Pigments of Fungi. LXI. Anhydroflavomannin-9,10-quinone 6,6´,8´-Tri-O-methyl Ether from an Australian Dermocybe Toadstool

1999 ◽  
Vol 52 (10) ◽  
pp. 989 ◽  
Author(s):  
Melvyn Gill ◽  
Jin Yu ◽  
Evelin Raudies
Keyword(s):  
Methyl Ether ◽  
Spectroscopic Methods

Anhydroflavomannin-9,10-quinone 6,6´,8´-tri-O-methyl ether (4) is isolated from the Australian toadstool Dermocybe sp. WAT 24274 and its structure and stereochemistry are determined by spectroscopic methods.

scholarly journals Cytotoxic Sesterterpenes from Thai Marine Sponge Hyrtios erectus

Marine Drugs ◽  
2018 ◽  
Vol 16 (12) ◽  
pp. 474 ◽  
Author(s):  
Wirongrong Kaweetripob ◽  
Chulabhorn Mahidol ◽  
Pittaya Tuntiwachwuttikul ◽  
Somsak Ruchirawat ◽  
Hunsa Prawat
Keyword(s):  
Methyl Ether ◽  
Marine Sponge ◽  
Indole Alkaloids ◽  
Cytotoxic Activities ◽  
Spectroscopic Methods ◽  
The Absolute ◽  
Modified Mosher’S Method

Four sesterterpenes, erectusolides B, C, D, and seco-manoalide-25-methyl ether, two 2-furanone derivatives, erectusfuranones A and B, together with thirteen known sesterterpenes, (6Z)-neomanoalide-24-acetate, two diastereomers of 24-O-methylmanoalide, luffariolide B, manoalide, (6E)- and (6Z)-neomanoalide, seco-manoalide, scalarafuran, 12-acetylscalarolide, 12-epi-O-deacetyl-19-deoxyscalarin, 12-epi-scalarin, and 12-O-deacetyl-12-epi-scalarin, three indole alkaloids, 5-hydroxy-1H-indole-3-carbaldehyde, hyrtiosine A, and variabine B, and one norterpene, cavernosine were isolated from the marine sponge Hyrtios erectus. Their structures were determined by means of spectroscopic methods and the absolute configurations of the asymmetric centers were determined using the modified Mosher’s method. The cytotoxic activities for the isolated compounds have been reported.

Novel Flavonoids from the Fern Notholaena sulphurea

1987 ◽  
Vol 42 (9-10) ◽  
pp. 1063-1069 ◽  
Author(s):  
F. J. Arriaga-Giner ◽  
M. Mizuno ◽  
M. Iinuma ◽  
T. Tanaka ◽  
C. Scheele ◽  
...  
Keyword(s):  
Methyl Ether ◽  
Major Constituent ◽  
Spectroscopic Methods ◽  
White Form ◽  
Derivatives Of ◽  
Rare Group

The major constituent of the yellow frond exudate of the fern Notholaena sulphured was identified by spectroscopic methods as 3,5,2′-trihydroxy-7-methoxy-8-acetoxy flavone and its structure was confirmed by synthesis. This novel natural flavonoid was also detected in the frond exudate of five other Notholaena species. In the yellow form of N. sulphurea, the rare 5,2′- dihydroxy-7,8-dimethoxy flavone was also found, along with some trivial flavonoids. The white form of N. sulphurea produces three dihydrochalcones that are accompanied by some kaempferol methyl ethers and apigenin-7-methyl ether. The 3-acetoxy as well as the 3-butyroxy and the 4′- butyroxy derivatives of 7-methyl aromadendrin were also identified in this material. One of them was shown to belong to the extremely rare group of 3-cis-dihydroflavonols.

Pigments of Fungi. LII Anisochiral Flavomannin 6,6′,8-Tri-O-methyl Ether from an Australian Dermocybe Toadstool

1999 ◽  
Vol 52 (8) ◽  
pp. 749 ◽  
Author(s):  
Malcolm S. Buchanan ◽  
Melvyn Gill ◽  
Alberto Gimenez ◽  
Somphone Phonh-Axa ◽  
Evelin Raudies ◽  
...  
Keyword(s):  
Natural Product ◽  
Methyl Ether ◽  
Absolute Configuration ◽  
Enantiomeric Purity ◽  
Chemical Degradation ◽  
Spectroscopic Methods ◽  
Fruiting Bodies ◽  
The Absolute

Flavomannin 6,6′,8-tri-O-methyl ether occurs in the fruiting bodies of the Australian toadstool Dermocybe sp. WAT 24274 as an anisochiral mixture of the (3S,3′S,P)- and (3R,3′R,M)-enantiomers (5) and (7), respectively, in which the former predominates to the extent of 50% e.e. The structure of the natural product is determined by spectroscopic methods and the absolute configuration and enantiomeric purity are deduced from the c.d. spectrum and by chemical degradation of the natural product to a mixture of stereoisomeric dihydroanthracenones that has been analysed by chiral h.p.l.c.

