Three-Membered Metal-Nucleobase-Carboxylate System Showing Interesting 2D and 3D Architecture: Synthesis, Structure, Thermostability, and Magnetic Properties

2012 ◽  
Vol 65 (3) ◽  
pp. 320 ◽  
Author(s):  
Hai-Xiao Huang ◽  
Xiao-Zhao Tian ◽  
Yu-Mei Song ◽  
Zhen-Wei Liao ◽  
Gong-Ming Sun ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Hydrothermal Synthesis ◽  
Organic Compounds ◽  
Isophthalic Acid ◽  
3D Structures ◽  
Zeolite Type ◽  
3D Architecture ◽  
Metal Organic ◽  
Thermogravimetric Studies ◽  
2D And 3D

Via hydrothermal synthesis, we constructed four nucleobase metal-organic compounds, viz. Zn2(7H-ade)(oba)2·H2O (1), Zn(1H-hyp)(Hoba) (2), Ni(1H-ade)(ip) (3), and Cd(H2O)(9H-ade)(ip) (4), where ade, hyp, H2oba, and H2ip are adenine, hypoxanthine, 4,4′-oxybisbenzoic acid, and isophthalic acid, respectively. These polymers show novel 2D and 3D structures, such as 3-fold interpenetrating dmp net, supramolecular zeolite-type sra net, and exceptional 2D 44 net composed of three kinds of quadrangle, observed in polymers 1, 2, and 3, respectively. Moreover, thermogravimetric studies of polymers 1, 2, and 4, and the magnetic properties of 3 are also explored.

scholarly journals Reticular Chemistry: Molecular Precision in Infinite 2D and 3D

2019 ◽  
Vol 03 (01) ◽  
pp. 66-83 ◽  
Author(s):  
Omar M. Yaghi
Keyword(s):  
Chemical Stability ◽  
Carbon Capture ◽  
Metal Organic Frameworks ◽  
Water Harvesting ◽  
High Porosity ◽  
Covalent Organic Frameworks ◽  
3D Structures ◽  
Metal Organic ◽  
2D And 3D ◽  
Thermal And Chemical Stability

The long-standing dream of scientists to be able to link molecules together into crystalline, extended (infinite) 2D and 3D structures is now realized by the establishment of reticular chemistry through the discovery and development of metal-organic frameworks and covalent organic frameworks. The architectural, thermal, and chemical stability of such frameworks allowed study of their ultra-high porosity, reactivity and many applications including carbon capture and conversion to fuels, and water harvesting from desert air.

Poly[diaquo(1,10-phenanthroline-κ2N1:N10)(μ2-sulphato-κ2O:O′)copper(ii)]: hydrothermal synthesis, crystal structure and magnetic properties

RSC Advances ◽  
2016 ◽  
Vol 6 (51) ◽  
pp. 46030-46036 ◽  
Author(s):  
Amarjit Kamath ◽  
Dipu Kumar Mishra ◽  
Dhiraj Brahman ◽  
Guillaume Pilet ◽  
Biswajit Sinha ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Magnetic Properties ◽  
Hydrothermal Synthesis ◽  
Organic Hybrid ◽  
Metal Organic ◽  
Hybrid Complexes

Of late, hydrothermal synthesis has gained much interest in the synthesis of metal–organic hybrid complexes with fascinating architectures and topologies.

Luminescence and magnetic properties of three metal–organic frameworks based on the 5-(1H-tetrazol-5-yl)isophthalic acid ligand

CrystEngComm ◽  
2013 ◽  
Vol 15 (38) ◽  
pp. 7636 ◽  
Author(s):  
Antonio J. Calahorro ◽  
Alfonso Salinas-Castillo ◽  
José Manuel Seco ◽  
Javier Zuñiga ◽  
Enrique Colacio ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Metal Organic Frameworks ◽  
Isophthalic Acid ◽  
Acid Ligand ◽  
Metal Organic

Four metal–organic frameworks based on the 5-(1H-tetrazol-5-yl)isophthalic acid ligand: luminescence and magnetic properties

CrystEngComm ◽  
2016 ◽  
Vol 18 (9) ◽  
pp. 1523-1531 ◽  
Author(s):  
Wei Gao ◽  
Peng Li ◽  
Feng Liu ◽  
Xiu-Mei Zhang ◽  
Jie-Ping Liu
Keyword(s):  
Magnetic Properties ◽  
Metal Organic Frameworks ◽  
Isophthalic Acid ◽  
Acid Ligand ◽  
Metal Organic

scholarly journals Magnetic Ordering of Three Thiosemicarbazonecopper(II) Complexes

Proceedings ◽  
2019 ◽  
Vol 26 (1) ◽  
pp. 53
Author(s):  
Iñigo Etxebarria ◽  
M. Begoña Torres ◽  
Javier García-Tojal ◽  
José Vicente Cuevas ◽  
Gotzon Madariaga
Keyword(s):  
Magnetic Properties ◽  
Organic Compounds ◽  
Material Science ◽  
Magnetic Ordering ◽  
Point Of View ◽  
Metal Organic ◽  
Structural And Magnetic Properties

During the last decades, metal-organic compounds constitute an active field of research, and among them, complexes that combine thiosemicarbazone ligands with copper(II) are appealing from the point of view of material science due to their interesting structural and magnetic properties [1]. [...]

scholarly journals A survey of interactions in crystal structures of pyrazine-based compounds

2019 ◽  
Vol 75 (3) ◽  
pp. 231-247 ◽  
Author(s):  
Fatemeh Taghipour ◽  
Masoud Mirzaei
Keyword(s):  
Magnetic Properties ◽  
Hydrogen Bonding ◽  
Solid State ◽  
Organic Compounds ◽  
Coordination Polymers ◽  
Noncovalent Interactions ◽  
Metal Organic Framework ◽  
Supramolecular Architectures ◽  
Metal Organic

The important role of pyrazine (pz) and its derivatives in fields such as biochemistry and pharmacology, as well as in the study of magnetic properties, is surveyed. Recognition of these properties without extensive investigations into their structural properties is not possible. This review summarizes interactions that exist between these organic compounds by themselves in the solid state, as well as those in coordination polymers with metal ions and in polyoxometalate-based hybrids. Complexes based on pyrazine ligands can generate metal–organic framework (MOF) structures that bind polyoxometalates (POMs) through covalent and noncovalent interactions. Some biological and magnetic properties involving these compounds are considered and the effect of hydrogen bonding on their supramolecular architectures is highlighted.

Construction of Metal−Organic Frameworks with Tetranuclear Metal Clusters: Hydrothermal Synthesis, Structure, and Magnetic Properties

2010 ◽  
Vol 10 (2) ◽  
pp. 534-540 ◽  
Author(s):  
Guan-Hua Wang ◽  
Yong-Qian Lei ◽  
Ning Wang ◽  
Ren-Ling He ◽  
Heng-Qing Jia ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Hydrothermal Synthesis ◽  
Metal Clusters ◽  
Metal Organic Frameworks ◽  
Metal Organic
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