The Effects of SiO2 and CeO2 Addition on the Performances of MnOx/TiO2 Catalysts

2016 ◽  
Vol 69 (10) ◽  
pp. 1180
Author(s):  
Juhua Luo ◽  
Hongkai Mao ◽  
Xu Wang ◽  
Wei Yao
Keyword(s):  
Low Temperature ◽  
Pore Diameter ◽  
Catalytic Reduction ◽  
Pure Tio2 ◽  
Precipitation Method ◽  
Impregnation Method ◽  
Average Pore ◽  
Reduction Of No ◽  
No Conversion ◽  
Co Precipitation

A TiO2-SiO2 mixed oxide was obtained by a co-precipitation method. MnOx-CeO2/TiO2-SiO2 were prepared by an impregnation method and their activity towards the selective catalytic reduction of NO with NH3 at low temperature were evaluated. Compared with pure TiO2, TiO2-SiO2 exhibited an evidently larger surface area and pore volume, and a smaller average pore diameter with narrow distribution. The NO conversion of the MnOx/TiO2-SiO2 catalyst could be improved by the addition of an appropriate amount of CeO2 in the temperature range of 100–180°C. MnOx-CeO2/TiO2-SiO2 with 10 wt-% CeO2 showed the highest activity with 96 % NO conversion at 180°C.

A Ce-Zr-Ti Oxide Catalyst for Selective Catalytic Reduction of NO with Ammonia

2014 ◽  
Vol 535 ◽  
pp. 709-712
Author(s):  
Ye Jiang ◽  
Yan Yan ◽  
Shan Bo Huang ◽  
Xiong Zhang ◽  
Xin Wei Wang ◽  
...  
Keyword(s):  
High Activity ◽  
Selective Catalytic Reduction ◽  
Oxide Catalyst ◽  
Catalytic Reduction ◽  
Space Velocity ◽  
Impregnation Method ◽  
Reduction Of No ◽  
No Conversion ◽  
Temperature Range ◽  
Ti Oxides

A Ce-Zr-Ti oxide catalyst was prepared by an impregnation method and tested for the selective catalytic reduction of NO with NH3. The Ce-Zr-Ti oxide catalyst exhibited high activity and more than 95% NO conversion was obtained within the temperature range 300-500 °C at the high gas hourly space velocity of 50,000 h-1. The addition of Zr improved the activity of Ce-Ti oxides especially at higher reaction temperatures and their resistance to SO2.

Highly dispersed Fe2O3 on carbon nanotubes for low-temperature selective catalytic reduction of NO with NH3

2015 ◽  
Vol 51 (5) ◽  
pp. 956-958 ◽  
Author(s):  
Zhenping Qu ◽  
Lei Miao ◽  
Hui Wang ◽  
Qiang Fu
Keyword(s):  
Carbon Nanotubes ◽  
Low Temperature ◽  
Selective Catalytic Reduction ◽  
Low Temperatures ◽  
Catalytic Reduction ◽  
Reduction Of No ◽  
No Conversion ◽  
Highly Dispersed

Highly dispersed Fe2O3 nanoparticles supported on CNTs showed excellent NO conversion, selectivity and durability towards SO2/H2O at low temperatures (200–325 °C).

scholarly journals Physicochemical and Catalytic Properties of Vanadia/Titania Catalysts. V. Selective Catalytic Reduction of NO with NH3

2002 ◽  
Vol 20 (10) ◽  
pp. 937-945
Author(s):  
Th. El-Nabarawy ◽  
M.N. Alaya ◽  
S.A. Sayed Ahmed ◽  
A.M. Youssef
Keyword(s):  
Selective Catalytic Reduction ◽  
Catalytic Properties ◽  
Catalytic Reduction ◽  
Impregnation Method ◽  
Reduction Of No ◽  
No Conversion ◽  
Scr Of No ◽  
Monolayer Coverage

Vanadia/titania catalysts were prepared containing 6.0 or 8.0 wt% V2O5 via the impregnation method. The samples as prepared were calcined at 400°C or 600°C, respectively. Selective catalytic reduction (SCR) of NO with NH3 was carried out at 257°C over the prepared catalysts. NO conversion as a function of time was followed and the stationary conversion versus the amount of catalyst employed was also investigated. It was found that the vanadia/titania catalysts calcined at 400°C were more active in the SCR of NO with NH3 relative to those calcined at 600°C. This was attributed to such catalysts possessing complete monolayer coverage of vanadia on the titania substrate. It was established that V5+ was not the active vanadia species but V4+ and V3+ may act as such for the SCR of NO with NH3.

Selective catalytic reduction of NO with NH3 over novel iron–tungsten mixed oxide catalyst in a broad temperature range

2015 ◽  
Vol 5 (9) ◽  
pp. 4556-4564 ◽  
Author(s):  
Xiang Li ◽  
Junhua Li ◽  
Yue Peng ◽  
Tao Zhang ◽  
Shuai Liu ◽  
...  
Keyword(s):  
Selective Catalytic Reduction ◽  
Mixed Oxide ◽  
Oxide Catalyst ◽  
Catalytic Reduction ◽  
Precipitation Method ◽  
Reduction Of No ◽  
Molar Ratios ◽  
Scr Of No ◽  
Mixed Oxide Catalyst ◽  
Co Precipitation

A series of novel FeW(x) catalysts with different Fe/W molar ratios prepared by the co-precipitation method were investigated in the selective catalytic reduction (SCR) of NOx with NH3.

