The modification of coordinated acetonitrile lability on cobalt(II) induced by the coordination of 2,2-Di(aminomethyl)propan-1-ol
A single acetonitrile exchange process on Co(diap)(MeCN)32+ (where diap is 2,2-di(aminomethyl)-propan-1-ol) in acetonitrile solution is observed by 14N N.M.R. between 221 and 315.6 K. On the assumption that this process characterizes the two equivalent acetonitrile sites the following parameters are derived: kex(298 K) = (45 � 3) x 105 s-1, ΔH? = 3l.0 � 2.5 kJ mol-1, ΔS? = -l4 � 6 J Mol-1 K-1, where the exchange rate is given by 2kex[Co(diap)(MeCN)32+]. Alternative interpretations are also discussed.
Keyword(s):
Keyword(s):
2017 ◽
Vol 1
(2)
◽
pp. 177-191
Keyword(s):
Keyword(s):
2018 ◽
Vol 63
(2)
◽
pp. 67-86