scholarly journals Substance Abuse: Carbon Tetrachloride and the Ozone Layer

2016 ◽  
Vol 69 (12) ◽  
pp. 1375 ◽  
Author(s):  
Ian D. Rae
Keyword(s):  
Substance Abuse ◽  
Infrared Spectroscopy ◽  
Carbon Tetrachloride ◽  
Montreal Protocol ◽  
Upper Atmosphere ◽  
Oil And Grease ◽  
Standard Methods ◽  
Annual Basis ◽  
Ozone Depleting Substance ◽  
The Subject

Each year, ~200000 tonnes of carbon tetrachloride are produced and consumed as a solvent, a starting material for synthesis, or in standard methods of analysis. Because it is an ozone-depleting substance, this information is reported on an annual basis to the Montreal Protocol, under which it is a ‘controlled’ substance. Replacing emissive uses of carbon tetrachloride with ozone-friendly chemicals is proceeding slowly. One example is the use of tetrachloroethylene as a replacement for carbon tetrachloride in oil and grease analysis by infrared spectroscopy. Overall, however, there is more carbon tetrachloride in the upper atmosphere than can be accounted for in terms of known uses and emissions. The discrepancy is the subject of intensive and repeated investigation by atmospheric scientists.

scholarly journals Continued Emissions of the Ozone‐Depleting Substance Carbon Tetrachloride From Eastern Asia

2018 ◽  
Vol 45 (20) ◽  
Author(s):  
M. F. Lunt ◽  
S. Park ◽  
S. Li ◽  
S. Henne ◽  
A. J. Manning ◽  
...  
Keyword(s):  
Carbon Tetrachloride ◽  
Eastern Asia ◽  
Ozone Depleting Substance

Noninvasive measurement of forearm blood flow and oxygen consumption by near-infrared spectroscopy

1994 ◽  
Vol 76 (3) ◽  
pp. 1388-1393 ◽  
Author(s):  
R. A. De Blasi ◽  
M. Ferrari ◽  
A. Natali ◽  
G. Conti ◽  
A. Mega ◽  
...  
Keyword(s):  
Blood Flow ◽  
Oxygen Consumption ◽  
Infrared Spectroscopy ◽  
Near Infrared Spectroscopy ◽  
Healthy Subjects ◽  
Near Infrared ◽  
Forearm Blood Flow ◽  
Vascular Occlusion ◽  
Venous Occlusion ◽  
The Subject

We applied near-infrared spectroscopy (NIRS) for the simultaneous measurement of forearm blood flow (FBF) and oxygen consumption (VO2) in the human by inducing a 50-mmHg venous occlusion. Eleven healthy subjects were studied both at rest and after hand exercise during vascular occlusion. FBF was also measured by strain-gauge plethysmography. FBF measured by NIRS was 1.9 +/- 0.8 ml.100 ml-1.min-1 at rest and 8.2 +/- 2.9 ml.100 ml-1.min-1 after hand exercise. These values showed a correlation (r = 0.94) with those obtained by the plethysmography. VO2 values were 4.6 +/- 1.3 microM O2 x 100 ml-1.min-1 at rest and 24.9 +/- 11.2 microM O2 x 100 ml-1.min-1 after hand exercise. The scatter of the FBF and VO2 values showed a good correlation between the two variables (r = 0.93). The results demonstrate that NIRS provides the particular advantage of obtaining the contemporary evaluation of blood flow and VO2, allowing correlation of these two variables by a single maneuver without discomfort for the subject.

scholarly journals Model sensitivity studies of the decrease in atmospheric carbon tetrachloride

2016 ◽  
Vol 16 (24) ◽  
pp. 15741-15754 ◽  
Author(s):  
Martyn P. Chipperfield ◽  
Qing Liang ◽  
Matthew Rigby ◽  
Ryan Hossaini ◽  
Stephen A. Montzka ◽  
...  
Keyword(s):  
Carbon Tetrachloride ◽  
Transport Model ◽  
Three Dimensional ◽  
Montreal Protocol ◽  
Chemical Transport Model ◽  
Uncertainty Range ◽  
The Past ◽  
Systematic Biases ◽  
Lifetime Uncertainty ◽  
The Impact

