4,4'-Bipyridine complexes with some uranyl salts

1973 ◽  
Vol 26 (9) ◽  
pp. 1871 ◽  
Author(s):  
IS Ahuja ◽  
R Singh
Keyword(s):  
Solid State ◽  
Rock Salt ◽  
Infrared Spectra ◽  
Low Frequency ◽  
Bidentate Ligand ◽  
Frequency Region ◽  
Chelating Ligands ◽  
Uranyl Chloride ◽  
Metal Atoms ◽  
Polymeric Structures

The complexes formed by 4,4?-bipyridine with uranyl chloride, sulphate, and nitrate of the type UO2(4,4?-bipyridine)X2, where X = Cl or 1/2SO4, and UO2(4,4?-bi-pyridine)1.5(NO3)2 have been prepared and their infrared spectra in the rock salt and low-frequency region (down to 200 cm-1) studied in the solid state. I.r. spectra of these complexes show that 4,4?-bipyridine acts as a bidentate ligand bridging between two metal atoms. It is suggested that the sulphate and nitrate groups act as bidentate chelating ligands and the complexes are polymeric structures.

Organobismuth Compounds. III. Preparation and Infrared Spectra of Triphenylbismuth(V) Derivatives of Dibasic Acids

1971 ◽  
Vol 49 (15) ◽  
pp. 2529-2532 ◽  
Author(s):  
R. G. Goel ◽  
H. S. Prasad
Keyword(s):  
Solid State ◽  
Infrared Spectra ◽  
Frequency Region ◽  
The Other ◽  
Stretching Vibrations ◽  
Derivatives Of ◽  
Polymeric Structures

Triphenylbismuth carbonate, oxalate, sulfate, selenate, and chromate have been prepared and their solid state infrared (i.r.) spectra have been studied in the frequency region 4000 to 200 cm−1. The i.r. spectroscopic results indicate that, like the corresponding trimethyl- and triphenylantimony(V) derivatives, these compounds also have non-ionic polymeric structures containing bridging anion groups and five co-ordinate bismuth. The i.r. frequencies associated with the bismuth–anion stretching vibrations appear to occur at 300 cm−1 for the carbonate and below 300 cm−1 for the other compounds.

Organoantimony compounds. I. Infrared spectra of some trimethyl- and triphenyl-antimony derivatives

1969 ◽  
Vol 47 (8) ◽  
pp. 1423-1427 ◽  
Author(s):  
R. G. Goel ◽  
P. N. Joshi ◽  
D. R. Ridley ◽  
R. E. Beaumont
Keyword(s):  
Solid State ◽  
Infrared Spectra ◽  
Structural Characteristics ◽  
Anionic Group ◽  
Polymeric Structures

Organoantimony compounds of the type R3SbX and (R3Sb)2OX, where R is methyl or phenyl, and X is a bivalent anionic group such as SeO4, CrO4, or C2O4, have been prepared. Structural characteristics of these compounds have been determined by studying their infrared spectra in the solid state between 4000 and 250 cm−1. The spectral results indicate that in both types of compounds the anion X is coordinated to the R3Sb or (R3Sb—O—SbR3) group resulting in non-ionic, five coordinate, polymeric structures.

COORDINATION COMPLEXES OF GROUP (IV) HALIDES: PREPARATION AND INFRARED SPECTRA OF COORDINATION COMPOUNDS OF TITANIUM TETRACHLORIDE, TITANIUM TETRABROMIDE, ZIRCONIUM TETRACHLORIDE, AND TIN TETRACHLORIDE WITH α,ω-DINITRILES AS LIGANDS

1963 ◽  
Vol 41 (9) ◽  
pp. 2130-2136 ◽  
Author(s):  
Sumer Chand Jain ◽  
Roland Rivest
Keyword(s):  
Infrared Spectra ◽  
Dicarboxylic Acids ◽  
Coordination Complexes ◽  
Bidentate Ligand ◽  
Group Iv ◽  
Experimental Conditions ◽  
Short Chain Length ◽  
Metal Atoms ◽  
Titanium Tetrabromide ◽  
Tin Tetrachloride

Coordination complexes between dinitriles of dicarboxylic acids and tetrahalides of titanium, zirconium, or tin have been prepared. The analytical results and the infrared spectra indicate that on working under different experimental conditions three types of compounds are obtained: 2MX4.L—L, MX4.L—L, and MX4.2L—L where MX4 is a Lewis acid and L—L a bidentate ligand. The compounds 2MX4.L—L are explained by the formation of halogen bridging between the two metal atoms. The compounds MX4.L—L are considered to be either coordination polymers or chelates of variable ring size and the compounds MX4.2L—L, ordinary addition compounds where no chelation takes place because of the mutual interaction of the two CN groups in a dinitrile of a short chain length.

Infrared spectra of complexes of isoquinoline with cobalt(II), nickel(II), and zinc(II) sulphates

1968 ◽  
Vol 21 (2) ◽  
pp. 353 ◽  
Author(s):  
IS Ahuja
Keyword(s):  
Solid State ◽  
Infrared Spectra ◽  
Polymeric Structures

The complexes formed by isoquinoline with cobalt(11), nicke1(11), and zinc(11) sulphates have been prepared. These complexes have been examined spectroscopically in the solid state and the possible structures discussed. It is suggested that these complexes are polymeric structures. Allocations for the possible metal-oxygen modes have also been made.

