Chemistry of the Podocarpaceae. XL. Conversion of methyl 12-Hydroxypodocarpa-8,11,13-trien-19-oate into Methyl 13-hydroxypodocarpa-8,11,13-trien-19-oate

1972 ◽  
Vol 25 (6) ◽  
pp. 1253 ◽  
Author(s):  
RC Cambie ◽  
KP Mathai ◽  
AW Missen
Keyword(s):  
Raney Nickel ◽  
Favourable Case

Methods for the conversion of methyl (+)-12-hydroxypodocarpa-8,11,13- trien-19-oate (7) into the synthetically more useful compound methyl (+)-13-methoxypodocarpa-8,11,13-trien-19-oate (8) have been investigated. In the most favourable case, the transformation has been effected in c. 57% yield by a five-stage sequence involving hydrogenolysis of the 13-amino-12-tosylate (31) with Raney nickel.

Hydrophobic hydrogen anode with a nickel catalyst

1982 ◽  
Vol 47 (12) ◽  
pp. 3230-3235 ◽  
Author(s):  
Olga Marholová ◽  
Karel Smrček
Keyword(s):  
Surface Area ◽  
Nickel Catalyst ◽  
Raney Nickel ◽  
Platinum Catalyst ◽  
Raney Nickel Catalyst ◽  
Electrochemical Parameters ◽  
Geometric Surface ◽  
Geometric Surface Area ◽  
Hydrogen Anode ◽  
In Cells

A hydrophobic porous hydrogen anode was prepared whose electrochemical parameters are comparable with anodes containing a platinum catalyst. For its successful preparation, oxidation of the Raney nickel catalyst with air oxygen or with fluorine from Teflon must be prevented. The electrodes of a geometric surface area up to 450 cm2 were tested in cells and modules filled with 7M-KOH.

Neutron vibrational spectroscopy of hydrogen and deuterium on Raney nickel

1982 ◽  
Vol 77 (3) ◽  
pp. 1540-1547 ◽  
Author(s):  
R. R. Cavanagh ◽  
R. D. Kelley ◽  
J. J. Rush
Keyword(s):  
Vibrational Spectroscopy ◽  
Raney Nickel

ChemInform Abstract: STUDIES ON FURAN ACETAL COMPOUNDS. X. HYDROGENATION OF 2-FURYL-1,3-DIOXANES ON RANEY NICKEL

1978 ◽  
Vol 9 (1) ◽  
Author(s):  
V. G. KUL'NEVICH ◽  
Z. I. ZELIKMAN ◽  
ZH. V. KAPUSTYANSKAYA ◽  
V. G. GLUKHOVTSEV ◽  
S. E. TKACHENKO ◽  
...  
Keyword(s):  
Raney Nickel

The Effect of Bases on the Hydrogenation of Alkylphenols in the Presence of Raney Nickel

1944 ◽  
Vol 66 (7) ◽  
pp. 1218-1220 ◽  
Author(s):  
Herbert E. Ungnade ◽  
Dorothy V. Nightingale
Keyword(s):  
Raney Nickel

Synthesis and Crystal Structures of the P,N-Substituted Ferrocenes [Fe{η5-C5H4–P(S)Ph2}(η5-C5H4–NHCH2tBu)] and [Fe(η5-C5H4– PPh2)(η5-C5H4–NHCH2tBu)]

2014 ◽  
Vol 69 (8) ◽  
pp. 906-912 ◽  
Author(s):  
Michael Ritte ◽  
Clemens Bruhn ◽  
Ulrich Siemeling
Keyword(s):  
Crystal Structures ◽  
Raney Nickel ◽  
X Ray Diffraction ◽  
X Ray ◽  
Bromo Derivative

The P,N-substituted ferrocene [Fe{η5-C5H4-P(S)Ph2}(η5-C5H4-NHCH2tBu)] was prepared in six steps from the bromo derivative [Fe{η5-C5H4-PPh2}(η5-C5H4-Br)]. Its reductive desulfurisation with Raney nickel afforded the corresponding phosphino-substituted derivative [Fe(η5-C5H4- PPh2)(η5-C5H4-NHCH2tBu)]. Both compounds have been structurally characterised by singlecrystal X-ray diffraction studies.

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