Phosphate Removal from Aqueous Solutions using Neutralised Bauxite Refinery Residues (Bauxsol™)

2006 ◽  
Vol 3 (1) ◽  
pp. 65 ◽  
Author(s):  
Darren J. Akhurst ◽  
Graham B. Jones ◽  
Malcolm Clark ◽  
David McConchie

Environmental Context.Eutrophication of freshwater and marine ecosystems is a global problem, which is frequently linked to high phosphorus concentrations. The present study investigated the use of Bauxsol™, a modified bauxite refinery residue, to remove dissolved phosphate from water, and has shown that it can be used as a cost-effective adsorbent for treating phosphate-contaminated waters. The results provide water and environmental managers with a new technique for decreasing the phosphate loads in water and wastewater. Environmental benefits include improved water quality, minimisation of excessive plant growth, including potentially toxic blue green algae, and the utilisation of an industrial residue for environmental remediation. Abstract.Phosphate (PO43–) removal by Bauxsol™, a neutralised bauxite refinery residue, was investigated as a function of time, pH, ionic strength, adsorbent dosage, competing ions, and initial phosphate concentration. The results of adsorption and desorption studies indicate that adsorption of PO43– by Bauxsol™ is based on a ligand-exchange mechanism, although the low reversibility pH-independent desorption observed in acid-treated Bauxsol™ indicates a dominance of chemisorption. It was shown that PO43– adsorption onto both Bauxsol™ and acid-treated Bauxsol™ followed a Langmuir isotherm model, with adsorption capacities of 0.21 and 0.48 mmol g−1 at pH 9.0 and 5.2 respectively. Adsorption of PO43– by Bauxsol™ increased with decreasing pH, with maximum adsorption efficiencies obtained at pH 5.2 ± 0.1 (the lowest pH investigated), higher Bauxsol™ to initial phosphate concentration ratios, and increased time. Studies of the effects of competing ions on the adsorption of PO43– by Bauxsol™ indicated that adsorption decreased in the presence of HCO3− ions, whereas SO42–and Cl− ions had little effect, and Ca2+ and Mg2+ ions increased adsorption. These findings suggest that Bauxsol™ could be used as an efficient low-cost adsorbent for treating phosphate-contaminated waters.

Author(s):  
Harry Miller ◽  
Anders T. Johnson ◽  
Markus Ahrens ◽  
T. Kenton Flanery

A team forms to address the challenge of low cost, low maintenance gas compression that can be quickly ramped up to meet peak demands. The Natural Gas Industry recognizes the importance of efficient, flexible compression equipment for the transmission of gas. In the early 1900s the Gas Industry met its compression objectives with many small reciprocating compressor units. As competition increased, Gas Companies began employing more cost effective larger units 3.7 MW (5,000 bhp) and eventually gas turbines 11+ MW (15,000+ bhp) became the prime mover of choice. While gas fired engine driven compressors are convenient for gas companies; they are becoming increasingly difficult to install. Environmental restrictions have tightened making permitting difficult. The larger gas turbine units seemed a solution because they were the low capital cost prime mover and clean burning. However, gas turbines have not yet achieved the high degree of flexibility and fuel efficiency gas transporters hoped. Flexibility has become an increasingly important issue because of the new “Peaking Power Plants” that are coming online. Gas companies are trying to solve the problem of low cost, low maintenance compression that can be quickly ramped up to meet peak demands. The idea of using electric motors to drive compressors to minimize the environmental, regulatory, and maintenance issues is not new. The idea of installing an electrically powered, highly flexible, efficient, low maintenance compressor unit directly into the pipeline feeding the load, possibly underground where it won’t be seen or heard, is a new and viable way for the gas and electric industries to do business together. This paper examines the application of totally enclosed, variable speed electric motor driven gas compressors to applications requiring completely automated, low maintenance, quick response gas pressure boosters. In this paper we will describe how a natural gas transporter, compressor manufacturer, motor manufacturer, and power company have teamed up to design the world’s first gas compressor that can be installed directly in the pipeline. We will discuss methodologies for installing the proposed compressor, the environmental benefits — no emissions, a small footprint, minimal noise — and the benefit of being able to install compression exactly where it is needed to meet the peaking requirements of today’s new loads.