X-ray Structure Refinement and Vibrational Spectroscopy of Ca8Gd2 (PO4)6 O2

2013 ◽  
Vol 12 (10) ◽  
pp. 719-726
Author(s):  
R. Ayadi ◽  
Mohamed Boujelbene ◽  
T. Mhiri
Keyword(s):  
Solid State ◽  
General Formula ◽  
Vibrational Spectroscopy ◽  
Powder Diffraction ◽  
Infrared Spectra ◽  
Solid State Reaction ◽  
Structure Refinement ◽  
Unit Cell ◽  
Cell Group ◽  
X Ray

The present paper is interested in the study of compounds from the apatite family with the general formula Ca10 (PO4)6A2. It particularly brings to light the exploitation of the distinctive stereochemistries of two Ca positions in apatite. In fact, Gd-Bearing oxyapatiteCa8 Gd2 (PO4)6O2 has been synthesized by solid state reaction and characterized by X-ray powder diffraction. The site occupancies of substituents is0.3333 in Gd and 0.3333 for Ca in the Ca(1) position and 0. 5 for Gd in the Ca (2) position.  Besides, the observed frequencies in the Raman and infrared spectra were explained and discussed on the basis of unit-cell group analyses.

scholarly journals Flyback Converter for Solid-State Lighting Applications with Partial Energy Processing

Electronics ◽  
2020 ◽  
Vol 10 (1) ◽  
pp. 60
Author(s):  
Mario Ponce-Silva ◽  
Daniel Salazar-Pérez ◽  
Oscar Miguel Rodríguez-Benítez ◽  
Luis Gerardo Vela-Valdés ◽  
Abraham Claudio-Sánchez ◽  
...  
Keyword(s):  
Solid State ◽  
Power Supply ◽  
Design Methodology ◽  
Low Frequency ◽  
Solid State Lighting ◽  
Voltage Source ◽  
Flyback Converter ◽  
Partial Energy ◽  
In Series ◽  
Energy Processing

The main contribution of this paper is to show a new AC/DC converter based on the rearrangement of the flyback converter. The proposed circuit only manages part of the energy and the rest is delivered directly from the source to the load. Therefore, with the new topology, the efficiency is increased, and the stress of the components is reduced. The rearrangement consist of the secondary of the flyback is placed in parallel with the load, and this arrangement is connected in series with the primary side and the rectified voltage source. The re-arranged flyback is only a reductive topology and with no magnetic isolation. It was studied as a power supply for LEDs. A low frequency averaged analysis (LFAA) was used to determine the behavior of the proposed circuit and an equivalent circuit much easier to analyze was obtained. To validate the theoretical analysis, a design methodology was developed for the re-arranged flyback converter. The designed circuit was implemented in a 10 W prototype. Experimental results showed that the converter has a THDi = 21.7% and a PF = 0.9686.

Far Infrared Group Frequencies. V. Oximes and Aldoximes

1973 ◽  
Vol 27 (1) ◽  
pp. 22-26 ◽  
Author(s):  
S. M. Craven ◽  
F. F. Bentley ◽  
D. F. Pensenstadler
Keyword(s):  
Hydrogen Bond ◽  
Infrared Spectra ◽  
Low Frequency ◽  
Far Infrared ◽  
Torsional Vibrations ◽  
Lattice Vibrations ◽  
Dilute Solutions ◽  
Solid Samples ◽  
Bending Modes ◽  
Bond Stretch

The low frequency infrared spectra from 450 to 75 cm−1 of seven oximes and five aldoximes have been recorded for pure samples and for dilute solutions in cyclohexane. An intense characteristic band is present in the solution spectra at 367 ± 10 cm−1. This characteristic band shifts to 275 ± 10 cm−1 in the spectra of the OD compounds. The 367 ± 10 cm−1 and 275 ± 10 cm−1 bands are assigned to OH and OD torsional vibrations. A comparison of the solution spectra with spectra of the solid samples indicated that the OH … N hydrogen bond stretch of oximes and aldoximes occurs in 300 to 200 cm−1 region. Strong bands also are present in 140 to 100 cm−1 region which are due to OH … N bending modes or perhaps lattice vibrations.

Transition metal acetates

1968 ◽  
Vol 46 (22) ◽  
pp. 3443-3446 ◽  
Author(s):  
D. A. Edwards ◽  
R. N. Hayward
Keyword(s):  
Solid State ◽  
Thermogravimetric Analysis ◽  
Transition Metal ◽  
Infrared Spectra ◽  
Magnetic Moments ◽  
Acetate Group ◽  
Visible Spectra

Some anhydrous transition metal acetates (Mn(II), Co(II), Cu(II), Ni(II), Zn(II), Ag(I), Mo(II), Ce(III), La(III)) have been prepared and their infrared spectra measured in the solid state. The infrared spectra have been related to established modes of bonding of the acetate group to metals. Thermal decompositions of the anhydrous acetates have been investigated by thermogravimetric analysis; magnetic moments and visible spectra have been measured.

Incoherent inelastic neutron scattering from polyacetylenes in the low-frequency region

1985 ◽  
Vol 10 (4) ◽  
pp. 293-295 ◽  
Author(s):  
M. Tasumi ◽  
I. Harada ◽  
H. Takeuchi ◽  
H. Shirakawa ◽  
S. Suzuki ◽  
...  
Keyword(s):  
Neutron Scattering ◽  
Inelastic Neutron Scattering ◽  
Low Frequency ◽  
Inelastic Neutron ◽  
Frequency Region
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