scholarly journals Ferrocenylalanes. The preparation and properties of (η-C5H5)Fe(η-C5H4Al2Me4Cl)

1973 ◽  
Vol 26 (10) ◽  
pp. 2297 ◽  
Author(s):  
JL Atwood ◽  
BL Bailey ◽  
BL Kindberg ◽  
WJ Cook

The ferrocenylalane (η-C5H5)Fe(η-C5H4Al2Me4Cl) has been synthesized and characterized by means of X-ray diffraction, nuclear magnetic resonance, and mass spectral studies. The structural implications of these studies are discussed.

1988 ◽  
Vol 66 (6) ◽  
pp. 1467-1473 ◽  
Author(s):  
Carmen Avendaño ◽  
María Teresa Ramos ◽  
José Elguero ◽  
María Luisa Jimeno ◽  
Juana Bellanato ◽  
...  

Tautomerism of dibenzothiazolylmethane (1) and its C-methyl derivative (2) has been studied by 1H nuclear magnetic resonance, ultraviolet, and infrared spectroscopy using C,C-dimethyl (3) and N-methyl (4) derivatives as model compounds of the "CH" and "NH" forms, respectively. X-ray diffraction analysis of the "fixed" N-methyl derivative 4 shows that it corresponds to the Z-sE isomer 4b2. The CH tautomers are unstable in solution and they slowly isomerize into a mixture of NH tautomers that depends on the solvent and on the C-substituent (H or CH3).


1981 ◽  
Vol 46 (16) ◽  
pp. 3302-3305 ◽  
Author(s):  
Edmund J. Eisenbraun ◽  
Clinton E. Browne ◽  
Ernest L. Eliel ◽  
David L. Harris ◽  
Asadur Rahman ◽  
...  

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