Cerium Tetrafluoride. I. Preparation and reactions

1965 ◽  
Vol 18 (7) ◽  
pp. 959 ◽  
Author(s):  
WJ Asker ◽  
AW Wylie
Keyword(s):  
Aqueous Solution ◽  
Water Content ◽  
Water Vapour ◽  
Hydrogen Fluoride ◽  
Low Temperatures ◽  
Cerium Dioxide ◽  
Lattice Parameters ◽  
Refractive Indices ◽  
Dissociation Pressure ◽  
Cerium Trifluoride

Pure anhydrous cerium tetrafluoride is best prepared by fluorinating cerium dioxide at 350-500�. A monohydrate can be obtained from aqueous solution in a variety of ways, but it cannot be dehydrated without decomposition. It loses water "zeolitically" in vacuum, showing relatively small changes in lattice parameters for loss of 70% of its water content. Thereafter the lattice collapses, forming well-crystallized cerium trifluoride and poorly crystallized "anhydrous" cerium tetrafluoride. The refractive indices of anhydrous monoclinic cerium tetrafluoride have been measured and its fluorine dissociation pressure at 500� shown to be less than 0.5 mm. At higher temperatures the tetrafluoride sublimes incongruently, and at 835-841� it melts with extensive decomposition into a fluorine-poor liquid and a fluorine-rich vapour. Cerium tetrafluoride is easily reduced to the trifluoride by ammonia and by water vapour at low temperatures. At higher temperatures it is quantitatively converted by water vapour to cerium dioxide and hydrogen fluoride. When heated with cerium dioxide it is reduced to the trifluoride with liberation of oxygen.

scholarly journals Cold Wave-Induced Reductions in NDII and ChlRE for North-Western Pacific Mangroves Varies with Latitude and Climate History

2021 ◽  
Vol 13 (14) ◽  
pp. 2732
Author(s):  
Jonathan Peereman ◽  
J. Aaron Hogan ◽  
Teng-Chiu Lin
Keyword(s):  
Water Content ◽  
Geographic Distribution ◽  
Low Temperatures ◽  
Forest Canopy ◽  
Cold Wave ◽  
Mangrove Forests ◽  
Climate History ◽  
Wave Effects ◽  
Northern Pacific ◽  
Wave Induced

Mangrove forests growing at the poleward edges of their geographic distribution are occasionally subject to freezing (<0 °C) and cold wave (>0 °C) events. Cold wave effects on mangrove trees are well documented and adaptation to cold stress has been reported for local mangrove populations in the North Atlantic. However, there is less understanding of effects of cold waves on mangroves in the northern Pacific, especially at the regional scale. Moreover, it is unclear if cold tolerant mangrove species of North Asia display variation in resistance to cold temperatures across their geographic distribution. Using a cold wave event that occurred in January 2021, we evaluated the effects of low temperatures on vegetation index (VI) change (relative to a recent five-year baseline) for mangrove forests dominated by Kandelia obovata (Rhizophoraceae) and Avicennia marina (Acanthaceaee) at the northern edge of their geographical range. We used two VIs derived from Sentinel-2 imagery as indicators for canopy health: the normalized difference infrared index (NDII) and the chlorophyll red-edge index (ChlRE), which reflect forest canopy water content and chlorophyll concentration, respectively. We isolated the cold wave effects on the forest canopy from phenology (i.e., cold wave induced deviation from a five-year baseline) and used multiple linear regression to identify significant climatic predictors for the response of mangrove forest canopy VI change to low temperatures. For areas where the cold wave resulted in temperatures <10 °C, immediate decreases in both VIs were observed, and the VI difference relative to the baseline was generally greater at 30-days after the cold wave than when temperatures initially recovered to baseline values, showing a slight delay in VI response to cold wave-induced canopy damage. Furthermore, the two VIs did not respond consistently suggesting that cold-temperature induced changes in mangrove canopy chlorophyll and water content are affected independently or subject to differing physiological controls. Our results confirm that local baseline (i.e., recent past) climate predicts canopy resistance to cold wave damage across K. obovata stands in the northern Pacific, and in congruence with findings from New World mangroves, they imply geographic variation in mangrove leaf physiological resistance to cold for Northern Pacific mangroves.

Effects of exposure on water relations and photosynthesis of western hemlock in habitat forms

1976 ◽  
Vol 6 (1) ◽  
pp. 40-48 ◽  
Author(s):  
R. A. Keller ◽  
E. B. Tregunna
Keyword(s):  
Light Intensity ◽  
Water Content ◽  
Water Vapour ◽  
Western Hemlock ◽  
Diffusion Resistance ◽  
The Sun ◽  
Evaporative Demand ◽  
Photosynthetic Rates ◽  
Water Vapour Diffusion ◽  
Vapour Diffusion

