in the working air and the limiting components determining its biological effect.

scholarly journals USE OF SCALED SEMIVARIOGRAMS IN THE PLANNING SAMPLE OF SOIL CHEMICAL PROPERTIES IN SOUTHERN AMAZONAS, BRAZIL

2015 ◽  
Vol 39 (1) ◽  
pp. 31-39 ◽  
Author(s):  
Ivanildo Amorim de Oliveira ◽  
Milton César Costa Campos ◽  
José Marques Junior ◽  
Renato Eleotério de Aquino ◽  
Daniel de Bortoli Teixeira ◽  
...  
Keyword(s):  
Chemical Properties ◽  
Spherical Model ◽  
Exponential Model ◽  
Soil Samples ◽  
Soil Chemical Properties ◽  
Sampling Density ◽  
Sugarcane Crop ◽  
Lack Of Information ◽  
Set Up ◽  
Almost All

The lack of information concerning the variability of soil properties has been a major concern of researchers in the Amazon region. Thus, the aim of this study was to evaluate the spatial variability of soil chemical properties and determine minimal sampling density to characterize the variability of these properties in five environments located in the south of the State of Amazonas, Brazil. The five environments were archaeological dark earth (ADE), forest, pasture land, agroforestry operation, and sugarcane crop. Regular 70 × 70 m mesh grids were set up in these areas, with 64 sample points spaced at 10 m distance. Soil samples were collected at the 0.0-0.1 m depth. The chemical properties of pH in water, OM, P, K, Ca, Mg, H+Al, SB, CEC, and V were determined at these points. Data were analyzed by descriptive and geostatistical analyses. A large part of the data analyzed showed spatial dependence. Chemical properties were best fitted to the spherical model in almost all the environments evaluated, except for the sugarcane field with a better fit to the exponential model. ADE and sugarcane areas had greater heterogeneity of soil chemical properties, showing a greater range and higher sampling density; however, forest and agroforestry areas had less variability of chemical properties.

scholarly journals Lipid Indexes and Quality Evaluation of Omega-3 Rich Oil from the Waste of Japanese Spanish Mackerel Extracted by Supercritical CO2

Marine Drugs ◽  
2022 ◽  
Vol 20 (1) ◽  
pp. 70
Author(s):  
Vikash Chandra Roy ◽  
Jin-Seok Park ◽  
Truc Cong Ho ◽  
Byung-Soo Chun
Keyword(s):  
Fatty Acids ◽  
Polyunsaturated Fatty Acids ◽  
Supercritical Co2 ◽  
Heart Diseases ◽  
Chemical Properties ◽  
Atherogenic Index ◽  
Omega 3 ◽  
Coronary Heart Diseases ◽  
Spanish Mackerel ◽  
By Products

Japanese Spanish mackerel (JSM) (Scomberomorus niphonius) is a marine fish species containing health-beneficial polyunsaturated fatty acids (PUFAs). In the present study, the quality of JSM by-products oils extracted by supercritical CO2 (SC-CO2) and organic solvent extraction was compared in terms of physico-chemical properties of the oils. Eicosapentaenoic acid (EPA) is one of the important polyunsaturated fatty acids present in SC-CO2-extracted skin and muscle oil 5.81 ± 0.69% and 4.93 ± 0.06%, respectively. The amount of docosahexaenoic acid (DHA) in SC-CO2-extracted skin and muscle oil was 12.56 ± 0.38% and 15.01 ± 0.28%, respectively. EPA and DHA are considered as important PUFAs for the development of brain function and the prevention of coronary heart diseases. Extracted oils showed considerable antioxidant activity. In the obtained oils, atherogenic index (AI) values varied from 0.72 to 0.93 and thrombogenic index (TI) ranged from 0.75 to 0.92, which is considered an acceptable level. Fatty acid composition, bio potentiality, thermogravimetric, and vitamin D analysis showed that oils extracted from JSM by-products can be a good source of oil for application in food, pharmaceutical and cosmetic industries. Therefore, the present research revealed the potentiality of green valorisation of S. niphonius by-products as a possible sustainable approach for targeting the era of zero waste.

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