Studies on the Preparation and DeNOx Performance of MnxOy/CNTs Catalyst for Low-Temperature Selective Catalytic Reduction

2013 ◽  
Vol 798-799 ◽  
pp. 231-234 ◽  
Author(s):  
Bing Nan Ren ◽  
Qiao Wen Yang
Keyword(s):  
Low Temperature ◽  
Selective Catalytic Reduction ◽  
Oxide Catalyst ◽  
Catalytic Reduction ◽  
Space Velocity ◽  
Impregnation Method ◽  
Active Components ◽  
Reaction Conditions ◽  
No Conversion ◽  
Scr Of No

The metal oxide catalyst was prepared by loading MnxOyon carbon nanotubes (CNTs) with impregnation method. Then the catalyst was characterized by BET, TEM and XPS, and the catalytic activity of the catalyst for selective catalytic reduction (SCR) of NO at low-temperature was investigated. The results showed that the species of active components loaded on the catalyst were MnO2and Mn2O3. The NO conversion was improved with reduction temperature increase under 250°C, increased slowly over 250°C. The O2content had an outstanding effect on NO conversion of catalysts at a low concentration range. Once the oxygen content was enhanced over 5%, there was no significant increase in the NO conversion. With the increasing of space velocity, the NO conversion rate was decreased under the reaction conditions.

Effect of Cerium on Manganese Base Catalysts by Co-Precipitation for Low-Temperature SCR of NO with NH3

2014 ◽  
Vol 633 ◽  
pp. 121-124 ◽  
Author(s):  
Liang Jing Zhang ◽  
Su Ping Cui ◽  
Hong Xia Guo ◽  
Xiao Yu Ma ◽  
Xiao Gen Luo
Keyword(s):  
Catalytic Activity ◽  
Low Temperature ◽  
Selective Catalytic Reduction ◽  
Catalytic Reduction ◽  
Precipitation Method ◽  
Base Catalysts ◽  
Nox Conversion ◽  
Scr Of No ◽  
Co Precipitation ◽  
Low Temperature Scr

Catalysts of Mn/TiO2 and Mn-Ce /TiO2 prepared by co-precipitation method for low temperature selective catalytic reduction (SCR) of NO with NH3 were investigated in this study. The experimental results showed that co-precipitation method after improvement, the NO conversion of Mn-Ce/TiO2 catalyst increased sharply. Meanwhile, the addition of cerium has significant effects on the catalytic activity. Characterizations of catalysts were carried out by XRD, BET and H2-TPR. The characterized results indicated that co-precipitation method after improvement, in temperature windows 150 to 300 °C, showed higher NOx conversion.

Influence of Fe Doping on Ce-Mn/TiO2-ZrO2 Catalysts for Low-Temperature Selective Catalytic Reduction of NO

2014 ◽  
Vol 898 ◽  
pp. 447-451 ◽  
Author(s):  
Yun Xiao Teng ◽  
Cun Yi Song ◽  
Xi Ning Lu ◽  
Zhen Song Tong ◽  
Yu San Qin
Keyword(s):  
Low Temperature ◽  
Selective Catalytic Reduction ◽  
Catalytic Reduction ◽  
Sol Gel ◽  
Molar Ratio ◽  
Fe Doping ◽  
Reduction Of No ◽  
No Conversion ◽  
Scr Of No ◽  
Fe Catalysts

Fe-Ce-Mn catalysts loaded on TiO2-ZrO2materials were prepared by sol-gel method and then were investigated for low temperature selective catalytic reduction (SCR) of NO with NH3. It was found that the NO conversions over Fe-Ce-Mn/TiO2-ZrO2was slightly improved compared with that over Ce-Mn/TiO2-ZrO2. The results showed that 96% NO conversion was obtained over Fe-Ce-Mn/TiO2-ZrO2with the molar ratio of Fe/Mn=0.3. A comparative study of Fe-Ce-Mn/TiO2- ZrO2and Ce-Mn/TiO2-ZrO2for NO conversions at 140°C in the presence of H2O and SO2proved that Fe-Ce-Mn/TiO2-ZrO2exhibited higher resistance to H2O and SO2than that of without Fe catalysts. In addition, Fe-Ce-Mn/TiO2-ZrO2presented 90.49% NO conversion after cutting off the injection of SO2and H2O.

Synthesis of nanosphere TiO2 with flower-like micro-composition and its application for the selective catalytic reduction of NO with NH3 at low temperature

RSC Advances ◽  
2016 ◽  
Vol 6 (87) ◽  
pp. 84294-84308 ◽  
Author(s):  
Hong Wang ◽  
Kasha Cai ◽  
Jixing Liu ◽  
Xiangjun Zhang ◽  
Yan Li ◽  
...  
Keyword(s):  
Low Temperature ◽  
Selective Catalytic Reduction ◽  
Solvothermal Method ◽  
Catalytic Reduction ◽  
Impregnation Method ◽  
Reduction Of No

TiO2 nanospheres consisting of flower-like nanopowders were synthesized by a solvothermal method, and Cu/TiO2(T) catalysts were prepared via an impregnation method.

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