Study on Chemical Constituents of Lagotis yunnanensis

2012 ◽  
Vol 554-556 ◽  
pp. 1845-1848 ◽  
Author(s):  
Jin Yang ◽  
Hai Yan Wu ◽  
Qing Hua Li ◽  
Ping Yi ◽  
Yong Min ◽  
...  
Keyword(s):  
Methyl Ether ◽  
Chromatographic Method ◽  
Chemical Constituents ◽  
Ethanol Extract ◽  
Spectroscopic Methods ◽  
Effective Components ◽  
Whole Plant ◽  
First Time

Lagotis yunnanensis is a folkloric medicine in China. In order to investigate its effective components, The 95% ethanol extract of whole plant of L. yunnanensis was separated and purified with chromatographic method. Eight compounds were obtained and identified as luteolin (1), chrysoeriol (2), apigenin-7-methyl ether (3), 3, 4-dimethoxycinnamyl-D-glucopyranoside (4), verbascoside (5), cistanoside D (6), 2-O--D-glucopyranospylcucurbitacin D (7) and arvenin I (8) by spectroscopic methods. Compounds 1~3 are flavonoids, compounds 4~6 are phenylpropanoids and compounds 7 and 8 are triterpenoids. Compounds 4~8 have been obtained from this species for the first time.

New Furanocoumarins and Other Chemical Constituents from Ficus carica Root Heartwood

2013 ◽  
Vol 68 (1-2) ◽  
pp. 3-7 ◽  
Author(s):  
Renuka Jaina ◽  
Satish C. Jain ◽  
Teena Bhagchandani ◽  
Namita Yadav
Keyword(s):  
Spectral Data ◽  
Methyl Ether ◽  
Chemical Constituents ◽  
Ficus Carica ◽  
Spectroscopic Methods ◽  
Esi Ms ◽  
Chain Compounds ◽  
Related Compounds ◽  
Long Chain

Two new furanocoumarins, 5-(1”,1”-dimethylallyl)-8-methyl psoralen (1) and 2-O-acetyl oxypeucedanin hydrate-3”-methyl ether (2), were isolated from the root heartwood of Ficus carica Linn. together with three known furanocoumarins, two triterpenoids, two long-chain compounds, and a steroid. Their structures and relative confi gurations were elucidated by spectroscopic methods (IR, HR-ESI-MS, and NMR) and by comparison of their NMR spectral data with those of related compounds

Flavonoids from Achillea nobilis L.

2003 ◽  
Vol 58 (1-2) ◽  
pp. 11-16 ◽  
Author(s):  
Liselotte Krenn ◽  
Anca Miron ◽  
Enne Pemp ◽  
Ursula Petr ◽  
Brigitte Kopp
Keyword(s):  
Methyl Ether ◽  
Methanolic Extract ◽  
2D Nmr ◽  
Spectroscopic Methods ◽  
Esi Ms ◽  
H Nmr ◽  
Aerial Parts ◽  
Nmr Techniques ◽  
C Nmr

The detailed investigation of a methanolic extract of aerial parts of Achillea nobilis resulted in the isolation of 10 flavonoids. A new C-glycosylflavone, luteolin-6-C-apiofuranosyl-(1‴→2″)-glucoside, was isolated besides orientin, isoorientin, vitexin, isoschaftoside, luteolin- 7-O-β-glucuronide, luteolin-4′-O-β-glucoside and quercetin-3-O-methyl ether and two rare flavonolglycosides, quercetin-3-O-α-arabinosyl-(1‴→6″ )-glucoside and quercetin-3-O-methylether-7-O-β-glucoside. The structures were established either by comparison with authentic substances or by UV, 1H NMR and 13C NMR spectroscopic methods including 2ᴅ-NMR techniques and ESI-MS

