Solvothermal Syntheses and Characterizations of Two Isomorphous One-Dimensional Chain Complexes Constructed by Orotic Acid

2002 ◽  
Vol 55 (10) ◽  
pp. 681 ◽  
Author(s):  
D. Sun ◽  
R. Cao ◽  
Y. Liang ◽  
M. Hong ◽  
Y. Zhao ◽  
...  
Keyword(s):  
Metal Ion ◽  
Orotic Acid ◽  
Three Dimensional ◽  
Distorted Octahedral Geometry ◽  
Dimensional Chain ◽  
Orthorhombic Space Group ◽  
One Dimensional ◽  
Hydrogen Bond Interactions ◽  
Chain Complexes ◽  
Dimensional Network

Solvothermal reactions of M(OAc)2 (M = Ni, Co) with orotic acid (2,6-dioxo-1,2,3,6-tetrahydropyrimidine-4-carboxylic acid, H3L) in H2O/MeOH (1 : 1) gave rise to two new isomorphous polymeric complexes, [M(HL)(H2O)3]n [M = Ni, (4); Co, (5)], with one-dimensional chain structures. Both complexes crystallize in the orthorhombic space group P212121, with a 7.7438(7), b 7.7610(7), c 14.6528(12) �, Z 4 for (4), and a 7.7005(3), b 7.8725(3), c 14.6997(10) �, Z 4 for (5). X-Ray diffraction analysis shows that the metal ion is coordinated by nitrogen and oxygen atoms of an orotate ligand (HL2–) and water molecules in a distorted octahedral geometry. The hydrogen-bond interactions between chains leads to the formation of three-dimensional network structures.

scholarly journals Bis(propane-1,3-diamine)disaccharinatonickel(II)

2012 ◽  
Vol 68 (4) ◽  
pp. m425-m426 ◽  
Author(s):  
Gökhan Kaştaş ◽  
Can Kocabıyık
Keyword(s):  
Metal Ion ◽  
Crystal Packing ◽  
Chair Conformation ◽  
Membered Ring ◽  
Octahedral Geometry ◽  
Distorted Octahedral Geometry ◽  
Inversion Center ◽  
One Dimensional ◽  
Dimensional Network ◽  
Distorted Octahedral

In the title complex, [Ni(C7H4NO3S)2(C3H10N2)2] or [Ni(sac)2(pen)2] (sac = saccharinate or 1,1,3-trioxo-2,3-dihydro-1λ6,2-benzothiazol-2-ide and pen = propane-1,3-diamine), the NiIIion sits on an inversion center, being coordinated by two N atoms of the sac ligands, which occupytranspositions, and four N atoms of the bidentate pen ligands to define a distorted octahedral geometry. The pen ligands chelate the metal ion, forming a six-membered ring which adopts a half-chair conformation, while the sac ligands adopt the most common coordination mode. The crystal packing is stabilized by N—H...O hydrogen bonds, which form a one-dimensional network along [010]. It is also supported by an N—H...S hydrogen bond between the amine group of the pen ligand and the sulfonyl group of the sac ligand.

A new one-dimensional CuIIcomplex with a three-dimensional supramolecular architecture incorporating benzene-1,3-dicarboxylate and 1-[(1H-benzotriazol-1-yl)methyl]-1H-imidazole

2017 ◽  
Vol 73 (2) ◽  
pp. 91-96 ◽  
Author(s):  
Jian-Hua Li ◽  
Meng-Di Zhu ◽  
Qiu-Ying Huang
Keyword(s):  
Thermogravimetric Analysis ◽  
Water Molecule ◽  
Main Chain ◽  
Three Dimensional ◽  
Donor Ligands ◽  
Dimensional Chain ◽  
Supramolecular Architecture ◽  
Coordination Environment ◽  
One Dimensional ◽  
Dimensional Network

Subtle modifications ofN-donor ligands can result in complexes with very different compositions and architectures. In the complexcatena-poly[[bis{1-[(1H-benzotriazol-1-yl)methyl]-1H-imidazole-κN3}copper(II)]-μ-benzene-1,3-dicarboxylato-κ3O1,O1′:O3], {[Cu(C8H4O4)(C10H9N5)2(H2O)]·2H2O}n, each CuIIion is six-coordinated by two N atoms from two crystallographically independent 1-[(1H-benzotriazol-1-yl)methyl]-1H-imidazole (bmi) ligands, by three O atoms from two symmetry-related benzene-1,3-dicarboxylate (bdic2−) ligands and by one water molecule, leading to a distorted CuN2O4octahedral coordination environment. The CuIIions are connected by bridging bdic2−anions to generate a one-dimensional chain. The bmi ligands coordinate to the CuIIions in monodentate modes and are pendant on opposite sides of the main chain. In the crystal, the chains are linked by O—H...O and O—H...N hydrogen bonds, as well as by π–π interactions, into a three-dimensional network. A thermogravimetric analysis was carried out and the fluorescence behaviour of the complex was also investigated.

