Electrode surface concentrations for mixed transfer processes: transfer by diffusion and chemical reaction for a plane electrode

1964 ◽  
Vol 17 (1) ◽  
pp. 16 ◽  
Author(s):  
CM Groden ◽  
GH Aylward ◽  
JW Hayes
Keyword(s):  
Electron Transfer ◽  
Chemical Reaction ◽  
Electrode Surface ◽  
Transfer Reaction ◽  
Electron Transfer Reaction ◽  
Transfer Processes ◽  
Plane Electrode ◽  
Reversible Electron Transfer ◽  
Irreversible Chemical Reaction

An expression has been derived and tables computed for the concentration of oxidant and reductant at the electrode surface as a function of time and polarizing potential in the case where an irreversible chemical reaction follows a reversible electron transfer reaction under the conditions of a somewhat idealized polarographic system.

Surface concentrations for a mixed transfer process at an expanding spherical electrode

1966 ◽  
Vol 19 (6) ◽  
pp. 923 ◽  
Author(s):  
CM Gorden ◽  
RF Matlak
Keyword(s):  
Electron Transfer ◽  
Chemical Reaction ◽  
Transfer Process ◽  
Transfer Reaction ◽  
Electron Transfer Reaction ◽  
Spherical Electrode ◽  
Reversible Electron Transfer ◽  
Irreversible Chemical Reaction

An expression has been derived for the concentration of oxidant and reductant at the surface of an expanding spherical electrode as a function of time and the polarizing potential in the case where a slow irreversible chemical reaction follows a reversible electron transfer reaction under the conditions of a somewhat idealized polarographic system.

Network Simulation of a Reversible Electron Transfer under Cyclic Voltammetric Conditions

1992 ◽  
Vol 57 (7) ◽  
pp. 1373-1380 ◽  
Author(s):  
Carlos F. González-Fernández ◽  
Maria T. García-Hernández ◽  
José Horno
Keyword(s):  
Electron Transfer ◽  
Transfer Reaction ◽  
Circuit Simulation ◽  
Computer Time ◽  
Electron Transfer Reaction ◽  
Great Accuracy ◽  
Electrical Circuit ◽  
Cyclic Voltammetric ◽  
Reversible Electron Transfer ◽  
Moderate Cost

Reversible electron transfer reaction of a freely diffusing species has been studied using the network approach. A network model for this process under cyclic voltammetric conditions has been proposed, and a numerical simulation has been made with the help of the electrical circuit simulation routine PSPICE. A great accuracy in simulated voltammograms has been reached with a personal computer at a moderate cost in computer time.

Reversible Electron Transfer Reaction between Polyaniline and Thiol/Disulfide Couples

1996 ◽  
Vol 100 (33) ◽  
pp. 14016-14021 ◽  
Author(s):  
Tetsu Tatsuma ◽  
Hiroshi Matsui ◽  
Eiichi Shouji ◽  
Noboru Oyama
Keyword(s):  
Electron Transfer ◽  
Transfer Reaction ◽  
Electron Transfer Reaction ◽  
Reversible Electron Transfer
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