The viscosity of dilute aqueous solutions of aliphatic alcohols

1982 ◽  
Vol 35 (3) ◽  
pp. 465 ◽  
Author(s):  
DM Alexander ◽  
DC Moy
Keyword(s):  
Aqueous Solutions ◽  
Aliphatic Alcohols ◽  
Low Concentrations ◽  
Dilute Aqueous Solutions ◽  
B Coefficients

Relative viscosities have been measured of dilute aqueous solutions of aliphatic alcohols, including methanol, ethanol, the propanols, the butanols and the pentanols, at temperatures of 278, 293 and 313 K at concentrations in the range 10-4-10-2 mol dm-3. The Jones and Dole B coefficients have been calculated and compared with literature data extrapolated to low concentrations.

Adsorption of U(VI) from dilute aqueous solutions onto peat moss

2007 ◽  
Vol 95 (1) ◽  
Author(s):  
H. A. Omar ◽  
M. Aziz ◽  
K. Shakir
Keyword(s):  
Ionic Strength ◽  
Aqueous Solutions ◽  
Uranium Concentration ◽  
Probable Mechanism ◽  
Peat Moss ◽  
Optimum Conditions ◽  
Low Concentrations ◽  
Equilibrium Data ◽  
Dilute Aqueous Solutions

The adsorption of U(VI) onto peat moss has been studied as a function of uranium concentration, pH, shaking time and ionic strength. The pH and ionic strength of the solution markedly affect the extent of removal. The attainment of equilibrium is fast and the equilibrium data fit well the Freundlich, Langmuir and Dubinin-Radushkevich equations. A probable mechanism of uptake is discussed. Further studies demonstrate that under optimum conditions peat moss can be used for the treatment of waste solutions containing low concentrations of uranium.

A Method of Measuring the Concentration of Certain Polymers in Dilute Aqueous Solutions

1967 ◽  
Vol 71 (677) ◽  
pp. 381-383
Author(s):  
Y. Goren ◽  
P. O. Kane ◽  
J. F. Norbury
Keyword(s):  
Boundary Layer ◽  
Reynolds Number ◽  
Chemical Analysis ◽  
Aqueous Solutions ◽  
Polymer Solution ◽  
Analytical Method ◽  
Polymer Concentration ◽  
Low Concentrations ◽  
Dilute Aqueous Solutions ◽  
Flow Through

A technique has been devised for measuring the concentration of “Polyox” in dilute aqueous solutions. “Poly-ox”* is one of those polymers whose addition to water in low concentrations causes a reduction in skin friction (if the Reynolds number is sufficiently high) in turbulent flow through a pipe or boundary layer. (See, for example, ref. 1.) The analytical method is probably applicable to other polymers having this property, and it should be generally useful in this field of research. For example, in any experiment in which a polymer solution is injected at a point in a boundary layer, the method could be used to determine the distribution of polymer concentration at downstream sections. It is based on polarography, a well-established tool of chemical analysis of which an excellent account is given in ref. 2.

scholarly journals Disproportionation and Polymerization of Plutonium(IV) in Dilute Aqueous Solutions

1983 ◽  
Vol 26 ◽  
Author(s):  
T. W. Newton ◽  
V. L. Rundberg
Keyword(s):  
Ionic Strength ◽  
Aqueous Solutions ◽  
Rate Constants ◽  
Second Order ◽  
Disproportionation Reaction ◽  
Reaction Products ◽  
Constant Ph ◽  
Low Concentrations ◽  
Dilute Aqueous Solutions ◽  
Ph Range

ABSTRACTThe rates of polymerization and disproportionation of Pu(IV) have been studied using low concentrations: (1.7 − 10) × 10−6M Pu, (0.8 − 12) × 10−4M HCI and 0.01M ionic strength. Osmium(II) complexes such as the tris−4,41−2,21−bipyridine complex were found to react rapidly with Pu(IV) but very slowly, if at all, with Pu(IV) polymer, Pu(lll), or Pu(V). Thus, it is possible to determine unreacted Pu(IV) in the presence of reaction products by using Os(II) complexes. Disproportionation reaction products, Pu(IlI) and Pu(V), were determined using their reactions with Ce(IV) sulfate. We find −d[Pu(IV)]/dt = k'[Pu(IV)]2 at constant pH. Log k1 varies from about 4.25 at pH 3 to about 7.0 at pH 4.1 (units for k1 are M−1min−1). The [H+] dependence varies from about −2 to −3 over the pH range studied. The measured rate is the sum of those for polymerization and disproportionation; the latter reaction amounts to about 75% of the total at pH 3 and 20% at pH 4. The second-order rate constants for disproportionation are very much larger than expected on the basis of extrapolation from 0.2 to 1.OM HClO, solutions. The products of the reaction do not affect the rate, but U(VI), aged Pu(IV) polymer, and CO2 increase the rate.

