scholarly journals Lability of Pb in soil: effects of soil properties and contaminant source

2014 ◽  
Vol 11 (6) ◽  
pp. 690 ◽  
Author(s):  
Lingchen Mao ◽  
Elizabeth H. Bailey ◽  
Jonathan Chester ◽  
Joseph Dean ◽  
E. Louise Ander ◽  
...  
Keyword(s):  
Soil Properties ◽  
Soil Ph ◽  
Extraction Procedure ◽  
Parent Material ◽  
Isotopic Dilution ◽  
Human Populations ◽  
Isotopic Ratios ◽  
Contaminant Source ◽  
Adverse Health Effects ◽  
Soil Parent Material

Environmental context There is growing concern that lead in the environment may cause adverse health effects in human populations. We investigated the combined use of isotopic abundance and isotopic dilution to show how the origins of soil Pb and soil characteristics affect lability. Soil pH and soil Pb content are the dominant controls on Pb lability; the lability of recent petrol-derived Pb is similar to that of other sources in urban soils but greater than geogenic Pb in rural roadside topsoils. Abstract Lability of lead in soils is influenced by both soil properties and source(s) of contamination. We investigated factors controlling Pb lability in soils from (i) land adjacent to a major rural road, (ii) a sewage processing farm and (iii) an archive of the geochemical survey of London. We measured isotopically exchangeable Pb (E-values; PbE), phase fractionation of Pb by a sequential extraction procedure (SEP) and inferred source apportionment from measured Pb isotopic ratios. Isotopic ratios (206Pb/207Pb and 208Pb/207Pb) of total soil Pb fell on a mixing line between those of petrol and UK coal or Pb ore. The main determinant of the isotopically exchangeable Pb fraction (%E-value) was soil pH: %E-values decreased with increasing pH. In rural roadside topsoils, there was also evidence that petrol-derived Pb remained more labile (35%) than Pb from soil parent material (27%). However, in biosolid-amended and London soils, %E-values were low (~25%), covered a restricted range and showed no clear evidence of source-dependent lability.

Amalgamation and Harmonization of Soil Survey Reports into a Multi-purpose Database

2020 ◽  
Author(s):  
Shane Robert Furze ◽  
Paul Arp
Keyword(s):  
New Brunswick ◽  
Soil Properties ◽  
Vegetation Type ◽  
Soil Classification ◽  
Parent Material ◽  
Soil Survey ◽  
Soil Horizon ◽  
Soil Conditions ◽  
Soil Parent Material ◽  
Soil Surveys

There is a growing demand for standardized, easily accessible and detailed information pertaining to soil and its variability across the landscape. Typically, this information is only available for select areas in the form of local or regional soil surveys reports which are difficult, and costly, to develop. Additionally, soil surveying protocols have changed with time, resulting in inconsistencies between surveys conducted over different periods. This article describes systematic procedures applied to generate an aspatial, terminologically- and unit-consistent, database for forest soils from county-based soil survey reports for the province of New Brunswick, Canada. The procedures involved (i) amalgamating data from individual soil surveys following a hierarchical framework, (ii) summarizing and grouping soil information by soil associations, (iii) assigning correct soil associates to each association, with each soil associate distinguished by drainage classification, (iv) assigning pedologically-correct horizon sequences, as identified in the original soil surveys, to each soil associate, (v) assigning horizon descriptors and measured soil properties to each horizon, as outlined by the Canadian System of Soil Classification, and (vi) harmonizing units of measurement for individual soil properties. Identification and summarization of all soil associations (and corresponding soil associates) was completed with reference to the principal soil-forming factors, namely soil parent material, topographic surface expressions, soil drainage, and dominant vegetation type(s). This procedure, utilizing 17 soil surveys, resulted in an amalgamated database containing 106 soil associations, 243 soil associates, and 522 soil horizon sequences summarizing the variability of forest soil conditions across New Brunswick.

scholarly journals Factors of Variation of Soil Chemical Properties in Metalliferous Ecosystems of Tenke-Fungurume, Katanga, Democratic Republic of the Congo

2019 ◽  
Author(s):  
D. Kaya Muyumba ◽  
E. Ilunga wa Ilunga ◽  
M.-P. Faucon ◽  
G. Mahy ◽  
A. Liénard ◽  
...  
Keyword(s):  
Soil Properties ◽  
Democratic Republic ◽  
Democratic Republic Of Congo ◽  
Chemical Properties ◽  
Site Effect ◽  
Parent Material ◽  
Geochemical Composition ◽  
Soil Parent Material ◽  
Republic Of The Congo ◽  
Metric Variation