Measurements of relative turgidity, transpiration rates, and photosynthetic rates on sun-grown and shade-grown western hemlock (Tsugaheterophylla (Raf.) Sarg.) were used to indicate effects of varying degrees of exposure.The sun-adapted form had low photosynthetic rates but maintained its water content under conditions of high evaporative demand. The shade-adapted form desiccated under exposed conditions, and in contrast with the sun-adapted form, its water vapour diffusion resistance decreased with increasing light intensity.

scholarly journals The behaviour of visual purple at low temperature

1941 ◽  
Vol 179 (977) ◽  
pp. 151-159 ◽  
Keyword(s):  
Aqueous Solution ◽  
Low Temperature ◽  
Low Temperatures ◽  
Room Temperature ◽  
Absorption Curve ◽  
Quantum Yields

Visual purple is soluble and stable in a mixture of glycerol and water (3:1). At room temperature the spectrum of such a solution is identical with that of the aqueous solution. At — 73° C the peak of the absorption curve is higher and narrower than at room temperature, and it is shifted towards longer waves. The product of photodecomposition at — 73° C has a spectrum in ­ dependent of pH and is at low temperatures thermostable and photostable, but at room temperature it decomposes therm ally to indicator yellow. The primary product appears to be identical with transient orange. The quantum yields of the photoreaction at low and at room temperature are of the same order.

scholarly journals Quality assessment of water cycle parameters in REMO by Radar-Lidar synergy

2007 ◽  
Vol 7 (3) ◽  
pp. 8455-8524
Author(s):  
B. Hennemuth ◽  
A. Weiss ◽  
J. Bösenberg ◽  
D. Jacob ◽  
H. Linné ◽  
...  
Keyword(s):  
Remote Sensing ◽  
Heat Flux ◽  
Soil Moisture ◽  
Water Content ◽  
Water Vapour ◽  
Water Cycle ◽  
Sensible Heat Flux ◽  
Regional Model ◽  
Cloud Base ◽  
Cloud Radar

Abstract. A comparison study of water cycle parameters derived from ground-based remote-sensing instruments and from the regional model REMO is presented. Observational data sets were collected during three measuring campaigns in summer/autumn 2003 and 2004 at Richard Aßmann Observatory, Lindenberg, Germany. The remote sensing instruments which were used are differential absorption lidar, Doppler lidar, ceilometer, cloud radar, and micro rain radar for the derivation of humidity profiles, ABL height, water vapour flux profiles, cloud parameters, and rain rate. Additionally, surface latent and sensible heat flux and soil moisture were measured. Error ranges and representativity of the data are discussed. For comparisons the regional model REMO was run for all measuring periods with a horizontal resolution of 18 km and 33 vertical levels. Parameter output was every hour. The measured data were transformed to the vertical model grid and averaged in time in order to better fit with gridbox model values. The comparisons show that the atmospheric boundary layer is not adequately simulated, on most days it is too shallow and too moist. This is found to be caused by a wrong partitioning of energy at the surface, particularly a too large latent heat flux. The reason is obviously an overestimation of soil moisture during drying periods by the one-layer scheme in the model. The profiles of water vapour transport within the ABL appear to be realistically simulated. The comparison of cloud cover reveals an underestimation of low-level and mid-level clouds by the model, whereas the comparison of high-level clouds is hampered by the inability of the cloud radar to see cirrus clouds above 10 km. Simulated ABL clouds apparently have a too low cloud base, and the vertical extent is underestimated. The ice water content of clouds agree in model and observation whereas the liquid water content is unsufficiently derived from cloud radar reflectivity in the present study. Rain rates are similar, but the representativeness of both observations and grid box values is low.

Water vapour pressure above saturated salt solutions at low temperatures

1999 ◽  
Vol 155 (2) ◽  
pp. 297-309 ◽  
Author(s):  
V Morillon ◽  
F Debeaufort ◽  
J Jose ◽  
J.F Tharrault ◽  
M Capelle ◽  
...  
Keyword(s):  
Water Vapour ◽  
Vapour Pressure ◽  
Low Temperatures ◽  
Water Vapour Pressure ◽  
Salt Solutions

Calculation of the X-ray powder reflection profiles of very small needle-like crystals. II. Quantitative results on eskisehir sepiolite fibers

1981 ◽  
Vol 14 (6) ◽  
pp. 451-454 ◽  
Author(s):  
A. Yücel ◽  
M. Rautureau ◽  
D. Tchoubar ◽  
C. Tchoubar
Keyword(s):  
Water Content ◽  
Calculation Method ◽  
Lattice Parameters ◽  
Boundary Effects ◽  
Cross Sectional ◽  
X Ray ◽  
Hydration State ◽  
Quantitative Results ◽  
Small Needle

A calculation method for the X-ray profiles from small, needle-like crystallites [Yücel, Rautureau, Tchoubar & Tchoubar (1980). J. Appl. Cryst. 13, 370–374] is applied to natural Eskisehir sepiolite mineral. By analysing the hk0 reflections, quantitative results are given on the average cross-sectional dimensions, their distribution, preferred directions of growth, lattice parameters, hydration state, and imperfections. Practical methods for the determination of the zeolitic water content and the importance of boundary effects are proposed.

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