The reduction of zinc(II) in concentrated lithium halide solutions

1972 ◽  
Vol 25 (1) ◽  
pp. 1 ◽  
Author(s):  
GH Aylward ◽  
GS Buchanan ◽  
RW Lee ◽  
EC Watton
Keyword(s):  
Electron Transfer ◽  
Lithium Chloride ◽  
Electrolyte Concentration ◽  
Lithium Bromide ◽  
Lithium Iodide ◽  
Faradaic Impedance ◽  
Transfer Processes ◽  
Electron Transfer Processes ◽  
Bromide Solutions

The reduction of zinc(11) in lithium halide solutions has been studied using a.c. and d.c. polarography over an electrolyte concentration range of 1-20m for lithium chloride and lithium bromide solutions, and 1-12m for lithium iodide solutions. The degree of reversibility for the reduction increased with increase in electrolyte concentration in the order LiI > LiBr > LiCl. Faradaic impedance techniques were utilized to evaluate the rates of the electron-transfer processes.

scholarly journals RuIII(edta) complexes as molecular redox catalysts in chemical and electrochemical reduction of dioxygen and hydrogen peroxide: inner-sphere versus outer-sphere mechanism

RSC Advances ◽  
2021 ◽  
Vol 11 (35) ◽  
pp. 21359-21366
Author(s):  
Debabrata Chatterjee ◽  
Marta Chrzanowska ◽  
Anna Katafias ◽  
Maria Oszajca ◽  
Rudi van Eldik
Keyword(s):  
Hydrogen Peroxide ◽  
Electron Transfer ◽  
Electrochemical Reduction ◽  
Molecular Oxygen ◽  
Outer Sphere ◽  
Transfer Processes ◽  
Edta Complexes ◽  
Inner Sphere ◽  
Electron Transfer Processes ◽  
Sphere Mechanism

[RuII(edta)(L)]2–, where edta4– =ethylenediaminetetraacetate; L = pyrazine (pz) and H2O, can reduce molecular oxygen sequentially to hydrogen peroxide and further to water by involving both outer-sphere and inner-sphere electron transfer processes.

Photoinduced electron transfer in mechanically interlocked suit[3]ane systems

2021 ◽  
Author(s):  
Anton J Stasyuk ◽  
Olga A. Stasyuk ◽  
Miquel Solà ◽  
Alexander Voityuk
Keyword(s):  
Electron Transfer ◽  
Photoinduced Electron Transfer ◽  
New Class ◽  
Transfer Processes ◽  
Two Component ◽  
Electron Transfer Processes

Suitanes, a new class of two-component mechanically interlocked systems, have recently been developed. In this work, we report a detailed study of photoinduced electron transfer processes in the suit[3]anes consisting...

scholarly journals Regulation of electron transfer processes affects phototrophic mat structure and activity

2015 ◽  
Vol 6 ◽  
Author(s):  
Phuc T. Ha ◽  
Ryan S. Renslow ◽  
Erhan Atci ◽  
Patrick N. Reardon ◽  
Stephen R. Lindemann ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Transfer Processes ◽  
Electron Transfer Processes ◽  
Structure And Activity

Effects of electron-transfer processes on conformation

1986 ◽  
Vol 19 (10) ◽  
pp. 300-306 ◽  
Author(s):  
Walter Huber ◽  
Klaus Muellen
Keyword(s):  
Electron Transfer ◽  
Transfer Processes ◽  
Electron Transfer Processes
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