Author(s):  
Nikhil Dave ◽  
Katie Sue Pascavis ◽  
John Patterson ◽  
Michael Kozicki ◽  
David Wallace ◽  
...  

AbstractSevere acute respiratory syndrome coronavirus 2 (SARS-CoV-2), an elusive and highly pathogenic agent, has resulted in the ongoing COVID-19 pandemic affecting numerous populations worldwide. New studies investigating the tenacity of SARS-CoV-2 have highlighted its ability to persist on a myriad of surfaces for several days, including gowns and shoes. As a result, there is a global need for sterilization of a variety of potentially-contaminated items, ranging from clothing to personal protective equipment like face coverings. To this end, we have designed and constructed a cost-effective, scalable, and sustainable sterilization system that uses ozone gas to inactivate viral particles. We sought to determine the efficacy of the system in the sterilization of viral particles as well as its ability to sterilize N95 respirators for reuse. N95 respirators inoculated with P22 bacteriophage and sterilized in the ozone system showed a 6-log10 reduction in viral load when treated at 25 ppm for 150 minutes. Further, N95 respirators treated with five 150-minute cycles at 35 ppm for a total concentration-time product (CT) of 26,250 ppm min in the ozone system showed comparable filtration efficiency to untreated N95 respirators in a 50 to 200 nmr particulate challenge filtration test. Interestingly, the surgical N95 respirators tested showed complete inactivation of fluid resistance and degradation of the elasticity of polyisoprene straps after five cycles in the sterilization system. Taken together, these data suggest that while our ozone system may negatively affect certain protective aspects of surgical N95 respirators, it does effectively sterilize viral particles and can be utilized for a multitude of other use cases, including sterilizing polypropylene face coverings after potential SARS-CoV-2 contamination. In addition to providing long-term environmental benefits, deployment of this system during the ongoing pandemic reduces the risk of COVID-19 community transmission while conserving monetary resources otherwise spent on the continuous purchase of disposable face coverings.


2013 ◽  
Vol 67 (5) ◽  
pp. 983-988 ◽  
Author(s):  
Shuncai Wang ◽  
Rongzhuo Yuan ◽  
Xueyong Yu ◽  
Chaojie Mao

This study explored the feasibility of utilizing lead–zinc tailings for phosphate removal in laboratory experiments. The adsorption isotherm, kinetics and pH effect were examined in batch experiments. The Freundlich and Langmuir isotherm models were used for data fitting. The adsorption kinetics can be best described by the simple Elovich equation. The phosphate adsorption tends to decrease with the increase of pH, from 0.37 mg P/g at pH 2.05 to 0.12 mg P/g at pH 7.01, and tends to increase from 0.12 mg P/g at pH 7.01 to 0.64 mg P/g at pH 12.52. The actual phosphate removal on the tailings could be a consequence of adsorption and precipitation reactions with Fe, Al and Ca. Due to their low cost, this type of tailings has the potential to be utilized for cost-effective removal of phosphate from wastewater.


2003 ◽  
Vol 83 (5) ◽  
pp. 547-556 ◽  
Author(s):  
L. Zeng ◽  
R. L. Johnson ◽  
X. Li ◽  
J. Liu

The use of low-cost materials for P removal is of interest for developing cost-effective techniques for preventing P pollution. This paper reports a study on phosphate removal from aqueous solutions by sorption on two volcanic soils. The raw and HCl-treated soils were characterized with respect to oxalate-extractable and dithionite-extractable Al and Fe contents, surface area, and P sorption capacities. The phosphate sorption isotherms, kinetics, pH effects, and desorbability were evaluated in batch tests. The measured isotherm data were well fitted by the Freundlich and Temkin models. Phosphate sorption on these soils was relatively fast and the kinetics could be satisfactorily described by the simple Elovich and power function equations. The two soils had maximum phosphate sorption capacities of approximately 0.85 and 1.35 mg g-1 gram of soil at pH 6.0–6.5. The pH had different effects on phosphate sorption on these soils, likely due to either calcium phosphate precipitation or surface repulsion of the negatively charged phosphate species at a higher pH. Column flow-through tests using both synthetic phosphate solution and liquid swine manure confirmed the phosphate removal ability of the volcanic soils. It was concluded that volcanic soils could be potential low-cost materials for controlling P pollution from agricultural sources. Key words: Phosphate removal, volcanic soil, sorption, isotherm, kinetics, desorption


