New metabolites from the brown alga Cystophora torulosa

1977 ◽  
Vol 30 (11) ◽  
pp. 2527 ◽  
Author(s):  
RP Gregson ◽  
R Kazlauskas ◽  
PT Murphy ◽  
RJ Wells

The lipid-soluble extract of the brown alga Cystophora torulosa has yielded a complex mixture of polyketide-derived alkenyl resorcinols and a phloroglucinol, together with two straight chain polyenes. Two polyprenyl chromans were also isolated in low yield.

1979 ◽  
Vol 32 (12) ◽  
pp. 2783 ◽  
Author(s):  
AJ Blackman ◽  
C Dragar ◽  
RJ Wells

The lipid-soluble extract of Perithalia caudata has been shown to contain 4-(1'',1''-dimethylprop-2-enyl)-2-(3''-methylbut-2''-enyl)phenol (1), which is the first example known of a naturally occurring phenol bearing a reversed isoprene unit in the para position.


1970 ◽  
Vol 25 (1) ◽  
pp. 54-56 ◽  
Author(s):  
Jürgen Jacob ◽  
Gernot Grimmer

The uropygial (preen) gland fat of the puffin (fratercula arctica) is mainly a mixture of waxes (77%) and triglycerides (23%). The isolated triglycerides which are the main part of the fat tissue of the gland differ only little from the depot fat which was investigated simultaneously. After separation into groups of equal carbon number by preparative GLC the waxes were shown to be a complex mixture of esters between straight-chain, even-numbered alcohols (chain-length C8, C10, C12, C14 and C16) and octanoic, decanoic and dodecanoic acid.


1981 ◽  
Vol 12 (1) ◽  
Author(s):  
R. KAZLAUSKAS ◽  
J. MULDER ◽  
P. T. MURPHY ◽  
R. J. WELLS
Keyword(s):  

1982 ◽  
Vol 35 (1) ◽  
pp. 165 ◽  
Author(s):  
R Kazlauskas ◽  
PT Murphy ◽  
RJ Wells ◽  
RP Gregson

The dichloromethane-soluble extract of the brown alga Acrocarpia paniculata has yielded two homologous branched chain lipids containing a furan ring. Reaction of a substituted furan with 4-phenyl-4H-1,2,4-triazoline-3,5-dione to yield an alkyl 2-ene-1,4-dione was used to determine the orientation of substituents on a 2,3,5-substituted furan.


Tetrahedron ◽  
1981 ◽  
Vol 37 (18) ◽  
pp. 3209-3213 ◽  
Author(s):  
M.D. Higgs ◽  
L.J. Mulheirn
Keyword(s):  

1980 ◽  
Vol 33 (9) ◽  
pp. 2097 ◽  
Author(s):  
R Kazlauskas ◽  
J Mulder ◽  
PT Murphy ◽  
RJ Wells

The antiinflammatory principle of the brown alga Caulocystis cephalornithos has been shown to be 6-tridecylsalicylic acid. Four other metabolites, 3-tridecylphenol, pentadec-1-ene, (E)-heptadec-3-en- 2-one and 8-hydroxy-3-undecyl-1H-2-benzopyran-1-one were also isolated from the dichloromethane extract of the freeze-dried alga.


2004 ◽  
Vol 59 (3-4) ◽  
pp. 263-270 ◽  
Author(s):  
Andreas Bertsch ◽  
Horst Schweer ◽  
Andreas Titze

The labial gland secretions from males of the bumble bee Bombus (Pyrobombus) perplexus Cresson were analysed by gas chromatography/mass spectrometry (GC/MS) in the electron impact and positive ion chemical ionization mode. The major compound of the complex mixture of alkenols, alkenals, fatty acids, hydrocarbons, wax type esters and steroids is 3,7,11,15-tetramethyl-2,6,10-hexadecatrien-1-ol (geranylcitronellol), considerable amounts of hexadecan-1-ol and Z-9-hexadecen-1-ol were also found. All alcohols were present as esters of the detected acids. In older samples both the acids and the alcohols sometimes could not be detected in the GC; therefore, the possibility to check the detected acid-alcohol pattern by interpreting the wax type ester peaks is very instructive. Moreover, the labial gland contains a rich mixture of mono- and di-unsaturated straight chain hydrocarbons. The similarity in composition of the labial glands of the North American B. (Pyrobombus) perplexus with the Eurasian species B. (Pyrobombus) hypnorum corroborates the assumption that the two species are conspecific. The likely supposition that the hydrocarbons could play an essential role in the chemical communication in bumble bees is discussed.


Planta Medica ◽  
2009 ◽  
Vol 75 (09) ◽  
Author(s):  
AO Santos ◽  
EA Britta ◽  
T Ueda-Nakamura ◽  
BP Dias Filho ◽  
EM Bianco ◽  
...  

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