Abstract. Carbon tetrachloride (CCl4) is an ozone-depleting substance, which is controlled by the Montreal Protocol and for which the atmospheric abundance is decreasing. However, the current observed rate of this decrease is known to be slower than expected based on reported CCl4 emissions and its estimated overall atmospheric lifetime. Here we use a three-dimensional (3-D) chemical transport model to investigate the impact on its predicted decay of uncertainties in the rates at which CCl4 is removed from the atmosphere by photolysis, by ocean uptake and by degradation in soils. The largest sink is atmospheric photolysis (74 % of total), but a reported 10 % uncertainty in its combined photolysis cross section and quantum yield has only a modest impact on the modelled rate of CCl4 decay. This is partly due to the limiting effect of the rate of transport of CCl4 from the main tropospheric reservoir to the stratosphere, where photolytic loss occurs. The model suggests large interannual variability in the magnitude of this stratospheric photolysis sink caused by variations in transport. The impact of uncertainty in the minor soil sink (9 % of total) is also relatively small. In contrast, the model shows that uncertainty in ocean loss (17 % of total) has the largest impact on modelled CCl4 decay due to its sizeable contribution to CCl4 loss and large lifetime uncertainty range (147 to 241 years). With an assumed CCl4 emission rate of 39 Gg year−1, the reference simulation with the best estimate of loss processes still underestimates the observed CCl4 (overestimates the decay) over the past 2 decades but to a smaller extent than previous studies. Changes to the rate of CCl4 loss processes, in line with known uncertainties, could bring the model into agreement with in situ surface and remote-sensing measurements, as could an increase in emissions to around 47 Gg year−1. Further progress in constraining the CCl4 budget is partly limited by systematic biases between observational datasets. For example, surface observations from the National Oceanic and Atmospheric Administration (NOAA) network are larger than from the Advanced Global Atmospheric Gases Experiment (AGAGE) network but have shown a steeper decreasing trend over the past 2 decades. These differences imply a difference in emissions which is significant relative to uncertainties in the magnitudes of the CCl4 sinks.

scholarly journals Grease Quality Issues on Middle Voltage Switchgear: Corrosivity, Resistivity, Safety and Ageing

2019 ◽  
Vol 20 (1) ◽  
pp. 216-228
Author(s):  
Mohd Sabri Mahmud ◽  
Sanuri Ishak ◽  
Mohd Najib Razali ◽  
Mohd Aizudin Abdul Aziz ◽  
Musfafikri Musa
Keyword(s):  
Gas Chromatography ◽  
Infrared Spectroscopy ◽  
Electrochemical Reaction ◽  
Chemical Change ◽  
Copper Corrosion ◽  
Standard Methods ◽  
Dropping Point ◽  
Physical Tests ◽  
Common Problems ◽  
Quality Issues

Grease products recommended by OEM for conventional 11kV switchgears are generally trusted. Some disadvantages might however exist among them or their supply could be insufficient and lead to use of non-OEM-recommended grease. This paper reports analysis methods to evaluate both types of grease that were recently used in the switchgears at local electrical distribution stations owned by Tenaga Nasional Berhad. Hardened, greenish and severely irritating greases probably caused by incompatible compounding, electrochemical reaction, and hazardous components, respectively, were among common problems faced by workers. Eight physical tests and four chemical tests were conducted on 10 grease samples using thermogravimetry, switchgear rig, gas chromatography and infrared spectroscopy besides other equipment and standard methods. Grease stability, oil bleeding, flammability of grease droplet and dropping point were among the characteristics determined in the analyses. The results reveal copper corrosion, chemical change, instable and inconsistent grease, and toxics in grease, which surprisingly included the OEM-recommended one. ABSTRAK: Produk gris yang disyorkan oleh Pengeluar Peralatan Asal (OEM) bagi gear-suis konvensional 11 kV secara umumnya dipercayai ramai. Kemungkinan terdapat kekurangan pada produk-produk tersebut ataupun bekalan gris mereka yang tidak mencukupi telah mendorong kepada penggunaan gris yang tidak disyorkan oleh OEM. Kaedah analisis kajian ini melaporkan tentang kedua-dua jenis gris yang kebelakangan ini digunakan oleh Tenaga Nasional Berhad pada gear-suis di stesen pencawang elektrik. Gris mengeras, berlumut dan menjengkelkan mungkin disebabkan oleh sebatian bahan yang tidak sesuai, tindak balas elektrokimia dan komponen yang tidak selamat, masing-masing adalah antara masalah yang dihadapi oleh para pekerja. Lapan ujian fizikal dan empat ujian kimia telah dijalankan pada 10 sampel gris menggunakan termogravimetri, pemakai gear-suis, kromatografi gas dan spektroskopi inframerah selain alatan lain dan kaedah-kaedah piawai. Antara ciri-ciri yang dikaji dalam analisis ini adalah kestabilan gris, sifat lelehan minyak, sifat mudah terbakar titisan gris dan takat rendah gris. Hasil kajian mendapati gris ini menyebabkan tembaga terhakis, sifat kimia berubah, sifat gris yang tidak stabil dan mudah berubah, dan juga beracun memberi kejutan kerana pihak OEM tetap mengesyorkan gris jenis ini.

scholarly journals Emissions of Carbon Tetrachloride (CCl<sub>4</sub>) from Europe

2016 ◽  
Author(s):  
Francesco Graziosi ◽  
Jgor Arduini ◽  
Paolo Bonasoni ◽  
Francesco Furlani ◽  
Umberto Giostra ◽  
...  
Keyword(s):  
Carbon Tetrachloride ◽  
Large Scale ◽  
Stratospheric Ozone ◽  
Montreal Protocol ◽  
Scale Production ◽  
Top Down ◽  
Significant Discrepancy ◽  
Bottom Up ◽  
Atmospheric Observations ◽  
Global Emissions

