Silicon Analogues of Polyfluorene as Materials for Organic Electronics

2009 ◽  
Vol 62 (5) ◽  
pp. 393 ◽  
Author(s):  
Wallace W. H. Wong ◽  
Joel F. Hooper ◽  
Andrew B. Holmes
Keyword(s):  
Thermal Stability ◽  
Optical Properties ◽  
Electronic Materials ◽  
Electronic Devices ◽  
Organic Electronic Devices ◽  
Organic Electronic ◽  
Light Emitting ◽  
Organic Electronic Materials ◽  
Resistance To Oxidation ◽  
Improved Performance

Poly(dibenzosilole)s have been increasingly reported as an alternative to polyfluorene in organic electronic materials. Poly(dibenzosilole)s show similar optical properties to polyfluorene, but with improved resistance to oxidation and thermal stability. Several poly(dibenzosilole)s and their co-polymers have been incorporated into organic electronic devices, such as light emitting diodes and solar cells. These materials have shown improved performance over their polyfluorene-based counterparts.

Substituted triphenylamines as building blocks for star shaped organic electronic materials

2015 ◽  
Vol 39 (3) ◽  
pp. 1840-1851 ◽  
Author(s):  
Daniel Lumpi ◽  
Brigitte Holzer ◽  
Johannes Bintinger ◽  
Ernst Horkel ◽  
Simon Waid ◽  
...  
Keyword(s):  
Organic Semiconductors ◽  
Electronic Materials ◽  
Electronic Devices ◽  
Building Blocks ◽  
Organic Electronic Devices ◽  
Organic Electronic ◽  
Organic Electronic Materials

A series of star shaped organic semiconductors was synthesized and characterized. The applicability of these materials in organic electronic devices was demonstrated.

scholarly journals Biodegradation of bio-sourced and synthetic organic electronic materials towards green organic electronics

2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Eduardo Di Mauro ◽  
Denis Rho ◽  
Clara Santato
Keyword(s):  
Organic Electronics ◽  
Electronic Materials ◽  
Chemical Elements ◽  
Electronic Devices ◽  
Polyphenylene Sulfide ◽  
Environmentally Benign ◽  
Organic Electronic ◽  
Synthetic Materials ◽  
Organic Electronic Materials ◽  
Thermophilic Conditions

AbstractUbiquitous use of electronic devices has led to an unprecedented increase in related waste as well as the worldwide depletion of reserves of key chemical elements required in their manufacturing. The use of biodegradable and abundant organic (carbon-based) electronic materials can contribute to alleviate the environmental impact of the electronic industry. The pigment eumelanin is a bio-sourced candidate for environmentally benign (green) organic electronics. The biodegradation of eumelanin extracted from cuttlefish ink is studied both at 25 °C (mesophilic conditions) and 58 °C (thermophilic conditions) following ASTM D5338 and comparatively evaluated with the biodegradation of two synthetic organic electronic materials, namely copper (II) phthalocyanine (Cu–Pc) and polyphenylene sulfide (PPS). Eumelanin biodegradation reaches 4.1% (25 °C) in 97 days and 37% (58 °C) in 98 days, and residual material is found to be without phytotoxic effects. The two synthetic materials, Cu–Pc and PPS, do not biodegrade; Cu–Pc brings about the inhibition of microbial respiration in the compost. PPS appears to be potentially phytotoxic. Finally, some considerations regarding the biodegradation test as well as the disambiguation of “biodegradability” and “bioresorbability” are highlighted.

scholarly journals Waiting for Act 2: what lies beyond organic light-emitting diode (OLED) displays for organic electronics?

Nanophotonics ◽  
2020 ◽  
Vol 10 (1) ◽  
pp. 31-40
Author(s):  
Stephen R. Forrest
Keyword(s):  
Organic Electronics ◽  
Light Emitting Diode ◽  
Electronic Devices ◽  
Organic Electronic Devices ◽  
Organic Electronic ◽  
Light Emitting ◽  
Organic Light Emitting Diode ◽  
Organic Light ◽  
Semiconductor Thin Films ◽  
Display Technology

AbstractOrganic light-emitting diode (OLED) displays are now poised to be the dominant mobile display technology and are at the heart of the most attractive televisions and electronic tablets on the market today. But this begs the question: what is the next big opportunity that will be addressed by organic electronics? We attempt to answer this question based on the unique attributes of organic electronic devices: their efficient optical absorption and emission properties, their ability to be deposited on ultrathin foldable, moldable and bendable substrates, the diversity of function due to the limitless palette of organic materials and the low environmental impact of the materials and their means of fabrication. With these unique qualities, organic electronics presents opportunities that range from lighting to solar cells to medical sensing. In this paper, we consider the transformative changes to electronic and photonic technologies that might yet be realized using these unconventional, soft semiconductor thin films.

scholarly journals Convenient fabrication of conjugated polymer semiconductor nanotubes and their application in organic electronics

2018 ◽  
Vol 5 (8) ◽  
pp. 180868
Author(s):  
Lanchao Ma ◽  
Shuixing Dai ◽  
Xiaowei Zhan ◽  
Xinyang Liu ◽  
Yu Li
Keyword(s):  
Organic Solar Cells ◽  
Field Effect Transistors ◽  
Electronic Devices ◽  
Solution Concentration ◽  
Core Shell ◽  
Organic Electronic Devices ◽  
Organic Electronic ◽  
Light Emitting ◽  
Preparation Conditions ◽  
Polymer Semiconductor

