Charge Transfer Polymerization in Ionic Liquids

2004 ◽  
Vol 57 (2) ◽  
pp. 129 ◽  
Author(s):  
Ranganathan Vijayaraghavan ◽  
Douglas R. MacFarlane
Keyword(s):  
Molecular Weight ◽  
Ionic Liquids ◽  
Charge Transfer ◽  
Room Temperature ◽  
Reaction Rate ◽  
Reaction Times ◽  
Room Temperature Ionic Liquids ◽  
Reaction Conditions ◽  
Butyl Amine ◽  
Conventional Ct

Charge transfer (CT) polymerization of methyl methacrylate has been successfully carried out by employing n-butyl amine and carbon tetrachloride as CT initiators and hydroquinone as promoter in room-temperature ionic liquids (ILs) as solvents. The reaction rate and polymer yields at short reaction times are enhanced in the IL solvent compared to conventional solvents. The effect of various reaction conditions including concentration of amine, IL, and temperature have been studied. The polymers were characterized for thermal and molecular weight properties and compared with the conventional CT reaction.

Ultrafast solvation dynamics and charge transfer reactions in room temperature ionic liquids

2014 ◽  
Vol 16 (26) ◽  
pp. 13008-13026 ◽  
Author(s):  
Yutaka Nagasawa ◽  
Hiroshi Miyasaka
Keyword(s):  
Electron Transfer ◽  
Ionic Liquids ◽  
Charge Transfer ◽  
Room Temperature ◽  
Liquid Structure ◽  
Transfer Reactions ◽  
Room Temperature Ionic Liquids ◽  
Solvation Dynamics ◽  
Charge Transfer Reactions

In this perspective, we review the recent studies concerning the liquid structure and solvation dynamics of ionic liquids, and their influence upon electron transfer and charge transfer reactions.

Influence of Chemical Structure on the Solubility of Low Molecular Weight Carbohydrates in Room Temperature Ionic Liquids

2014 ◽  
Vol 53 (36) ◽  
pp. 13843-13850 ◽  
Author(s):  
Cipriano Carrero-Carralero ◽  
Laura Ruiz-Aceituno ◽  
Lourdes Ramos ◽  
F. Javier Moreno ◽  
M. Luz Sanz
Keyword(s):  
Molecular Weight ◽  
Ionic Liquids ◽  
Chemical Structure ◽  
Room Temperature ◽  
Room Temperature Ionic Liquids ◽  
Low Molecular Weight
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