Author(s):  
Tanwi Singh ◽  
Anshuman Sinha

The major risk associated with low platelet count in pregnancy is the increased risk of bleeding during the childbirth or post that. There is an increased blood supply to the uterus during pregnancy and the surgical procedure requires cutting of major blood vessels. Women with thrombocytopenia are at increased risk of losing excessive blood. The risk is more in case of caesarean delivery as compared to vaginal delivery. Hence based on above findings the present study was planned for Assessment of the Platelet Count in the Pregnant Women in IGIMS, Patna, Bihar. The present study was planned in Department of Pathology, Indira Gandhi Institute of Medical Science, Patna, Bihar, India. The present study was planned from duration of January 2019 to June 2019. In the present study 200 pregnant females samples received for the platelet estimation were enrolled in the present study. Clinically platelet indices can be a useful screening test for early identification of preeclampsia and eclampsia. Also platelet indices can assess the prognosis of this disease in pregnant women and can be used as an effective prognostic marker because it correlates with severity of the disease. Platelet count is a simple, low cost, and rapid routine screening test. Hence the data generated from the present study concludes that platelet count can be used as a simple and cost effective tool to monitor the progression of preeclampsia, thereby preventing complications to develop during the gestational period. Keywords: Platelet Count, Pregnant Women, IGIMS, Patna, Bihar, etc.


2019 ◽  
Vol 2019 (4) ◽  
pp. 7-22
Author(s):  
Georges Bridel ◽  
Zdobyslaw Goraj ◽  
Lukasz Kiszkowiak ◽  
Jean-Georges Brévot ◽  
Jean-Pierre Devaux ◽  
...  

Abstract Advanced jet training still relies on old concepts and solutions that are no longer efficient when considering the current and forthcoming changes in air combat. The cost of those old solutions to develop and maintain combat pilot skills are important, adding even more constraints to the training limitations. The requirement of having a trainer aircraft able to perform also light combat aircraft operational mission is adding unnecessary complexity and cost without any real operational advantages to air combat mission training. Thanks to emerging technologies, the JANUS project will study the feasibility of a brand-new concept of agile manoeuvrable training aircraft and an integrated training system, able to provide a live, virtual and constructive environment. The JANUS concept is based on a lightweight, low-cost, high energy aircraft associated to a ground based Integrated Training System providing simulated and emulated signals, simulated and real opponents, combined with real-time feedback on pilot’s physiological characteristics: traditionally embedded sensors are replaced with emulated signals, simulated opponents are proposed to the pilot, enabling out of sight engagement. JANUS is also providing new cost effective and more realistic solutions for “Red air aircraft” missions, organised in so-called “Aggressor Squadrons”.


Author(s):  
Gary McVoy ◽  
Mark Sengenberger ◽  
Elizabeth Novak

Public-works agencies have an obligation to enhance the environment as opportunities arise. The New York State Department of Transportation (NYSDOT) has developed an environmental initiative to make an affirmative contribution to the environment, using the department’s organizational strengths. The environmental initiative is a paradigm shift applicable to all departments of transportation (DOTs). Conventional reactive regulatory compliance can reduce unnecessary environmental damage and sometimes gain grudging regulatory agency cooperation; however, it is not a positive, satisfying way of doing the people’s work. Through proactive steps, NYSDOT has become an important part of the state’s environmental solution (often at little or no additional cost) and has changed its working relationships with environmental agencies and groups. As these agencies and groups have become partners, instead of adversaries, permit-approval times have improved, mitigation costs have declined, morale has improved, and cost-effective environmental benefits are being realized. Procedures are outlined to apply the engineering capabilities of a DOT to the environmental-stewardship responsibilities shared by all governmental organizations.