Organic heterojunction is indispensable in organic electronic devices, such as organic solar cells, organic light-emitting diodes and so on. Fabrication of core–shell nanostructure provides a feasible and novel way to prepare organic heterojunction, which is beneficial for miniaturization and integration of organic electronic devices. Fabrication of nanotubes which constitute the core–shell structure in large quantity is the key for the realization of application. In this work, a simple and convenient method to prepare nanotubes using conjugated copolymer of perylene diimide and dithienothiophene (P(PDI-DTT)) was demonstrated. The relationship between preparation conditions (solvent atmosphere, solution concentration and pore diameter of templates) and morphology of nanostructure was studied systematically. P(PDI-DTT) nanotubes could be fabricated in regular shape and large quantity by preparing the solution with appropriate concentration and placing anodic aluminium oxide template with nanopore diameter of 200 nm in the solvent atmosphere. The tubular structure was confirmed by scanning electron microscopy. P(PDI-DTT) nanotubes exhibited electron mobility of 0.02 cm 2 V –1 s –1 in field-effect transistors under ambient condition. Light-emitting nanostructures were successfully fabricated by incorporating tetraphenylethylene into polymer nanotubes.

scholarly journals Fullerene Dissymmetrization as a Means to Achieve Single Enantiomer Electron Acceptors with Maximized Chiroptical Responsiveness

2020 ◽  
Author(s):  
Wenda Shi ◽  
Francesco Salerno ◽  
Alejandro Santana-Bonilla ◽  
Matthew Ward ◽  
Xueyan Hou ◽  
...  
Keyword(s):  
Electronic Materials ◽  
Light Response ◽  
Electron Acceptors ◽  
Fullerene Cage ◽  
Structure Property ◽  
Organic Electronic Devices ◽  
Organic Electronic ◽  
Structure Property Relationships ◽  
Organic Electronic Materials ◽  
Fast Light

<p>Solubilized fullerene derivatives have revolutionised the development of organic photovoltaic devices, acting as excellent electron acceptors. The addition of solubilizing addends to the fullerene cage results in a large number of isomers, which are generally employed as isomeric mixtures. Moreover, a significant number of these isomers are chiral, which further adds to the isomeric complexity. The opportunities presented by single isomer, and particularly single enantiomer, fullerenes in organic electronic materials and devices are poorly understood. Here we separate 10 pairs of enantiomers from the 19 structural isomers of bis[60]PCBM, using them to elucidate important chiroptical structure-property relationships and demonstrating their application to a single enantiomer circularly polarized (CP) light detecting device. We find that larger chiroptical responses occur through inherent chirality of the fullerene cage and particularly through transitions with low CT character. When used in a single enantiomer organic field-effect transistor device, we demonstrate the potential to discriminate CP light with a fast light response time and with a very high photocurrent dissymmetry factor (<i>g<sub>ph</sub></i> = ±1.35). Our study thus provides key strategies to design fullerenes with large chiroptical responses for use as single enantiomer components of organic electronic devices. We anticipate that our data will position chiral fullerenes as an exciting material class for the growing field of chiral electronic technologies.</p>

scholarly journals Fullerene Dissymmetrization as a Means to Achieve Single Enantiomer Electron Acceptors with Maximized Chiroptical Responsiveness

2020 ◽  
Author(s):  
Wenda Shi ◽  
Francesco Salerno ◽  
Alejandro Santana-Bonilla ◽  
Matthew Ward ◽  
Xueyan Hou ◽  
...  
Keyword(s):  
Electronic Materials ◽  
Light Response ◽  
Electron Acceptors ◽  
Fullerene Cage ◽  
Structure Property ◽  
Organic Electronic Devices ◽  
Organic Electronic ◽  
Structure Property Relationships ◽  
Organic Electronic Materials ◽  
Fast Light

<p>Solubilized fullerene derivatives have revolutionised the development of organic photovoltaic devices, acting as excellent electron acceptors. The addition of solubilizing addends to the fullerene cage results in a large number of isomers, which are generally employed as isomeric mixtures. Moreover, a significant number of these isomers are chiral, which further adds to the isomeric complexity. The opportunities presented by single isomer, and particularly single enantiomer, fullerenes in organic electronic materials and devices are poorly understood. Here we separate 10 pairs of enantiomers from the 19 structural isomers of bis[60]PCBM, using them to elucidate important chiroptical structure-property relationships and demonstrating their application to a single enantiomer circularly polarized (CP) light detecting device. We find that larger chiroptical responses occur through inherent chirality of the fullerene cage and particularly through transitions with low CT character. When used in a single enantiomer organic field-effect transistor device, we demonstrate the potential to discriminate CP light with a fast light response time and with a very high photocurrent dissymmetry factor (<i>g<sub>ph</sub></i> = ±1.35). Our study thus provides key strategies to design fullerenes with large chiroptical responses for use as single enantiomer components of organic electronic devices. We anticipate that our data will position chiral fullerenes as an exciting material class for the growing field of chiral electronic technologies.</p>

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