Steam distillation of taints from cream: IV. Vapour/liquid equilibrium relationships for mesityl oxide and some α-diketones as possible reference substances

1959 ◽  
Vol 26 (1) ◽  
pp. 24-32 ◽  
Author(s):  
F. H. McDowall
Keyword(s):  
Aqueous Solutions ◽  
Steam Distillation ◽  
Mesityl Oxide ◽  
Liquid Equilibrium ◽  
Low Concentrations ◽  
Dilute Aqueous Solutions ◽  
Equilibrium Relationships ◽  
The Relationship

1. Measurements, by means of a continuous vaporization equilibrium still, of vapour/liquid equilibrium relationships in the steam distillation of dilute aqueous solutions showed that for mesityl oxide the relationship was linear, equilibrium coefficient (CV/CL)= 74.2. For acetylpropionyl it was linear over the concentration range l–10 p.p.m. in the liquid, CV/CL=51, and above a concentration of 20 p.p.m. it was again approximately linear. At 20 and 50 p.p.m. in the liquid the values found for CV/CL were 34 and 21·5 respectively.3. For acetyl-iso-butyryl it was not linear even at very low concentrations, of the order of 1–3 p.p.m. in the liquid, but there was an approach to linearity at concentrations 0–1 p.p.m., CV/CL=240. At concentrations above 1 p.p.m. in the liquid there was a steady fall in the value for the equilibrium coefficient.4. For acetylvaleryl it was curvilinear even over the concentration range 0·1–4·0 p.p.m. in the liquid. At 0·5–1·0 p.p.m. in the liquid the equilibrium coefficient was of the order of 240. Above a concentration of 4 p.p.m. in the liquid the relationship was linear.5. For acetylcaproyl it was approximately linear only over the concentration 0·1–0·4 p.p.m. in the liquid, CV/CL=180. At 4 and 8 p.p.m. in the liquid the coefficients were 90 and 70 respectively.6. For acetylbenzoyl it was curvilinear at low concentrations, i.e. 0·1–0·5 p.p.m. in the liquid, CV/CL=30 decreasing to 16. Above this concentration there was a gradual fall in the equilibrium coefficient to 11·5 at 70 p.p.m. in the liquid.7. Of the substances investigated only diacetyl and acetylpropionyl and, within limits, acetylbenzoyl were considered to be of suitable properties for use as reference substances in detailed investigations on cream deodorization equipment.

The reactions of oligoalcohols with arsenic, arsenous, boric and germanic acids

1980 ◽  
Vol 45 (10) ◽  
pp. 2645-2655 ◽  
Author(s):  
Antonín Mikan ◽  
Miloš Bartušek
Keyword(s):  
Aqueous Solutions ◽  
Equilibrium Constants ◽  
Dilute Aqueous Solutions

The reactions of sorbitol, mannitol, adonitol, dulcitol, glucose and glycerol with H3AsO4, H3AsO3, H3BO3 and GeO2 acids in dilute aqueous solutions were studied by potentiometric neutralization titrations. The formation of the following chelates was demonstrated: As(V)L3-, As(III)L(OH)2-, HAs(III)L(OH)2, BL2-, GeL2(OH)- and GeL32- and the equilibrium constants for their formation were found. Conditions for formation of these chelates of organic oligohydroxy compounds are discussed.

Study of potential oscillations during reaction of an aluminium single crystal with an aqueous KOH solution

1990 ◽  
Vol 55 (2) ◽  
pp. 345-353 ◽  
Author(s):  
Ivan Halaša ◽  
Milica Miadoková
Keyword(s):  
Aqueous Solutions ◽  
Single Crystal ◽  
Single Crystals ◽  
Periodic Potential ◽  
Optimum Conditions ◽  
Potential Oscillations ◽  
Dilute Aqueous Solutions ◽  
Experimental Findings ◽  
Kinetics Of

The authors investigated periodic potential changes measured on oriented sections of Al single crystals during spontaneous dissolution in dilute aqueous solutions of KOH, with the aim to find optimum conditions for the formation of potential oscillations. It was found that this phenomenon is related with the kinetics of the reaction investigated, whose rate also changed periodically. The mechanism of the oscillations is discussed in view of the experimental findings.

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