A Shift-Lattice Interpretation of Structures in the Au4Mn Region of the Au-Mn System

1996 ◽  
Vol 49 (8) ◽  
pp. 873
Author(s):  
RJD Tilley ◽  
RP Williams

The structures of a number of ordered phases in the Au-Mn system derived from the face- centred cubic structure of Au4Mn have been described in a systematic manner by use of shift-lattice distributions of the manganese atoms throughout the matrix of the alloys. The simplest structures are describable in terms of one-dimensional shift lattices, but many are best treated as two- or three-dimensional shift lattices. This approach has allowed structural correlations to be presented that have not been described previously and the variation in stoichiometry of these phases to be accounted for without recourse to defect populations. The diffraction patterns of such structures are also discussed, especially incommensurate patterns from materials with 'infinitely large' crystallographic unit cells.

2020 ◽  
Vol 8 (3) ◽  
pp. 202 ◽  
Author(s):  
Viktor P. Afanas’ev ◽  
Alexander Yu. Basov ◽  
Vladimir P. Budak ◽  
Dmitry S. Efremenko ◽  
Alexander A. Kokhanovsky

In this paper, we analyze the current state of the discrete theory of radiative transfer. One-dimensional, three-dimensional and stochastic radiative transfer models are considered. It is shown that the discrete theory provides a unique solution to the one-dimensional radiative transfer equation. All approximate solution techniques based on the discrete ordinate formalism can be derived based on the synthetic iterations, the small-angle approximation, and the matrix operator method. The possible directions for the perspective development of radiative transfer are outlined.


1984 ◽  
Vol 41 ◽  
Author(s):  
N. Tanaka ◽  
J. M. Cowley

AbstractElectron diffraction patterns with <111> incidence of f.c.c. plate-like crystals prepared by gas evaporation technique show forbidden spots such as the 1/3.422 spot. The origin of the spots has been explained in terms of planar defects such as (i) fractional unit cells on (111) surfaces, (ii) repeated thin twins and (iii) stacking faults or hexagonal layers. In the present study, the defect structures are examined by CBED and HRTEM techniques. The <111> CBED pattern of the platelet shows three-fold symmetry for the whole pattern. The dark field patterns of ± 1/3. 422 discs show symmetry of. These features prove that the platelet ha-s no center of symmetry for the three dimensional crystal (3m) and irregular arrangements of twins parallel to (111) planes. The electron micrographs taken along the <110> and <211> directions can give “cross-section” images of the platelet. The images show a few repeated twins with a thickness of several nm. The dark field images taken with the forbidden spots with <111> incidence show weak step contrast. The contrast may be due to fractional unit cells. Consequently, the forbidden spots of the platelet are mostly due to the fractional unit cells.


Introduction .–Through the work of Bloch our understanding of the behaviour of electrons in crystal lattices has been much advanced. The principal idea of Bloch’s theory is the assumption that the interaction of a given electron with the other particles of the lattice may be replaced in first approximation by a periodic field of potential. With this model an interpretation of the specific heat, the electrical and thermal conductivity, the magnetic susceptibility, the Hall effect, and the optical properties of metals could be obtained. The advantages and limitations inherent in the assumption of Bloch will be much the same as those encountered when replacing the interaction of the electrons in an atom by a suitable central shielding of the unclear field, as in the work of Thomas and Hartree. In the papers quoted a number of general results were given regarding the behaviour of electrons in any periodic field of potential. To obtain a clearer idea of the details of this behaviour with a view to the application in special problems, however, it appeared worth while to investigate the mechanics of electrons in periodic fields of potential somewhat similar to those met with in practice and of such nature that the energy values W and eigenfunctions Ψ of the wave-equation can actually be computed. It is the purpose of this article to discuss a case where the integration is possible. In Section 1 the energy values and in Section 2 the wave-functions in their dependence on the binding introduced by the potential field are discussed for the one dimensional problem. In Section 3 the matrix elements of the linear momentum, which furnish the electric current associated with the various stationary states, are well as the probability of radiative transitions between these states, are evaluated. In Section 4 the results are extended to the three dimensional case and those features considered which one may expect to find in the case of more general periodic fields of potential. Section 5 deals with some applications to physical problems.


1993 ◽  
Vol 8 (4) ◽  
pp. 202-205
Author(s):  
A. N. Sapozhnikov ◽  
E. K. Vasil'ev

By methods of X-ray structure analysis commensurate (one dimensional) and incommensurate (three-dimensional) modulations of the lazurite structure from Baikal deposits are considered. The analysis of the X-ray diffraction powder and single crystal data showed that the one-dimensional (anisotropic) modulation deforms the lazurite cubic structure and is manifested in a broadening and splitting of sublattice lines on the powder diffraction pattern of the mineral. At a three-dimensional modulation, the cubic structure is maintained. It is concluded that a density modulation is a cause of the incommensurate modulation of the lazurite structure. Due to this arrangement, a crystallographic equivalency of subcells is maintained. The cause of the commensurate modulation is an ordered distribution of intraframework units and the displacement modulation where all atoms of the mineral structure participate.


2003 ◽  
Vol 59 (4) ◽  
pp. 429-438 ◽  
Author(s):  
Mitsuko Onoda ◽  
Anne-Claire Dhaussy ◽  
Yasushi Kanke

The structure of a crystal of newly synthesized YV4O8 was refined on the assumption that two polytypes and their respective twin forms intergrow. The model was expressed as a commensurate composite crystal with two types of subsystem: one is a V4O8 framework with rather large tunnels and the other consists of Y ions. In the tunnels, Y ions and vacancies are located at every second site in an ordered manner that is characteristic of each polytype. Refinement was performed using a high-dimensional formalism and all reflections from all domains. Diffuse streaks observed in the X-ray and electron diffraction patterns were simulated using the matrix method that has been used for one-dimensional disorder such as stacking faults. The unusual diffraction phenomena that occur in a crystal of YV4O8 are explained as arising from a multiple-domain structure of coexisting polytypes.


