The Crystal Size and Morphology of Silicalite as Influenced by Gel Nucleation Temperature, Alkalinity and Sodium-Chloride Concentration
Keyword(s):
The influence of sodium chloride, nucleation temperature and alkalinity on crystal size and product morphology of silicalite is described for crystallizations at temperatures of about 170�C. Addition of sodium chloride and increasing alkalinity produce crystals with less intergrowth. Nucleating the gel at 90�C before crystallization significantly reduces crystal size. The intergrowths on the faces of silicalite can be separated and features of the interlocking of separate crystal entities revealed.
2002 ◽
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2018 ◽
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