Vapour phase composition above molten salt mixtures: A mass spectrometric study

1966 ◽  
Vol 19 (6) ◽  
pp. 1003 ◽  
Author(s):  
H Bloom ◽  
JW Hastie
Keyword(s):  
Phase Composition ◽  
Alkali Metal ◽  
Mass Spectrometric Study ◽  
Vapour Phase ◽  
Divalent Metal ◽  
Mass Spectrometric ◽  
Spectrometric Study ◽  
Complex Molecules ◽  
Salt Mixtures ◽  
Salt Systems

A preliminary mass spectrometric study has been carried out on salt vapours in equilibrium with both solid and liquid CdCl2, CsCl, PbCl2, and the salt systems CdCl2 + RbCl, CdCl2+ CsCl, PbCl2 + RbCl, and PbCl2 + CsCl. The results are interpreted to indicate the existence of complex molecules of the type AMCl3 in the salt systems studied (where A is an alkali metal and M is a divalent metal).

Mass spectrometry of the vapours over PbBr2+MBr mixtures (M = Na, K, Rb, Cs)

1971 ◽  
Vol 24 (10) ◽  
pp. 2001 ◽  
Author(s):  
H Bloom ◽  
RG Anthony
Keyword(s):  
Mass Spectrometry ◽  
General Formula ◽  
Mass Spectrometric Study ◽  
Mass Spectrometric ◽  
Enthalpies Of Formation ◽  
Second Law ◽  
Spectrometric Study ◽  
Complex Molecules ◽  
Bipyramidal Structure

A mass spectrometric study of vapours above molten PbBr2+MBr mixtures has revealed the existence of vapour species of general formula MPbBr3 (M = Na, K, Rb, Cs). Second-law enthalpies of formation of these complexes were found to be in the range -39 to -44 kcal/mol; entropies of formation are estimated between -20 to -21 e.u. It is believed that these complex molecules have a bipyramidal structure.

Fast atom bombardment mass spectrometric study of alkali metal cationized unsaturatedC-glycosides

1993 ◽  
Vol 28 (1) ◽  
pp. 42-48 ◽  
Author(s):  
Mohamed Brakta ◽  
Brahim Chaguir ◽  
Denis Sinou ◽  
Michel Becchi ◽  
Marie Joëlle Bobenrieth ◽  
...  
Keyword(s):  
Alkali Metal ◽  
Fast Atom Bombardment ◽  
Mass Spectrometric Study ◽  
Mass Spectrometric ◽  
Spectrometric Study
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