scholarly journals A carbonato complex of Molybdenum K6Mo(CO3)5.2H2O

1957 ◽  
Vol 10 (3) ◽  
pp. 367 ◽  
Author(s):  
MC Steele
Keyword(s):  
2013 ◽  
Vol 2013 ◽  
pp. 1-4 ◽  
Author(s):  
Nguyen Duc Van

The synthesis and structural properties of lead-free piezoelectric (K0.5Na0.5)NbO3powders prepared by mechanochemical method using Nb2O5, K2CO3, and Na2CO3as starting materials were reported. X-ray diffraction, infrared spectroscopy, Raman spectroscopy, and scanning electron microscopy were used to characterize the prepared samples. Results showed that, for the first time, by selecting the milling speed of 600 rpm and the ball-to-powder weight ratio of 35 : 1 as milling parameters, pure (K0.5Na0.5)NbO3crystalline phase was obtained directly in the as-milled samples after 5 h of milling time. The existence of a carbonato complex betweenCO32−and Nb5+ions as an intermediate species of the formation of (K0.5Na0.5)NbO3was also found.


2015 ◽  
Vol 306 (3) ◽  
pp. 761-768 ◽  
Author(s):  
Dong-Yong Chung ◽  
Min-Sung Park ◽  
Keun-Young Lee ◽  
Eil-Hee Lee ◽  
Kwang-Wook Kim ◽  
...  

1981 ◽  
Vol 20 (2) ◽  
pp. 376-381 ◽  
Author(s):  
Melvyn Rowen. Churchill ◽  
Romana A. Lashewycz ◽  
Kanayuthu. Koshy ◽  
Tara P. Dasgupta

2012 ◽  
Vol 233-234 ◽  
pp. 213-218 ◽  
Author(s):  
Kwang-Wook Kim ◽  
Keun-Young Lee ◽  
Dong-Yong Chung ◽  
Eil-Hee Lee ◽  
Jei-Kwon Moon ◽  
...  

2006 ◽  
Vol 177 (33-34) ◽  
pp. 2987-2995 ◽  
Author(s):  
T ROJAC ◽  
M KOSEC ◽  
P SEGEDIN ◽  
B MALIC ◽  
J HOLC

2006 ◽  
Vol 70 (1) ◽  
pp. 348-355 ◽  
Author(s):  
Corey R. Centerwall ◽  
Kirk A. Tacka ◽  
Deborah J. Kerwood ◽  
Jerry Goodisman ◽  
Bonnie B. Toms ◽  
...  

1978 ◽  
Vol 32 (5) ◽  
pp. 486-488 ◽  
Author(s):  
E. Koglin ◽  
H. J. Schenk ◽  
K. Schwochau

Brown coal removes uranium from sea water where it is present mainly as [UO2(CO3)3]4−. The adsorption and binding of uranium is studied by infrared spectroscopy. The spectra of the coal-uranium adducts still exhibit the asymmetric stretching vibration of the uranyl ion, but no CO32− frequencies, suggesting that uranium is retained as UO22+. The coal humic acids are shown to be responsible for the decomposition of the carbonato complex. The subsequent uptake of uranium is not a pure cation exchange process since the shift of the asymmetric uranyl stretching frequency from 950 cm−1 (hydrated UO22+) to 890 cm−1 points to complexation of UO22+ by carboxylate groups which act as bidentate ligands.


Nature ◽  
1967 ◽  
Vol 216 (5116) ◽  
pp. 681-682 ◽  
Author(s):  
R. D. CANNON ◽  
J. L. TSAY
Keyword(s):  

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