A Series of Novel Flavanones from Fern Exudates

1980 ◽  
Vol 35 (9-10) ◽  
pp. 685-690 ◽  
Author(s):  
Eckhard Wollenweber ◽  
Volker H. Dietz ◽  
Detlef Schillo ◽  
Gerhard Schilling
Keyword(s):  
Methyl Ether ◽  
Spectroscopic Methods ◽  
Minor Components ◽  
Minor Constituents ◽  
Trimethyl Ether

Abstract The white farinose exudate on the fronds of Cheilanthes argentea contains a series of flavanones as minor constituents. These were identified by spectroscopic methods as: 5,4′-diOH,6,7-diOMe flavanone and its 4′-OMe derivative, 5,4′-diOH,7,8-diOMe flavanone and its 4′-OMe derivative, 5,6-diOH,7,8,4′-triOMe flavanone, 5,4′-diOH, 6,7,8-triOMe flavanone and its 4′-OMe derivative. The farina of Notholaena limitanea var. mexicana contains eriodictyol-7,4′-di-methyl ether and eriodictyol-7,3′, 4′-trimethyl ether as minor components. Both compounds were also identified in the exudate of N. fendleri, together with naringenin-7-OMe and naringenin-4′-OMe. In N. lemmonii var. lemmonii trace amounts of 5-OH,7,3′,4′,5′-tetra-OMe flavanone were detected. Nine of these substances are novel natural flavanones.

A test of the effects of pregnenolone methyl ether on subjective feelings of B-29 crews after a twelve-hour mission.

1955 ◽  
Author(s):  
Saul B. Sells ◽  
John R. Barry ◽  
David K. Trites ◽  
Herman I. Chinn
Keyword(s):  
Methyl Ether

Observations on a Relationship between Steroid Metabolism and the Concentration of Plasma Fibrinogen

1963 ◽  
Vol 10 (02) ◽  
pp. 400-405 ◽  
Author(s):  
B. A Amundson ◽  
L. O Pilgeram
Keyword(s):  
Blood Coagulation ◽  
Methyl Ether ◽  
Broad Spectrum ◽  
Human Subjects ◽  
Plasma Fibrinogen ◽  
Steroid Metabolism ◽  
Specific Site ◽  
Chain Reaction ◽  
Normal Human ◽  
A Chain

SummaryEnovid (5 mg norethynodrel and 0.075 mg ethynylestradiol-3-methyl ether) therapy in young normal human subjects causes an increase in plasma fibrinogen of 32.4% (P >C 0.001). Consideration of this effect together with other effects of Enovid on the activity of specific blood coagulatory factors suggests that the steroids are exerting their effect at a specific site of the blood coagulation and/or fibrinolytic system. The broad spectrum of changes which are induced by the steroids may be attributed to a combination of a chain reaction and feed-back control.

Temperature Dependence of the Self-Assembled Styrene Based Random Ionomers in Aqueous Solution

2003 ◽  
Vol 775 ◽  
Author(s):  
Sung-Hwa Oh ◽  
Ju-Myung Song ◽  
Joon-Seop Kim ◽  
Hyang-Rim Oh ◽  
Jeong-A Yu
Keyword(s):  
Partition Coefficients ◽  
Room Temperature ◽  
Aqueous Media ◽  
The Self ◽  
Spectroscopic Methods ◽  
Ion Content ◽  
Repeat Units ◽  
Notable Effect ◽  
Order Of Magnitude ◽  
Experimental Errors

AbstractSolution behaviors of poly(styrene-co-sodium methacrylate) were studied by fluorescence spectroscopic methods using pyrene as a probe. The mol% of methacrylate was in the range 3.6–9.4. Water and N,N-dimethylforamide(DMF) mixture was used as a solvent (DMF/water = 0.2 mol %). The critical micelle (or aggregation) concentrations of ionomers and the partition coefficients of pyrene were obtained the temperature range 10–80°C. At room temperature, the values of CMCs (or CACs) were in the range 4.7 ×10-6 5.3 ×10-6 g/mL and we could not find any notable effect of the content of ionic repeat units within the experimental errors. Unlike CMCs, as the ion content increased, partitioning of pyrene between the hydrophobic aggregates and an aqueous media decreased from 1.5 ×105 to 9.4 ×104. As the temperature increased from 10 to 80 °C, the values of CMCs increased less than one order of magnitude. While, the partition coefficients of pyrene decreased one order of magnitude and the effect of the ion content became negligible.

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