scholarly journals The free-radical phenylation of isoquinolinium cation

1982 ◽  
Vol 35 (10) ◽  
pp. 2179 ◽  
Author(s):  
AJ Beveridge ◽  
LK Dyall
Keyword(s):  
Free Radical ◽  
Acid Solution ◽  
Trifluoroacetic Acid ◽  
Theoretical Predictions ◽  
Radical Phenylation

Free-radical phenylation of isoquinolinium cation has been effected by photolysis of phenylthalliurn(III)di(trifluoroacetate) in a trifluoroacetic acid solution of isoquinoline. Analysis (g.l.c. and h.p.l.c.) of the isomeric phenylisoquinoline mixture showed that the dominant product (81.1 %) was 1-phenylisoquinoline, in accordance with two published theoretical predictions.

The Relative Reactivities of the Seven Nuclear Positions of Isoquinoline to Free-Radical Phenylation

1979 ◽  
Vol 32 (2) ◽  
pp. 345 ◽  
Author(s):  
LK Dyall ◽  
CJ Pullin
Keyword(s):  
Free Radical ◽  
Theoretical Predictions ◽  
Radical Phenylation ◽  
Reactivity Order

Free-radical phenylation of isoquinoline has been effected both by photolysis of phenylthallium(III) di(trifluoroacetate) and by the action of pentyl nitrite on aniline. Analysis of the isomeric phenyl isoquinoline mixture by g.l.c. and h.p.l.c. established the reactivity order in the isoquinoline nucleus to be 1 > 5 > 8 > 4 > 3,6,7. This experimental order is compared with the eight published theoretical predictions, none of which is correct.

scholarly journals Solvent Effect on the Free Radical Phenylation with Phenylazotriphenylmethane

1973 ◽  
Vol 46 (2) ◽  
pp. 546-550 ◽  
Author(s):  
Michio Kobayashi ◽  
Hiroshi Minato ◽  
Nobuko Watanabe
Keyword(s):  
Free Radical ◽  
Solvent Effect ◽  
Radical Phenylation

ChemInform Abstract: Ozonization of Perfluoroolefins in Trifluoroacetic Acid Solution.

ChemInform ◽  
1990 ◽  
Vol 21 (5) ◽  
Author(s):  
N. I. MOISEEVA ◽  
A. E. GEKHMAN ◽  
E. S. RUMYANTSEV ◽  
V. I. KLIMANOV ◽  
I. I. MOISEEV
Keyword(s):  
Acid Solution ◽  
Trifluoroacetic Acid

Ozonation of perfluoroolefins in trifluoroacetic acid solution

1989 ◽  
Vol 38 (7) ◽  
pp. 1570-1570 ◽  
Author(s):  
N. I. Moiseeva ◽  
A. E. Gekhman ◽  
E. S. Rumyantsev ◽  
V. I. Klimanov ◽  
I. I. Moiseev
Keyword(s):  
Acid Solution ◽  
Trifluoroacetic Acid

Free-Radical Phenylation of Ferricenium Ion

1964 ◽  
Vol 86 (5) ◽  
pp. 952-953 ◽  
Author(s):  
A. L. J. Beckwith ◽  
R. J. Leydon
Keyword(s):  
Free Radical ◽  
Radical Phenylation
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