2-[(E)-2-(4-Methoxyphenyl)ethenyl]-1-methylquinolinium 4-bromobenzenesulfonate

2006 ◽  
Vol 62 (7) ◽  
pp. o2725-o2727 ◽  
Author(s):  
Hoong-Kun Fun ◽  
Pinanong Rodwatcharapiban ◽  
Boonwasana Jindawong ◽  
Suchada Chantrapromma
Keyword(s):  
Crystal Structure ◽  
Benzene Ring ◽  
Title Compound ◽  
Three Dimensional ◽  
Dihedral Angles ◽  
Dimensional Chain ◽  
One Dimensional ◽  
Π Interactions ◽  
Compound C ◽  
Dimensional Network

In the title compound C19H18NO+·C6H4BrSO3 −, the cation is almost planar. The benzene ring of the anion makes dihedral angles of 84.23 (12) and 84.59 (15)°, respectively, with the quinolinium group and the benzene ring of the cation. The cations and anions are arranged in an alternating one-dimensional chain along the b axis, and these chains are interconnected through C—H...O and C—H...Br interactions to form a three-dimensional network. C—H...π interactions are also observed in the crystal structure.

Novel one- and two-dimensional ZnIIcoordination polymers based on a versatile 3,6-bis(pyridin-4-yl)phenanthrene-9,10-dione ligand

2015 ◽  
Vol 71 (12) ◽  
pp. 1089-1095
Author(s):  
Guoxia Jin ◽  
Jia Wang ◽  
Qidi Wu ◽  
Zheng Han ◽  
Jianping Ma
Keyword(s):  
Hydrogen Bond ◽  
Hydrothermal Reaction ◽  
Three Dimensional ◽  
Two Dimensional ◽  
One Dimensional ◽  
Hydrogen Bond Interactions ◽  
Dimensional Network ◽  
Left And Right ◽  
Solvent Systems ◽  
Single Crystal Analysis

Two new ZnIIcoordination polymers, namely,catena-poly[[dibromidozinc(II)]-μ-[3,6-bis(pyridin-4-yl)phenanthrene-9,10-dione-κ2N:N′]], [ZnBr2(C24H14N2O2)]n, (1), and poly[[bromido[μ3-10-hydroxy-3,6-bis(pyridin-4-yl)phenanthren-9-olato-κ3N:N′:O9]zinc(II)] hemihydrate], {[ZnBr(C24H15N2O2)]·0.5H2O}n, (2), have been synthesized through hydrothermal reaction of ZnBr2and a 60° angular phenanthrenedione-based linker,i.e.3,6-bis(pyridin-4-yl)phenanthrene-9,10-dione, in different solvent systems. Single-crystal analysis reveals that polymer (1) features one-dimensional zigzag chains connected by weak C—H...π and π–π interactions to form a two-dimensional network. The two-dimensional networks are further stacked in anABABfashion along theaaxis through C—H...O hydrogen bonds. LayersAandBcomprise left- and right-handed helical chains, respectively. Coordination polymer (2) displays a wave-like two-dimensional layered structure with helical chains. In this compound, there are two opposite helical –Zn–HL– chains [HLis 10-hydroxy-3,6-bis(pyridin-4-yl)phenanthren-9-olate] in adjacent layers. The layers are packed in anABABsequence and are further connected through O—H...Br and O—H...O hydrogen-bond interactions to form a three-dimensional framework. In (1) and (2), the mutidentateLand HLligands exhibits different coordination modes.

