Chemical Approaches in Processing Wheat Gluten-Based Polymer Materials

2014 ◽  
Vol 67 (1) ◽  
pp. 6 ◽  
Author(s):  
Xiaoqing Zhang

Processing wheat gluten-based renewable and biodegradable polymer materials through chemical modifications has been demonstrated as an effective way to improve the mechanical strength and modulus, material flexibility, barrier properties, and thermal processability, and to introduce new functionalities. Challenges still remain in further enhancing material properties, balancing hydrophilicity/hydrophobicity and biodegradability in the material, achieving a designed performance, and maintaining the material sustainability. A good understanding of protein structures, reactivity, and functionalities of wheat gluten is fundamental for such research and development, and a close collaboration between bio-chemists, polymer chemists, and material scientists is necessary for the approach.

2020 ◽  
Vol 67 (2) ◽  
pp. 115-120
Author(s):  
Raisa A. Alekhina ◽  
Victoriya E. Slavkina ◽  
Yuliya A. Lopatina

The article presents options for recycling polymers. The use of biodegradable materials is promising. This is a special class of polymers that can decompose under aerobic or anaerobic conditions under the action of microorganisms or enzymes forming natural products such as carbon dioxide, nitrogen, water, biomass, and inorganic salts. (Research purpose) The research purpose is in reviewing biodegradable materials that can be used for the manufacture of products used in agriculture. (Materials and methods) The study are based on open information sources containing information about biodegradable materials. Research methods are collecting, studying and comparative analysis of information. (Results and discussion) The article presents the advantages and disadvantages of biodegradable materials, mechanical properties of the main groups of biodegradable polymers. The article provides a summary list of agricultural products that can be made from biodegradable polymer materials. It was found that products from the general group are widely used in agriculture. Authors have found that products from a special group can only be made from biodegradable polymers with a controlled decomposition period in the soil, their use contributes to increasing the productivity of crops. (Conclusions) It was found that biodegradable polymer materials, along with environmental safety, have mechanical properties that allow them producing products that do not carry significant loads during operation. We have shown that the creation of responsible products (machine parts) from biodegradable polymers requires an increase in their strength properties, which is achievable by creating composites based on them. It was found that the technological complexity of their manufacture and high cost are the limiting factors for the widespread use of biodegradable polymers at this stage.


2020 ◽  
Vol 9 (1) ◽  
pp. 700-715 ◽  
Author(s):  
Wei Jian ◽  
David Hui ◽  
Denvid Lau

AbstractRecent advances in biomedicine largely rely on the development in nanoengineering. As the access to unique properties in biomaterials is not readily available from traditional techniques, the nanoengineering becomes an effective approach for research and development, by which the performance as well as the functionalities of biomaterials has been greatly improved and enriched. This review focuses on the main materials used in biomedicine, including metallic materials, polymers, and nanocomposites, as well as the major applications of nanoengineering in developing biomedical treatments and techniques. Research that provides an in-depth understanding of material properties and efficient enhancement of material performance using molecular dynamics simulations from the nanoengineering perspective are discussed. The advanced techniques which facilitate nanoengineering in biomedical applications are also presented to inspire further improvement in the future. Furthermore, the potential challenges of nanoengineering in biomedicine are evaluated by summarizing concerned issues and possible solutions.


Polymers ◽  
2021 ◽  
Vol 13 (16) ◽  
pp. 2588
Author(s):  
Mansuri M. Tosif ◽  
Agnieszka Najda ◽  
Aarti Bains ◽  
Grażyna Zawiślak ◽  
Grzegorz Maj ◽  
...  

In recent years, scientists have focused on research to replace petroleum-based components plastics, in an eco-friendly and cost-effective manner, with plant-derived biopolymers offering suitable mechanical properties. Moreover, due to high environmental pollution, global warming, and the foreseen shortage of oil supplies, the quest for the formulation of biobased, non-toxic, biocompatible, and biodegradable polymer films is still emerging. Several biopolymers from varied natural resources such as starch, cellulose, gums, agar, milk, cereal, and legume proteins have been used as eco-friendly packaging materials for the substitute of non-biodegradable petroleum-based plastic-based packaging materials. Among all biopolymers, starch is an edible carbohydrate complex, composed of a linear polymer, amylose, and amylopectin. They have usually been considered as a favorite choice of material for food packaging applications due to their excellent forming ability, low cost, and environmental compatibility. Although the film prepared from bio-polymer materials improves the shelf life of commodities by protecting them against interior and exterior factors, suitable barrier properties are impossible to attain with single polymeric packaging material. Therefore, the properties of edible films can be modified based on the hydrophobic–hydrophilic qualities of biomolecules. Certain chemical modifications of starch have been performed; however, the chemical residues may impart toxicity in the food commodity. Therefore, in such cases, several plant-derived polymeric combinations could be used as an effective binary blend of the polymer to improve the mechanical and barrier properties of packaging film. Recently, scientists have shown their great interest in underutilized plant-derived mucilage to synthesize biodegradable packaging material with desirable properties. Mucilage has a great potential to produce a stable polymeric network that confines starch granules that delay the release of amylose, improving the mechanical property of films. Therefore, the proposed review article is emphasized on the utilization of a blend of source and plant-derived mucilage for the synthesis of biodegradable packaging film. Herein, the synthesis process, characterization, mechanical properties, functional properties, and application of starch and mucilage-based film are discussed in detail.


1992 ◽  
Vol 264 ◽  
Author(s):  
Y.H. Jeng ◽  
Mirng-Ji Lii

AbstractA laser based surface scanning technique was utilized to measure the polyimide coated silicon wafer curvature resulting from thermal cycling and mismatch, Meanwhile, mechanical properties of polyimide thin film were characterized by DMA, TMA and tensile test. Based on the obtained material properties, A FEA model was developed to analyze the experimental results -reasonable correlation was obtained.Similar approaches were taken one step further in the MCM silicon substrate curvature measurement. In a MCM package with silicon substrate, epoxy adhesive, and ceramic package, substrate warpage was developed in a thermal cycle due to thermal mismatch between the substrate and the package and coupling effect linked by epoxy adhesive. Three different substrate curvature measurement techniques were applied to identify the substrate curvature and epoxy thin film properties were also well characterized. A 3D FEA model incorporating with the epoxy material properties was developed to analyze the substrate warpage and investigate an optimal package design.


2013 ◽  
Vol 51 ◽  
pp. 229-235 ◽  
Author(s):  
Ine Rombouts ◽  
Bert Lagrain ◽  
Jan A. Delcour ◽  
Hasan Türe ◽  
Mikael S. Hedenqvist ◽  
...  

2010 ◽  
Vol 95 (12) ◽  
pp. 2309-2317 ◽  
Author(s):  
Xiaoqing Zhang ◽  
Yesim Gozukara ◽  
Parveen Sangwan ◽  
Dachao Gao ◽  
Stuart Bateman

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