Chemistry of the Podocarpaceae. XXXV. 12-Methoxypodocarpa-8,11,13- triene and 12-Methoxyabieta-8,11,13-triene derivatives: A synthesis of (+)-hinokione methyl ether

1971 ◽  
Vol 24 (12) ◽  
pp. 2611 ◽  
Author(s):  
RC Cambie ◽  
TJ Fullerton

12-Methoxypodocarpa-8,11,13-trien-19-oic acid (9) and 12-methoxyabieta- 8,11,13-trien-19-oic acid (10) have been converted into 3-0x0-4,4-dimethyl derivatives (15) and (18) by successive reactions involving oxidative decarboxylation, selective epoxidation, epoxide opening, double bond isomerization, oxidation, and reductive methylation. The sequence starting from the acid (10) provides a synthesis of the methyl ether of hinokione (14).

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2015 ◽  
Vol 5 (45) ◽  
pp. 36075-36082 ◽  
Author(s):  
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Gobi Selvam ◽  
Kannan Srinivasan

Isomerization of ethyl linoleate and vegetable oils to conjugated derivatives is achieved over an MgAl-LDH supported ruthenium catalyst under mild reaction conditions.


Biochemistry ◽  
1988 ◽  
Vol 27 (17) ◽  
pp. 6495-6499 ◽  
Author(s):  
Yoshinori Shichida ◽  
Katsuki Nakamura ◽  
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Author(s):  
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Kongkiat Suriye ◽  
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Joongjai Panpranot

2011 ◽  
Vol 27 (05) ◽  
pp. 1081-1088
Author(s):  
LI Yan-Feng ◽  
◽  
ZHU Ji-Qin ◽  
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HE Peng ◽  
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