A one-dimensional zinc(II) coordination polymer based on mixed multidentateN- andO-donor ligands

2015 ◽  
Vol 71 (4) ◽  
pp. 306-310 ◽  
Author(s):  
Qiu-Ying Huang ◽  
Yu-Hong Zhang ◽  
Xiang-Ru Meng
Keyword(s):  
Coordination Polymer ◽  
Main Chain ◽  
Three Dimensional ◽  
Donor Ligands ◽  
Dimensional Chain ◽  
Two Dimensional ◽  
Coordination Environment ◽  
One Dimensional ◽  
Carboxylate Groups ◽  
Dimensional Network

In the title coordination polymer,catena-poly[[bis[{1-[(1H-benzimidazol-2-yl-κN3)methyl]-1H-tetrazole}zinc(II)]-bis(μ4-pentane-1,5-dioato-1:2:1′:2′κ4O1:O1′:O5:O5′)] methanol disolvate], {[Zn(C5H6O4)(C9H8N6)]·CH3OH}n, each ZnIIion is five-coordinated by four O atoms from four glutarate ligands and by one N atom from a 1-[(1H-benzimidazol-2-yl)methyl]-1H-tetrazole (bimt) ligand, leading to a slightly distorted square-pyramidal coordination environment. Two ZnIIions are linked by four bridging glutarate carboxylate groups to generate a dinuclear [Zn2(CO2)4] paddle-wheel unit. The dinuclear units are further connected into a one-dimensional chainviathe glutarate ligands. The bimt ligands coordinate to the ZnIIions in a monodentate mode and are pendant on both sides of the main chain. In the crystal, the chains are linked by O—H...O and N—H...O hydrogen bonds into a two-dimensional layered structure. Adjacent layers are further packed into a three-dimensional network through van der Waals forces. A thermogravimetric analysis was carried out and the photoluminescent behaviour of the polymer was investigated.

Crystal structure, shape analysis and bioactivity of new LiI, NaI and MgII complexes with 1,10-phenanthroline and 2-(3,4-dichlorophenyl)acetic acid

2019 ◽  
Vol 75 (3) ◽  
pp. 294-303 ◽  
Author(s):  
Syed Raza Shah ◽  
Zarbad Shah ◽  
Najeeb Ullah ◽  
Javid Hussain ◽  
Rashid Al-Harrasi ◽  
...  
Keyword(s):  
Acetic Acid ◽  
Chain Structure ◽  
Distorted Octahedral Geometry ◽  
Water Molecules ◽  
Dimensional Chain ◽  
Asymmetric Unit ◽  
Orthorhombic Space Group ◽  
Triclinic Space Group ◽  
Space Group ◽  
One Dimensional

Reactions of 1,10-phenanthroline (phen) and 2-(3,4-dichlorophenyl)acetic acid (dcaH) with Mn (CO3) (M = LiI, NaI and MgII; n = 1 and 2) in MeOH yield the mononuclear lithium complex aqua[2-(3,4-dichlorophenyl)acetato-κO](1,10-phenanthroline-κ2 N,N′)lithium(I), [Li(C8H5Cl2O2)(C12H8N2)(H2O)] or [Li(dca)(phen)(H2O)] (1), the dinuclear sodium complex di-μ-aqua-bis{[2-(3,4-dichlorophenyl)acetato-κO](1,10-phenanthroline-κ2 N,N′)sodium(I)}, [Na2(C8H5Cl2O2)2(C12H8N2)2(H2O)2] or [Na2(dca)2(phen)2(H2O)2] (2), and the one-dimensional chain magnesium complex catena-poly[[[diaqua(1,10-phenanthroline-κ2 N,N′)magnesium]-μ-2-(3,4-dichlorophenyl)acetato-κ2 O:O′] 2-(3,4-dichlorophenyl)acetate monohydrate], {[Mg(C8H5Cl2O2)(C12H8N2)(H2O)2](C8H5Cl2O2)·H2O} n or {[Mg(dca)(phen)(H2O)2](dca)·H2O} n (3). In these complexes, phen binds via an N,N′-chelate pocket, while the deprotonated dca− ligands coordinate either in a monodentate (in 1 and 2) or bidentate (in 3) fashion. The remaining coordination sites around the metal ions are occupied by water molecules in all three complexes. Complex 1 crystallizes in the triclinic space group P\overline{1} with one molecule in the asymmetric unit. The Li+ ion adopts a four-coordinated distorted seesaw geometry comprising an [N2O2] donor set. Complex 2 crystallizes in the triclinic space group P\overline{1} with half a molecule in the asymmetric unit, in which the Na+ ion adopts a five-coordinated distorted spherical square-pyramidal geometry, with an [N2O3] donor set. Complex 3 crystallizes in the orthorhombic space group P212121, with one Mg2+ ion, one phen ligand, two dca− ligands and three water molecules in the asymmetric unit. Both dcaH ligands are deprotonated, however, one dca− anion is not coordinated, whereas the second dca− anion coordinates in a bidentate fashion bridging two Mg2+ ions, resulting in a one-dimensional chain structure for 3. The Mg2+ ion adopts a distorted octahedral geometry, with an [N2O4] donor set. Complexes 1–3 were evaluated against urease and α-glucosidase enzymes for their inhibition potential and were found to be inactive.