Our study aimed at deepen our understanding of relationships between soil properties and vegetation distribution in metalliferous ecosystems of Tenke-Fungurume in the Democratic Republic of Congo. The first question concerned the differences and similarities between soils of the main vegetation units and four variation factors of soil properties were summarized by multivariate analysis. They were all linked to lithology and significantly contributed to explain the distribution of vegetation units. Our result suggest that the variation of soil properties which is observed within the various vegetation units (rocky steppe savanna, sward, and steppe savannas on slope or on Dembo) should partially be attributed to differences of geochemical composition of rocks between sites but the main source of variability is to be found inside each hill. The soil contamination in Cu and Co originates from rock weathering and besides site effect and topographic distribution of the rocks, the variability of soil properties within one vegetation unit may be due to variability of soil parent material and not only to erosion. The second question dealt with the changes of soil properties at small distances. Metric variation was studied from transects between adjacent vegetation units. Our results showed that the abrupt changes of vegetation units which were clearly identified on the field were all truly explained by the variations of one or more properties linked to lithology. The key point being the Cu bioavailability.

scholarly journals The effect of soil properties on zinc lability and solubility in soils of Ethiopia – an isotopic dilution study

SOIL ◽  
2021 ◽  
Vol 7 (1) ◽  
pp. 255-268
Author(s):  
Abdul-Wahab Mossa ◽  
Dawd Gashu ◽  
Martin R. Broadley ◽  
Sarah J. Dunham ◽  
Steve P. McGrath ◽  
...  
Keyword(s):  
Soil Ph ◽  
Solid Phase ◽  
Tropical Soils ◽  
Soil Samples ◽  
Sub Saharan Africa ◽  
Isotopic Dilution ◽  
Zn Deficiency ◽  
Human Populations ◽  
Mean Values ◽  
Geochemical Properties

Abstract. Zinc (Zn) deficiency is a widespread nutritional problem in human populations, especially in sub-Saharan Africa (SSA). The Zn concentration of crops consumed depends in part on the Zn status of the soil. Improved understanding of factors controlling the phyto-availability of Zn in soils can contribute to potential agronomic interventions to tackle Zn deficiency, but many soil types in SSA are poorly studied. Soil samples (n=475) were collected from a large part of the Amhara Region of Ethiopia, where there is widespread Zn deficiency. Zinc status was quantified by measuring several fractions, including the pseudo-total (aqua regia digestion; ZnTot), available (DTPA (diethylenetriamine pentaacetate) extractable; ZnDTPA), soluble (dissolved in 0.01 M Ca(NO3); ZnSoln) and isotopically exchangeable Zn, using the enriched stable Zn isotope 70Zn (ZnE). Soil geochemical properties were assessed for their influence on Zn lability and solubility. A parameterized geochemical assemblage model (Windermere Humic Aqueous Model – WHAM) was also employed to predict the solid phase fractionation of Zn in tropical soils rather than using sequential chemical extractions. ZnTot ranged from 14.1 to 291 mg kg−1 (median = 100 mg kg−1), whereas ZnDTPA in the majority of soil samples was less than 0.5 mg kg−1, indicating widespread phyto-available Zn deficiency in these soils. The labile fraction of Zn in soil (ZnE as % ZnTot) was low, with median and mean values of 4.7 % and 8.0 %, respectively. Labile Zn partitioning between the solid and the solution phases of soil was highly pH dependent, where 94 % of the variation in the partitioning coefficient of 70Zn was explained by soil pH. Similarly, 86 % of the variation in ZnSoln was explained by soil pH. Zinc distribution between adsorbed ZnE and ZnSoln was controlled by pH. Notably, Zn isotopic exchangeability increased with soil pH. This contrasts with literature on contaminated and urban soils and may arise from covarying factors, such as contrasting soil clay mineralogy across the pH range of the soils used in the current study. These results could be used to improve agronomic interventions to tackle Zn deficiency in SSA.