1974 ◽  
Vol 62 (2) ◽  
pp. 331-358 ◽  
Author(s):  
Benoit B. Mandelbrot

Kolmogorov's ‘third hypothesis’ asserts that in intermittent turbulence the average ε of the dissipation ε, taken over any domainD, is ruled by the lognormal probability distribution. This hypothesis will be shown to be inconsistent, save under assumptions that are extreme and unlikely. Further, a widely used justification of lognormality, due to Yaglom and based on probabilistic argument involving a self-similar cascade, will be discussed. In this model, lognormality indeed applies strictly when D is ‘an eddy’, typically a three-dimensional box embedded in a self-similar hierarchy, and may perhaps remain a reasonable approximation when D consists of a few such eddies. On the other hand, the experimental situation is described better by considering averages taken over essentially one-dimensional domainsD. The first purpose of this paper is to carry out Yaglom's cascade argument, labelled as ‘microcanonical’, for such averaging domains. The second is to replace Yaglom's model by a different, less constrained one, based upon the concept of ‘canonical cascade’. It will be shown, both for one-dimensional domains in a microcanonical cascade, and for all domains in canonical cascades, that in every non-degenerate caJe the distribution of ε differs from the lognormal distribution. Depending upon various parameters, the discrepancy may be either moderate, or considerable, or even extreme. In the latter two cases, high-order moments of E turn out to be infinite. This avoids various paradoxes (to be explored) that are present in Kolmogorov's and Yaglom's approaches. The third purpose is to note that high-order moments become infinite only when the number of levels of the cascade tends to infinity, meaning that the internal scale η tends to zero. Granted the usual value of η, this number of levels is actually small, so the representativity of the limit is questionable. This issue was investigated through computer simulation. The results bear upon the question of the extent to which Kolmogorov's second hypothesis applies in the face of intermittency. The fourth purpose is as follows. Yaglom noted that the cascade model predicts that dissipation only occurs in a portion of space of very small total volume. In order to describe the structure of this portion of space, it will be shown useful to introduce the concept of the ‘intrinsic fractional dimension’ A of the carrier of intermittent turbulence. The fifth purpose is to study the relations between the parameters ruling the distribution of η, and those ruling its spectral and dimensional properties. Both conceptually and numerically, these various parameters turn out to be distinct, which opens up several problems for empirical study.


Author(s):  
O.C. de Hodgins ◽  
K. R. Lawless ◽  
R. Anderson

Commercial polyimide films have shown to be homogeneous on a scale of 5 to 200 nm. The observation of Skybond (SKB) 705 and PI5878 was carried out by using a Philips 400, 120 KeV STEM. The objective was to elucidate the structural features of the polymeric samples. The specimens were spun and cured at stepped temperatures in an inert atmosphere and cooled slowly for eight hours. TEM micrographs showed heterogeneities (or nodular structures) generally on a scale of 100 nm for PI5878 and approximately 40 nm for SKB 705, present in large volume fractions of both specimens. See Figures 1 and 2. It is possible that the nodulus observed may be associated with surface effects and the structure of the polymers be regarded as random amorphous arrays. Diffraction patterns of the matrix and the nodular areas showed different amorphous ring patterns in both materials. The specimens were viewed in both bright and dark fields using a high resolution electron microscope which provided magnifications of 100,000X or more on the photographic plates if desired.


Author(s):  
Peter Sterling

The synaptic connections in cat retina that link photoreceptors to ganglion cells have been analyzed quantitatively. Our approach has been to prepare serial, ultrathin sections and photograph en montage at low magnification (˜2000X) in the electron microscope. Six series, 100-300 sections long, have been prepared over the last decade. They derive from different cats but always from the same region of retina, about one degree from the center of the visual axis. The material has been analyzed by reconstructing adjacent neurons in each array and then identifying systematically the synaptic connections between arrays. Most reconstructions were done manually by tracing the outlines of processes in successive sections onto acetate sheets aligned on a cartoonist's jig. The tracings were then digitized, stacked by computer, and printed with the hidden lines removed. The results have provided rather than the usual one-dimensional account of pathways, a three-dimensional account of circuits. From this has emerged insight into the functional architecture.


Author(s):  
A. F. Marshall ◽  
J. W. Steeds ◽  
D. Bouchet ◽  
S. L. Shinde ◽  
R. G. Walmsley

Convergent beam electron diffraction is a powerful technique for determining the crystal structure of a material in TEM. In this paper we have applied it to the study of the intermetallic phases in the Cu-rich end of the Cu-Zr system. These phases are highly ordered. Their composition and structure has been previously studied by microprobe and x-ray diffraction with sometimes conflicting results.The crystalline phases were obtained by annealing amorphous sputter-deposited Cu-Zr. Specimens were thinned for TEM by ion milling and observed in a Philips EM 400. Due to the large unit cells involved, a small convergence angle of diffraction was used; however, the three-dimensional lattice and symmetry information of convergent beam microdiffraction patterns is still present. The results are as follows:1) 21 at% Zr in Cu: annealed at 500°C for 5 hours. An intermetallic phase, Cu3.6Zr (21.7% Zr), space group P6/m has been proposed near this composition (2). The major phase of our annealed material was hexagonal with a point group determined as 6/m.


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