2018 ◽  
Vol 32 (2) ◽  
pp. 103-119
Author(s):  
Colleen M. Boland ◽  
Chris E. Hogan ◽  
Marilyn F. Johnson

SYNOPSIS Mandatory existence disclosure rules require an organization to disclose a policy's existence, but not its content. We examine policy adoption frequencies in the year immediately after the IRS required mandatory existence disclosure by nonprofits of various governance policies. We also examine adoption frequencies in the year of the subsequent change from mandatory existence disclosure to a disclose-and-explain regime that required supplemental disclosures about the content and implementation of conflict of interest policies. Our results suggest that in areas where there is unclear regulatory authority, mandatory existence disclosure is an effective and low cost regulatory device for encouraging the adoption of policies desired by regulators, provided those policies are cost-effective for regulated firms to implement. In addition, we find that disclose-and-explain regulatory regimes provide stronger incentives for policy adoption than do mandatory existence disclosure regimes and also discourage “check the box” behavior. Future research should examine the impact of mandatory existence disclosure rules in the year that the regulation is implemented. Data Availability: Data are available from sources cited in the text.


2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Robert Christie

Abstract This paper presents an overview of the general chemical principles underlying the structures, synthesis and technical performance of azo pigments, the dominant chemical class of industrial organic pigments in the yellow, orange, and red shade areas, both numerically and in terms of tonnage manufactured. A description of the most significant historical features in this group of pigments is provided, starting from the discovery of the chemistry on which azo colorants are based by Griess in the mid-nineteenth century, through the commercial introduction of the most important classical azo pigments in the early twentieth century, including products known as the Hansa Yellows, β-naphthol reds, including metal salt pigments, and the diarylide yellows and oranges, to the development in the 1950s and 1960s of two classes of azo pigments that exhibit high performance, disazo condensation pigments and benzimidazolone-based azo pigments. A feature that complicates the description of the chemical structures of azo pigments is that they exist in the solid state as the ketohydrazone rather than the hydroxyazo form, in which they have been traditionally been illustrated. Numerous structural studies conducted over the years on an extensive range of azo pigments have demonstrated this feature. In this text, they are referred to throughout as azo (hydrazone) pigments. Since a common synthetic procedure is used in the manufacture of virtually all azo (hydrazone) pigments, this is discussed in some detail, including practical aspects. The procedure brings together two organic components as the fundamental starting materials, a diazo component and a coupling component. An important reason for the dominance of azo (hydrazone) pigments is that they are highly cost-effective. The syntheses generally involve low cost, commodity organic starting materials and are carried out in water as the reaction solvent, which offers obvious economic and environmental advantages. The versatility of the approach means that an immense number of products may be prepared, so that they have been adapted structurally to meet the requirements of many applications. On an industrial scale, the processes are straightforward, making use of simple, multi-purpose chemical plant. Azo pigments may be produced in virtually quantitative yields and the processes are carried out at or below ambient temperatures, thus presenting low energy requirements. Finally, provided that careful control of the reaction conditions is maintained, azo pigments may be prepared directly by an aqueous precipitation process that can optimise physical form, with control of particle size distribution, crystalline structure, and surface character. The applications of azo pigments are outlined, with more detail reserved for subsequent papers on individual products.


2021 ◽  
Vol 13 (15) ◽  
pp. 8421
Author(s):  
Yuan Gao ◽  
Jiandong Huang ◽  
Meng Li ◽  
Zhongran Dai ◽  
Rongli Jiang ◽  
...  

Uranium mining waste causes serious radiation-related health and environmental problems. This has encouraged efforts toward U(VI) removal with low cost and high efficiency. Typical uranium adsorbents, such as polymers, geopolymers, zeolites, and MOFs, and their associated high costs limit their practical applications. In this regard, this work found that the natural combusted coal gangue (CCG) could be a potential precursor of cheap sorbents to eliminate U(VI). The removal efficiency was modulated by chemical activation under acid and alkaline conditions, obtaining HCG (CCG activated with HCl) and KCG (CCG activated with KOH), respectively. The detailed structural analysis uncovered that those natural mineral substances, including quartz and kaolinite, were the main components in CCG and HCG. One of the key findings was that kalsilite formed in KCG under a mild synthetic condition can conspicuous enhance the affinity towards U(VI). The best equilibrium adsorption capacity with KCG was observed to be 140 mg/g under pH 6 within 120 min, following a pseudo-second-order kinetic model. To understand the improved adsorption performance, an adsorption mechanism was proposed by evaluating the pH of uranyl solutions, adsorbent dosage, as well as contact time. Combining with the structural analysis, this revealed that the uranyl adsorption process was mainly governed by chemisorption. This study gave rise to a utilization approach for CCG to obtain cost-effective adsorbents and paved a novel way towards eliminating uranium by a waste control by waste strategy.


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