Shea (Vitellaria paradoxa) tree and soil parent material effects on soil properties and intercropped sorghum grain-Zn in southern Mali, West Africa

2014 ◽  
Vol 386 (1-2) ◽  
pp. 21-33 ◽  
Author(s):  
Cheryl L. Verbree ◽  
Jacqueline A. Aitkenhead-Peterson ◽  
Richard H. Loeppert ◽  
Joseph M. Awika ◽  
William A. Payne
Keyword(s):  
West Africa ◽  
Soil Properties ◽  
Parent Material ◽  
Vitellaria Paradoxa ◽  
Soil Parent Material ◽  
Sorghum Grain

scholarly journals Zinc lability and solubility in soils of Ethiopia – an isotopic dilution study

2021 ◽  
Author(s):  
Abdul W. Mossa ◽  
Dawd Gashu ◽  
Martin R. Broadley ◽  
Sarah J. Dunham ◽  
Steve P. McGrath ◽  
...  
Keyword(s):  
Soil Ph ◽  
Clay Mineralogy ◽  
Soil Samples ◽  
Sub Saharan Africa ◽  
Isotopic Dilution ◽  
Zn Deficiency ◽  
Human Populations ◽  
Mean Values ◽  
Geochemical Properties ◽  
Zn Status

Abstract. Zinc (Zn) deficiency is a widespread nutritional problem in human populations, especially in sub-Saharan Africa (SSA). The Zn concentration of crops consumed depends in part on the Zn status of soil. Improved understanding of factors controlling the phyto-availability of Zn in soils can contribute to potential agronomic interventions to tackle Zn deficiency, although there are major knowledge gaps for many soil types in SSA. Soil samples (n = 475) were collected from a large part of the Amhara Region of Ethiopia where there is widespread Zn deficiency. Zinc status was quantified by measuring several fractions: pseudo-total (Aqua-Regia digestion; ZnTot), available (DTPA-extractable; ZnDTPA), soluble (dissolved in 0.01 M Ca(NO3); ZnSoln) and isotopically exchangeable Zn using the enriched stable Zn isotope 70Zn (ZnE). Soil geochemical properties were assessed for their influence on Zn lability and solubility. ZnTot ranged from 14.1 to 291 mg kg−1 (median = 100 mg kg−1) whereas ZnDTPA in the majority of soil samples was less than 0.5 mg kg−1 indicating widespread phytoavailable Zn deficiency in these soils. The labile fraction of Zn in soil (ZnE as %ZnTot) was low, with median and mean values of 4.7 % and 8.0 % respectively. Labile Zn partitioning between the solid and the solution phases of soil was highly pH-dependent where 94 % of the variation in the partitioning coefficient of 70Zn was explained by soil pH. Similarly, 86 % of the variation in ZnSoln was explained by soil pH. Zinc distribution between adsorbed ZnE and ZnSoln was pH controlled. Notably, Zn isotopic exchangeability increased with soil pH. This contrasts with literature on contaminated and urban soils and may arise from covarying factors such as contrasting soil clay mineralogy across the pH range of the soils used in the current study. These results could be used to improve agronomic interventions to tackle Zn deficiency in SSA.

scholarly journals Fractionation of Heavy Metals in Multi-Contaminated Soil Treated with Biochar Using the Sequential Extraction Procedure

Biomolecules ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 448
Author(s):  
Mahrous Awad ◽  
Zhongzhen Liu ◽  
Milan Skalicky ◽  
Eldessoky S. Dessoky ◽  
Marian Brestic ◽  
...  
Keyword(s):  
Heavy Metals ◽  
Organic Matter ◽  
Soil Organic Matter ◽  
Soil Ph ◽  
Contaminated Soil ◽  
Contaminated Soils ◽  
Extraction Procedure ◽  
Sequential Fractionation ◽  
Relationship Of ◽  
The Relationship

