Stability Constants of Silver(I) Complexes of Bis(2-chloroethyl) Sulfide (Sulfur Mustard) and Some Related Thioethers in Polar Organic Solvents

1990 ◽  
Vol 43 (9) ◽  
pp. 1573 ◽  
Author(s):  
RI Tilley
Keyword(s):  
Dimethyl Sulfoxide ◽  
Organic Solvents ◽  
Stability Constants ◽  
Sulfur Mustard ◽  
Sulfide Sulfur ◽  
Diethyl Sulfide ◽  
Polar Organic Solvents ◽  
Stability Constants Of Complexes

Stability constants of complexes formed between silver(I) and diethyl sulfide, 2-chloroethyl ethyl sulfide and bis (2-chloroethyl) sulfide (sulfur mustard) in acetone, methanol, dimethylformamide and dimethyl sulfoxide have been determined. The reduced stability of silver(I) complexes with ligands containing a 2-chloroethyl group has been explained in terms of the sulfonium ion character of the ligands.

scholarly journals Giant Pockels effect of polar organic solvents and water in the electric double layer on a transparent electrode

RSC Advances ◽  
2017 ◽  
Vol 7 (72) ◽  
pp. 45682-45690 ◽  
Author(s):  
Hironori Kanemaru ◽  
Shunpei Yukita ◽  
Hajime Namiki ◽  
Yugo Nosaka ◽  
Takayoshi Kobayashi ◽  
...  
Keyword(s):  
Dimethyl Sulfoxide ◽  
Organic Solvents ◽  
Double Layer ◽  
Electric Double Layer ◽  
Transparent Electrode ◽  
Pockels Effect ◽  
Ito Electrode ◽  
Polar Organic Solvents

The Pockels effect of polar organic solvents and water within the electric double layer on an ITO electrode is studied to find that water has the largest Pockels coefficient, followed in order by methanol, ethanol, and dimethyl sulfoxide.

The Hydrolysis of Bis(2-chloroethyl) Sulfide (Sulfur Mustard) in Aqueous Mixtures of Ethanol, Acetone and Dimethyl Sulfoxide

1993 ◽  
Vol 46 (3) ◽  
pp. 293 ◽  
Author(s):  
RI Tilley
Keyword(s):  
Transition State ◽  
Dimethyl Sulfoxide ◽  
Rate Constants ◽  
Charge Separation ◽  
Sulfur Mustard ◽  
Transition States ◽  
Aqueous Mixtures ◽  
Sulfide Sulfur ◽  
Rate Of Hydrolysis ◽  
Hydrolysis Of

The rate of hydrolysis of bis (2-chloroethyl) sulfide (sulfur mustard) in aqueous mixtures of ethanol, acetone and dimethyl sulfoxide has been measured and compared with previously reported values. Rate constants in water at 25°C for the two consecutive hydrolysis reactions undergone by sulfur mustard were estimated to be (2.93�0.15)×10-3 and (3.87�0.14)×10-3 s-1. Charge separation of 0.42 in the transition states was indicated together with significant solvation of the positive end of the transition state dipoles.

Extraction of strontium and barium salts by the nitrobenzene solution of dicarbolide in the presence of glymes

1985 ◽  
Vol 50 (3) ◽  
pp. 581-599 ◽  
Author(s):  
Petr Vaňura ◽  
Emanuel Makrlík
Keyword(s):  
Stability Constants ◽  
Organic Phase ◽  
Equilibrium Constants ◽  
Minor Role ◽  
Nitrobenzene Solution ◽  
Ligand Structure ◽  
Stability Constants Of Complexes ◽  
Separation Factors ◽  
The Stability ◽  
A Minor

Extraction of microamounts of Sr2+ and Ba2+ (henceforth M2+) from the aqueous solutions of perchloric acid (0.0125-1.02 mol/l) by means of the nitrobenzene solutions of dicarbolide (0.004-0.05 mol/l of H+{Co(C2B9H11)2}-) was studied in the presence of monoglyme (only Ba2+), diglyme, triglyme, and tetraglyme (CH3O-(CH2-CH2O)nCH3, where n = 1, 2, 3, 4). The distribution of glyme betweeen the aqueous and organic phases, the extraction of the protonized glyme molecule HL+ together with the extraction of M2+ ion and of the glyme complex with the M2+ ion, i.e., ML2+ (where L is the molecule of glyme), were found to be the dominating reactions in the systems under study. In the systems with tri- and tetraglymes the extraction of H+ and M2+ ions solvated with two glyme molecules, i.e., the formation of HL2+ and ML22+ species, can probably play a minor role. The values of the respective equilibrium constants, of the stability constants of complexes formed in the organic phase, and the theoretical separation factors αBa/Sr were determined. The effect of the ligand structure on the values of extraction and stability constants in the organic phase is discussed.

Analysis of natural wax from Nelumbo nucifera leaves by using polar and non-polar organic solvents

2021 ◽  
Author(s):  
Aradhya Dev Srivastav ◽  
Vireshwar Singh ◽  
Deepak Singh ◽  
Balendu Shekher Giri ◽  
Dhananjay Singh
Keyword(s):  
Organic Solvents ◽  
Nelumbo Nucifera ◽  
Polar Organic Solvents ◽  
Natural Wax

Dissolution of oxidation-cured poly(carbosilane) fiber into polar organic solvents

1997 ◽  
Vol 65 (2) ◽  
pp. 261-265 ◽  
Author(s):  
Masaki Narisawa ◽  
Satoshi Oda ◽  
Shuhei Kitano ◽  
Kiyohito Okamura
Keyword(s):  
Organic Solvents ◽  
Polar Organic Solvents

Adsorption behaviour of neutral organic substances at the free surface of polar organic solvents

2003 ◽  
Vol 552 ◽  
pp. 77-83 ◽  
Author(s):  
J Dąbkowski ◽  
R Pruszkowska-Drachal ◽  
M Dąbkowska ◽  
Z Koczorowski ◽  
S Trasatti
Keyword(s):  
Free Surface ◽  
Organic Solvents ◽  
Organic Substances ◽  
Adsorption Behaviour ◽  
Polar Organic Solvents

Polar organic solvents accelerate the rate of DNA strand replacement reaction

The Analyst ◽  
2015 ◽  
Vol 140 (6) ◽  
pp. 2023-2028 ◽  
Author(s):  
Tianchi Zhang ◽  
Chunli Shang ◽  
Ruixue Duan ◽  
Abdul Hakeem ◽  
Zhenyu Zhang ◽  
...  
Keyword(s):  
Organic Solvents ◽  
Reaction Rate ◽  
Replacement Reaction ◽  
Polar Organic Solvents ◽  
Dna Strand

Acceleration of the reaction rate by polar organic solvents during both simple and complicated DNA strand replacement reactions is reported.

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