Abstract. Carbon tetrachloride (CCl4) is a long-lived radiatively-active compound able to destroy stratospheric ozone. Due to its inclusion in the Montreal Protocol on Substances that Deplete the Ozone Layer, the last two decades have seen a sharp decrease in its large scale emissive use with a consequent decline of its atmospheric mole fractions. However, the Montreal Protocol restrictions do not apply to the use of carbon tetrachloride as feedstock for the production of other chemicals, implying the risk of fugitive emissions from the industry sector. The occurrence of such unintended emissions is suggested by a significant discrepancy between global emissions as derived by reported production and feedstock usage (bottom-up emissions), and those based on atmospheric observations (top-down emissions). In order to better constrain the atmospheric budget of carbon tetrachloride, several studies based on a combination of atmospheric observations and inverse modelling have been conducted in recent years in various regions of the world. This study is focused on the European scale and based on long-term high-frequency observations at three European sites, combined with a Bayesian inversion methodology. We estimated that average European emissions for 2006–2014 were 2.3 (± 0.8) Gg yr−1, with an average decreasing trend of 7.3 % per year. Our analysis identified France as the main source of emissions over the whole study period, with an average contribution to total European emissions of 25 %. The inversion was also able to allow the localisation of emission "hot-spots" in the domain, with major source areas in Southern France, Central England (UK) and Benelux (Belgium, The Netherlands, Luxembourg), where most of industrial scale production of basic organic chemicals are located. According to our results, European emissions correspond to 4.0 % of global emissions for 2006–2012. Together with other regional studies, our results allow a better constraint of the global budget of carbon tetrachloride and a better quantification of the gap between top-down and bottom-up estimates.

scholarly journals Perfusion Changes at the Forehead Measured by Photoplethysmography during a Head-Down Tilt Protocol

Biosensors ◽  
2019 ◽  
Vol 9 (2) ◽  
pp. 71
Author(s):  
Tomas Ysehak Abay ◽  
Kamran Shafqat ◽  
Panayiotis A. Kyriacou
Keyword(s):  
Infrared Spectroscopy ◽  
Near Infrared Spectroscopy ◽  
Near Infrared ◽  
Arterial Oxygen Saturation ◽  
Venous Blood ◽  
Arterial Oxygen ◽  
Large Variability ◽  
Large Vein ◽  
The Subject ◽  
Induced Changes

Photoplethysmography (PPG) signals from the forehead can be used in pulse oximetry as they are less affected by vasoconstriction compared to fingers. However, the increase in venous blood caused by the positioning of the patient can deteriorate the signals and cause erroneous estimations of the arterial oxygen saturation. To date, there is no method to measure this venous presence under the PPG sensor. This study investigates the feasibility of using PPG signals from the forehead in an effort to estimate relative changes in haemoglobin concentrations that could reveal these posture-induced changes. Two identical reflectance PPG sensors were placed on two different positions on the forehead (above the eyebrow and on top of a large vein) in 16 healthy volunteers during a head-down tilt protocol. Relative changes in oxygenated ( Δ HbO 2 ), reduced ( Δ HHb) and total ( Δ tHb) haemoglobin were estimated from the PPG signals and the trends were compared with reference Near Infrared Spectroscopy (NIRS) measurements. Also, the signals from the two PPG sensors were analysed in order to reveal any difference due to the positioning of the sensor. Δ HbO 2 , Δ HHb and Δ tHb estimated from the forehead PPGs trended well with the same parameters from the reference NIRS. However, placing the sensor over a large vasculature reduces trending against NIRS, introduces biases as well as increases the variability of the changes in Δ HHb. Forehead PPG signals can be used to measure perfusion changes to reveal venous pooling induced by the positioning of the subject. Placing the sensor above the eyebrow and away from large vasculature avoids biases and large variability in the measurements.

A Review of Process near Infrared Spectroscopy: 1980–1994

1993 ◽  
Vol 1 (4) ◽  
pp. 221-245 ◽  
Author(s):  
Jerry Workman
Keyword(s):  
Infrared Spectroscopy ◽  
Near Infrared Spectroscopy ◽  
Literature Search ◽  
Near Infrared ◽  
Process Analysis ◽  
The State ◽  
Chronological Order ◽  
Measurement Scheme ◽  
The Subject

For this review, papers on NIR process analysis were categorised according to their overall configuration and measurement scheme. This analyser taxonomy was chosen to demonstrate the state of the current use of process analyser terms and to allow the reader to access a broad range of applications by referring to the specific measuring characteristics of the analyser. The basis for this review was a literature search covering the period from January 1980 to January 1994 on the subject of Process NIR and FT-NIR analysis. Each section is in chronological order to allow the reader to observe the development (and refinement) of process NIR from 1980 to the present.

Hydration of Short-chain Poly(oxyethylene)s in Carbon Tetrachloride Studied by Infrared Spectroscopy

2003 ◽  
Vol 32 (2) ◽  
pp. 122-123 ◽  
Author(s):  
Hiroatsu Matsuura ◽  
Md. Ruhul Matin ◽  
Koji Okura
Keyword(s):  
Infrared Spectroscopy ◽  
Carbon Tetrachloride ◽  
Short Chain
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