Polymer Complexation by Hydrogen Bonding at the Interface
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Polymer complexes can form in the bulk and at interfaces. Polymer complex formation in the bulk has been studied for a long time. The recently developed layer-by-layer assembly technique well realizes polymer complexation at interfaces. The layer-by-layer assembly of polymers based on Coulomb forces or hydrogen bonding is a repeated complexation process conducted at a surface. This paper reviews both single (once only) and repeatable interfacial complexation by hydrogen bonding, the available hydrogen bonding pairs for complexation, the thermodynamics and kinetics of complexation, and construction schemes.
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2004 ◽
Vol 364
(1-2)
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pp. 324-332
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2019 ◽
Vol 16
(3)
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pp. 857-868
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2012 ◽
Vol 258
(14)
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pp. 5312-5318
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