Heavy metals (HMs) toxicity represents a global problem depending on the soil environment’s geochemical forms. Biochar addition safely reduces HMs mobile forms, thus, reducing their toxicity to plants. While several studies have shown that biochar could significantly stabilize HMs in contaminated soils, the study of the relationship of soil properties to potential mechanisms still needs further clarification; hence the importance of assessing a naturally contaminated soil amended, in this case with Paulownia biochar (PB) and Bamboo biochar (BB) to fractionate Pb, Cd, Zn, and Cu using short sequential fractionation plans. The relationship of soil pH and organic matter and its effect on the redistribution of these metals were estimated. The results indicated that the acid-soluble metals decreased while the fraction bound to organic matter increased compared to untreated pots. The increase in the organic matter metal-bound was mostly at the expense of the decrease in the acid extractable and Fe/Mn bound ones. The highest application of PB increased the organically bound fraction of Pb, Cd, Zn, and Cu (62, 61, 34, and 61%, respectively), while the BB increased them (61, 49, 42, and 22%, respectively) over the control. Meanwhile, Fe/Mn oxides bound represents the large portion associated with zinc and copper. Concerning soil organic matter (SOM) and soil pH, as potential tools to reduce the risk of the target metals, a significant positive correlation was observed with acid-soluble extractable metal, while a negative correlation was obtained with organic matter-bound metal. The principal component analysis (PCA) shows that the total variance represents 89.7% for the TCPL-extractable and HMs forms and their relation to pH and SOM, which confirms the positive effect of the pH and SOM under PB and BB treatments on reducing the risk of the studied metals. The mobility and bioavailability of these metals and their geochemical forms widely varied according to pH, soil organic matter, biochar types, and application rates. As an environmentally friendly and economical material, biochar emphasizes its importance as a tool that makes the soil more suitable for safe cultivation in the short term and its long-term sustainability. This study proves that it reduces the mobility of HMs, their environmental risks and contributes to food safety. It also confirms that performing more controlled experiments, such as a pot, is a disciplined and effective way to assess the suitability of different types of biochar as soil modifications to restore HMs contaminated soil via controlling the mobilization of these minerals.

scholarly journals Research on heavy metal level and co-occurrence network in typical ecological fragile area

2021 ◽  
Author(s):  
Yiwei Zhao ◽  
Liangmin Gao ◽  
Fugeng Zha ◽  
Xiaoqing Chen ◽  
Xiaofang Zhou ◽  
...  
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Human Factors ◽  
Human Life ◽  
Mining Area ◽  
Parent Material ◽  
Control Value ◽  
Pollution Levels ◽  
Soil Parent Material ◽  
Sampling Points

AbstractDue to the special sensitivity of typical ecologically fragile areas, a series of human life, mining, and other activities have a greater impact on the environment. In this study, three coal mines in Ordos City on the Loess Plateau were selected as the study area, and the pollution levels of heavy metals in the area were studied by measuring As, Hg, Cr, Cd, Cu, Ni, and Pb in the soil of 131 sampling points. Combined with the concept of “co-occurrence network” in biology, the level of heavy metals in soil was studied using geostatistics and remote sensing databases. The results showed that the concentrations of Hg, Cr, Ni, Cu, and Pb in more than half of the sampling points were higher than the local environmental background value, but did not exceed the risk control value specified by China, indicating that human factors have a greater influence, while Cd and As elements are mainly affected Soil parent material and human factors influence. Heavy metal elements have nothing to do with clay and silt but have an obvious correlation with gravel. Cd, Pb, As and Ni, Cd, Cr are all positively correlated, and different heavy metals are in space The distribution also reflects the autocorrelation, mainly concentrated in the northeast of the TS mining area and the middle of the PS mining area.

scholarly journals Soil Nutrient and Vegetation Diversity Patterns of Alpine Wetlands on the Qinghai-Tibetan Plateau

2021 ◽  
Vol 13 (11) ◽  
pp. 6221
Author(s):  
Muyuan Ma ◽  
Yaojun Zhu ◽  
Yuanyun Wei ◽  
Nana Zhao
Keyword(s):  
Species Diversity ◽  
Tibetan Plateau ◽  
Soil Properties ◽  
Soil Ph ◽  
Plant Biomass ◽  
Principal Component ◽  
Vegetation Diversity ◽  
Vegetation Biomass ◽  
Relative Contribution ◽  
The Relationship

To predict the consequences of environmental change on the biodiversity of alpine wetlands, it is necessary to understand the relationship between soil properties and vegetation biodiversity. In this study, we investigated spatial patterns of aboveground vegetation biomass, cover, species diversity, and their relationships with soil properties in the alpine wetlands of the Gannan Tibetan Autonomous Prefecture of on the Qinghai-Tibetan Plateau, China. Furthermore, the relative contribution of soil properties to vegetation biomass, cover, and species diversity were compared using principal component analysis and multiple regression analysis. Generally, the relationship between plant biomass, coverage, diversity, and soil nutrients was linear or unimodal. Soil pH, bulk density and organic carbon were also significantly correlated to plant diversity. The soil attributes differed in their relative contribution to changes in plant productivity and diversity. pH had the highest contribution to vegetation biomass and species richness, while total nitrogen was the highest contributor to vegetation cover and nitrogen–phosphorus ratio (N:P) was the highest contributor to diversity. Both vegetation productivity and diversity were closely related to soil properties, and soil pH and the N:P ratio play particularly important roles in wetland vegetation biomass, cover, and diversity.

