Gas-Phase Ion Chemistry of Siloxide and Silamide Ions by Using the Flowing Afterglow. Unusual Rearrangements Involving SiO and SiS Bond Formation

1989 ◽  
Vol 42 (4) ◽  
pp. 489 ◽  
Author(s):  
RAJ Ohair ◽  
JC Sheldon ◽  
JH Bowie ◽  
R Damrauer ◽  
CH Depuy
Keyword(s):  
Gas Phase ◽  
Exchange Reactions ◽  
Ion Chemistry ◽  
Simple Correlation ◽  
Flowing Afterglow ◽  
Gas Phase Ion Chemistry ◽  
Nucleophilic Displacement ◽  
Displacement Reactions ◽  
Gas Phase Ion ◽  
Sulfur Containing

Siloxide ions undergo O/S exchange reactions with suitable sulfur-containing neutrals, e.g. H3SiO-+CS2 → H3SiS-+COS. Silamide ions similarly undergo NR/O and NR/S exchange reactions together with nucleophilic displacement reactions, e.g. Me3SiNMe + CO2 → Me3SiO-+MeNCO →No simple correlation between rate and mechanism is observed for all the studied reactions.

ChemInform Abstract: Recent Gas Phase Ion Chemistry Studies

ChemInform ◽  
2010 ◽  
Vol 30 (20) ◽  
pp. no-no
Author(s):  
Nico M. M. Nibbering
Keyword(s):  
Gas Phase ◽  
Ion Chemistry ◽  
Gas Phase Ion Chemistry ◽  
Gas Phase Ion

Gas-Phase Ion Chemistry of Small Gold Cluster Anions

2010 ◽  
Vol 29 (13) ◽  
pp. 3001-3006 ◽  
Author(s):  
Robert F. Höckendorf ◽  
Yali Cao ◽  
Martin K. Beyer
Keyword(s):  
Gas Phase ◽  
Gold Cluster ◽  
Cluster Anions ◽  
Ion Chemistry ◽  
Gas Phase Ion Chemistry ◽  
Gas Phase Ion ◽  
Small Gold Cluster

Gas-phase ion chemistry of the propyne/ammonia and silane/propyne/ammonia systems

2004 ◽  
Vol 232 (2) ◽  
pp. 139-146 ◽  
Author(s):  
L. Operti ◽  
R. Rabezzana ◽  
F. Turco ◽  
G.A. Vaglio
Keyword(s):  
Gas Phase ◽  
Ion Chemistry ◽  
Gas Phase Ion Chemistry ◽  
Gas Phase Ion

Workshop on „the Applications of Quantum Mechanical Methods in Gas Phase Ion Chemistry“

1999 ◽  
pp. 431-444
Author(s):  
J. HruŠák ◽  
J. F. Liebman ◽  
P. P. Gaspar ◽  
D. J. Berger ◽  
E. Leere Oiestad ◽  
...  
Keyword(s):  
Gas Phase ◽  
Quantum Mechanical ◽  
Ion Chemistry ◽  
Gas Phase Ion Chemistry ◽  
Mechanical Methods ◽  
Gas Phase Ion
Sign in / Sign up

Export Citation Format

Share Document