A two-dimensional ZnIIcoordination polymer constructed from benzene-1,2,3-tricarboxylic acid andN,N′-bis[(pyridin-4-yl)methylidene]hydrazine

2015 ◽  
Vol 71 (7) ◽  
pp. 521-525
Author(s):  
Xiangfei Wang ◽  
Fang Yang ◽  
Meng Tang ◽  
Limin Yuan ◽  
Wenlong Liu
Keyword(s):  
Three Dimensional ◽  
Tricarboxylic Acid ◽  
Dimensional Chain ◽  
The Novel ◽  
Two Dimensional ◽  
One Dimensional ◽  
Hydrogen Bond Interactions ◽  
Secondary Building Units ◽  
Novel Complex ◽  
Thermal Stability Of

The hydrothermal synthesis of the novel complex poly[aqua(μ4-benzene-1,2,3-tricarboxylato)[μ2-4,4′-(hydrazine-1,2-diylidenedimethanylylidene)dipyridine](μ3-hydroxido)dizinc(II)], [Zn(C9H3O6)(OH)(C12H10N4)(H2O)]n, is described. The benzene-1,2,3-tricarboxylate ligand connects neighbouring Zn4(OH)2secondary building units (SBUs) producing an infinite one-dimensional chain. Adjacent one-dimensional chains are connected by theN,N′-bis[(pyridin-4-yl)methylidene]hydrazine ligand, forming a two-dimensional layered structure. Adjacent layers are stacked to generate a three-dimensional supramolecular architectureviaO—H...O hydrogen-bond interactions. The thermal stability of this complex is described and the complex also appears to have potential for application as a luminescent material.

The coordination chemistry of two symmetric fluorene-based organic ligands with cuprous chloride

2013 ◽  
Vol 69 (12) ◽  
pp. 1488-1493 ◽  
Author(s):  
Yan-Fei Liu ◽  
Chao-Wei Zhao ◽  
Jian-Ping Ma ◽  
Qi-Kui Liu ◽  
Yu-Bin Dong
Keyword(s):  
Hydrogen Bonds ◽  
Three Dimensional ◽  
Helical Chain ◽  
Cuprous Chloride ◽  
Dimensional Chain ◽  
Two Dimensional ◽  
One Dimensional ◽  
Dimensional Network ◽  
The Difference ◽  
The One

Two novel symmetric fluorene-based ligands, namely, 2,7-bis(1H-imidazol-1-yl)-9,9-dimethyl-9H-fluorene [L1 or (I), C21H18N4] and 2,7-bis(1H-imidazol-1-yl)-9,9-dipropyl-9H-fluorene (L2), have been used to construct the coordination polymerscatena-poly[[dichloridodicopper(I)(Cu—Cu)]-μ-2,7-bis(1H-imidazol-1-yl)-9,9-dimethyl-9H-fluorene], [Cu2Cl2(C21H18N4)]n, (II), andcatena-poly[[tetra-μ2-chlorido-tetracopper(I)]-bis[μ-2,7-bis(1H-imidazol-1-yl)-9,9-dipropyl-9H-fluorene]], [Cu4Cl4(C25H26N4)2]n, (III). There are three types of C—H...N hydrogen bonds in (I), resulting a two-dimensional network in theabplane, including a chiral helical chain along thebaxis. Compounds (II) and (III) are related one-dimensional polymers. In both, CuIatoms connect the symmetric ligands (L1 orL2) into a one-dimensional chain. In (II), the {[CuICl2]−} unit, acting as a co-anion, adheres to the one-dimensional chain through a weak Cu...Cu interaction. However, in (III), the {[CuI2Cl4]2−} unit links two different chains into a one-dimensional rope-ladder-type chain. In addition, there are C—H...Cl hydrogen bonds and π–π interactions in the extended structures of (II) and (III), the difference is that the chains in (II) are linked into a two-dimensional network while the chains in (III) are stacked into a three-dimensional framework.

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