The influence of forest site on rate and extent of soil compaction and profile disturbance of skid trails during ground-based harvesting

2000 ◽  
Vol 30 (8) ◽  
pp. 1196-1205 ◽  
Author(s):  
J R Williamson ◽  
W A Neilsen
Keyword(s):  
Root Growth ◽  
Soil Compaction ◽  
Forest Type ◽  
Soil Bulk Density ◽  
Parent Material ◽  
Forest Site ◽  
Undisturbed Soil ◽  
Soil Parent Material ◽  
Wet Forests

Soil compaction has been considered a principal form of damage associated with logging, restricting root growth and reducing productivity. The rate and extent of soil compaction on skid trails was measured at six field locations covering a range of dry and wet forests. Data was collected for up to 21 passes of a laden logging machine. A similar extent of compaction, averaging 0.17 g·cm-3 increase in total soil bulk density (BD), was recorded for all field sites despite substantial site and soil differences. On average, 62% of the compaction in the top 10 cm of the soil occurred after only one pass of a laden logging machine. The environment under which soils had formed played a major role in determining the BD of the undisturbed soil. Compaction was strongly related to the original BD, forest type, and soil parent material. Soil strengths obtained in the field fell below levels found to restrict root growth. However, reduction in macropores, and the effect of that on aeration and drainage could reduce tree growth. On the wettest soils logged, machine forces displaced topsoils rather than causing compaction in situ. Recommended logging methods and implications for the development of sustainability indices are discussed.

scholarly journals Spatial variability and mapping of soil fertility status in a high-potential smallholder farming area under sub-humid conditions in Zimbabwe

2021 ◽  
Vol 3 (4) ◽  
Author(s):  
Gabriel Soropa ◽  
Olton M. Mbisva ◽  
Justice Nyamangara ◽  
Ermson Z. Nyakatawa ◽  
Newton Nyapwere ◽  
...  
Keyword(s):  
Spatial Variability ◽  
Soil Properties ◽  
Soil Ph ◽  
Strong Evidence ◽  
Spatial Dependence ◽  
Random Component ◽  
Smallholder Farming ◽  
Mineral N ◽  
Spatial Trend ◽  
Spatial Trends

AbstractA study was conducted to examine spatial variability of soil properties related to fertility in maize fields across varying soil types in ward 10 of Hurungwe district, Zimbabwe; a smallholder farming area with sub-humid conditions and high yield potential. Purposively collected and geo-referenced soil samples were analyzed for texture, pH, soil organic carbon (OC), mineral N, bicarbonate P, and exchangeable K. Linear mixed model was used to analyze spatial variation of the data. The model allowed prediction of soil properties at unsampled sites by the empirical best linear unbiased predictor (EBLUP). Evidence for spatial dependence in the random component of the model was evaluated by calculating Akaike’s information criterion. Soil pH ranged from 4.0 to 6.9 and showed a strong spatial trend increasing from north to south, strong evidence for a difference between the home and outfields with homefields significantly higher and between soil textural classes with the sand clay loam fraction generally higher. Soil OC ranged from 0.2 to 2.02% and showed no spatial trend, but there was strong evidence for a difference between home and outfields, with mean soil OC in homefields significantly larger, and between soil textural classes, with soil OC largest in the sandy clay loams. Both soil pH and OC showed evidence for spatial dependence in the random effect, providing a basis for spatial prediction by the EBLUP, which was presented as a map. There were significant spatial trends in mineral N, available P and exchangeable K, all increasing from north to south; significant differences between homefields and outfields (larger concentrations in homefields), and differences between the soil textural classes with larger concentrations in the sandy clay loams. However, there was no evidence for spatial dependence in the random component, so no attempt was made to map these variables. These results show how management (home fields vs outfields), basic soil properties (texture) and other factors emerging as spatial trends influence key soil properties that determine soil fertility in these conditions. This implies that the best management practices may vary spatially, and that site-specific management is a desirable goal in conditions such as those which apply in Ward 10 of Hurungwe district in Zimbabwe.

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