Tris(dithioacetylacetonato)chromium(III)

1972 ◽  
Vol 25 (12) ◽  
pp. 2547 ◽  
Author(s):  
GA Heath ◽  
RL Martin ◽  
AF Masters

The synthesis of the first dithioaoetylacetonate of a Group VI transition metal has been achieved by reduction of the 3,5-dimethyl-1,2-dithiolium cation with divalent chromium. The physical properties of the dark green monomer [Cr(SacSac)3] are reported.

1968 ◽  
Vol 21 (6) ◽  
pp. 1435 ◽  
Author(s):  
R Colton ◽  
GR Scollary

Reaction of ammonium thiocyanate with dihalocarbonyls of molybdenum and tungsten(11) leads to the elimination of ammonium chloride and the formation of a dithiocyanatocarbonyl complex of the transition metal. Although the thiocyanatocarbonyls themselves have not been isolated in a pure state, a number of substituted derivatives with phosphorus donor ligands have been prepared and characterized. In general these complexes are less stable than the corresponding carbonyl halide derivatives.


RSC Advances ◽  
2015 ◽  
Vol 5 (14) ◽  
pp. 10703-10706
Author(s):  
Hwa Tiong Poh ◽  
Ashfaq A. Bengali ◽  
Wai Yip Fan

Group VI metal carbonyl hydrosulfides as water-soluble H2S-releasing molecules.


2018 ◽  
Vol 6 (18) ◽  
pp. 8693-8704 ◽  
Author(s):  
Ashima Rawat ◽  
Nityasagar Jena ◽  
Dimple Dimple ◽  
Abir De Sarkar

Artificial photosynthesis in group VI B transition metal dichalcogenide monolayers.


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