Structure and Magnetism of Cs2KCr(CN)6 at Very Low Temperatures
Keyword(s):
The structure of the elpasolite Cs2KCr(CN)6 has been determined at 7.0 K by neutron diffraction. 877 unique reflections refined to Rw = 0.020, Χ = 1.4. The Cr(CN)6 unit is close to regular octahedral coordination geometry, with bond lengths of 207.4(4) for Cr-C and 116.6(6) pm for C-N. The C-Cr-C angles average to 90.0(5)� and the Cr-C-N angles to 178.3(1)�. The magnetic susceptibility as a function of temperature and the magnetization as a function of magnetic field strength correspond to the 4A2g ground term perturbed by a small magnetic exchange effect.
1955 ◽
Vol 227
(1169)
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pp. 241-251
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1976 ◽
Vol 32
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pp. 613-622
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1998 ◽
Vol 08
(PR2)
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pp. Pr2-579-Pr2-582
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1978 ◽
Vol 39
(C6)
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pp. C6-816-C6-816
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1988 ◽
Vol 12
(2)
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pp. 89-96
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