Organolead(IV) Tricarboxylates, New Reagents for Organic Synthesis

1991 ◽  
Vol 44 (10) ◽  
pp. 1353 ◽  
Author(s):  
JT Pinhey
Keyword(s):  
Organic Synthesis ◽  
Bond Formation ◽  
Dicarbonyl Compounds ◽  
Carbon Bond ◽  
Carbon Nucleophiles ◽  
Carbon Carbon Bond ◽  
Marked Preference ◽  
Soft Carbon

Aryl-, vinyl- and alk-1-ynyl-lead(IV) tricarboxylates act as electrophilic arylating, vinylating and alkynylating agents, respectively, with a variety of nucleophiles, especially soft carbon nucleophiles such as β- dicarbonyl compounds, phenols and nitroalkanes. In their reactions, they show a marked preference for carbon-carbon bond formation, especially in which a quaternary centre is produced. The formation and the synthetically useful reactions of these new reagents are reviewed.

Modern Organic Synthesis in the Laboratory

2008 ◽  
Author(s):  
Jie Jack Li ◽  
Chris Limberakis ◽  
Derek A. Pflum
Keyword(s):  
Organic Chemistry ◽  
Graduate Students ◽  
Organic Synthesis ◽  
Functional Group ◽  
Bond Formation ◽  
Reaction Conditions ◽  
Carbon Bond ◽  
Oxidation Reduction ◽  
Carbon Carbon Bond ◽  
Daunting Task

Searching for reaction in organic synthesis has been made much easier in the current age of computer databases. However, the dilemma now is which procedure one selects among the ocean of choices. Especially for novices in the laboratory, it becomes a daunting task to decide what reaction conditions to experiment with first in order to have the best chance of success. This collection intends to serve as an "older and wiser lab-mate" one could have by compiling many of the most commonly used experimental procedures in organic synthesis. With chapters that cover such topics as functional group manipulations, oxidation, reduction, and carbon-carbon bond formation, Modern Organic Synthesis in the Laboratory will be useful for both graduate students and professors in organic chemistry and medicinal chemists in the pharmaceutical and agrochemical industries.

Hydrolase-catalyzed asymmetric carbon–carbon bond formation in organic synthesis

RSC Advances ◽  
2015 ◽  
Vol 5 (22) ◽  
pp. 16801-16814 ◽  
Author(s):  
Zhi Guan ◽  
Ling-Yu Li ◽  
Yan-Hong He
Keyword(s):  
Organic Synthesis ◽  
Bond Formation ◽  
Carbon Bond ◽  
Bond Forming ◽  
Carbon Carbon Bond ◽  
Bond Forming Reactions ◽  
Asymmetric Carbon

This article reviews the hydrolase-catalyzed asymmetric carbon–carbon bond-forming reactions for the preparation of enantiomerically enriched compounds in organic synthesis.

scholarly journals One-pot oxidative carbon–carbon bond formation of 3-benzylic and 3-allylic indoles with carbon nucleophiles

Tetrahedron ◽  
2008 ◽  
Vol 64 (22) ◽  
pp. 5262-5267 ◽  
Author(s):  
Jun-ichi Matsuo ◽  
Yumi Tanaki ◽  
Hiroyuki Ishibashi
Keyword(s):  
Bond Formation ◽  
One Pot ◽  
Carbon Bond ◽  
Carbon Nucleophiles ◽  
Carbon Carbon Bond

Aerobic Photooxidative Carbon–Carbon Bond Formation Between Tertiary Amines and Carbon Nucleophiles Using 2-Chloroanthra-9,10-quinone

Synlett ◽  
2014 ◽  
Vol 25 (10) ◽  
pp. 1453-1457 ◽  
Author(s):  
Akichika Itoh ◽  
Tomoaki Yamaguchi ◽  
Tomoya Nobuta ◽  
Norihiro Tada ◽  
Tsuyoshi Miura ◽  
...  
Keyword(s):  
Bond Formation ◽  
Tertiary Amines ◽  
Carbon Bond ◽  
Carbon Nucleophiles ◽  
Carbon Carbon Bond

Direct Oxidative Carbon−Carbon Bond Formation Using the “Cation Pool” Method. 1. Generation of Iminium Cation Pools and Their Reaction with Carbon Nucleophiles

1999 ◽  
Vol 121 (41) ◽  
pp. 9546-9549 ◽  
Author(s):  
Jun-ichi Yoshida ◽  
Seiji Suga ◽  
Shinkiti Suzuki ◽  
Naoya Kinomura ◽  
Atsushi Yamamoto ◽  
...  
Keyword(s):  
Bond Formation ◽  
Carbon Bond ◽  
Carbon Nucleophiles ◽  
Carbon Carbon Bond
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