Soil fertility changes in the long-term experimental plots at Kybybolite, South Australia. III. Changes in cation exchange capacity and exchangeable cations

1961 ◽  
Vol 12 (2) ◽  
pp. 273 ◽  
Author(s):  
JS Russell
Keyword(s):  
Organic Matter ◽  
Cation Exchange ◽  
Cation Exchange Capacity ◽  
Organic Matter Content ◽  
Exchange Capacity ◽  
Base Saturation ◽  
Upward Movement ◽  
Exchangeable Calcium ◽  
Exchange Complex

Changes in the cation exchange complex are one of the secondary effects arising out of the increasing organic matter content of soils, due to the influence of phosphorus fertilizers on leguminous pastures. Analysis of solonetzic soils from the long-term Kybybolite P plots indicates that there is a close relation between organic matter increase and increases in cation exchange capacity. For each increase of 0.1 % soil nitrogen, there has been a corresponding increase of 3.48 m-equiv.jl00 g in cation exchange capacity. Associated with these changes there have been increases in the level of exchangeable calcium and exchangeable hydrogen. Changes in exchangeable calcium appear related to the amount and form of fertilizer or amendment applied. Where little calcium has been added, the increase in cation exchange capacity has been satisfied almost entirely by hydrogen, and base saturation has decreased. There appears to have been little upward movement of metal cations from the lower horizons to the surface by plants, possibly owing to the species involved, or to the intractable nature of the B horizon. The possible effects of changes in the cation exchange complex on plant growth are discussed. Also, the possibility of maintaining base saturation on infertile soils where cation exchange capacity is being increased, is examined.

FACTEURS QUI INFLUENCENT LA TENEUR DE LA MATIERE ORGANIQUE ET LES PROPRIETES D'ECHANGE CATIONIQUE DES HORIZONS Ap DES SOLS DE GRANDE CULTURE DU QUEBEC

1976 ◽  
Vol 56 (3) ◽  
pp. 213-221 ◽  
Author(s):  
Y. A. MARTEL ◽  
M. R. LAVERDIERE
Keyword(s):  
Organic Matter ◽  
Cation Exchange ◽  
Cation Exchange Capacity ◽  
Organic Matter Content ◽  
Exchange Capacity ◽  
Western Canada ◽  
Regression Equations ◽  
Eastern Canada ◽  
Forage Crops ◽  
Exchangeable Bases

The objectives of this work were (1) to determine the relation existing between the organic matter contents of Ap horizons and their respective soil Orders, (Gleysolic and Podzolic), texture, pH and geographic locations in the different thermal regions of Quebec and (2) to determine the role of organic matter and soil texture on the cation exchange properties of the same Ap horizons coming from soils used for forage crops in Quebec. The cation-exchange capacity (CEC), the exchangeable bases and acidity were determined by using 1 N NH4OAC – pH 7. The results showed a variation in the carbon content ranging from 1.4 to 6.9%. The heat units accumulated in each region and the clay contents were correlated with the percentage of carbon and nitrogen. Soil pH and soil Orders (Gleysolic vs. Podzolic) did not seem to affect the organic matter content. The cation-exchange capacity (CEC) ranged from 10.6 to 42.6 meq/100 g soil; 40% of this was attributable to carbon and 32% to clay contents. Simple and multiple regression equations showed that carbon was correlated with the exchangeable acidity, while clay was related to the exchangeable bases. The CEC of organic matter and clay were respectively 161 ± 45 meq/100 g organic matter and 29 ± 6 meq/100 g clay. These values, lower than for Western Canada, reflected the nature of the organic matter that is less developed in Eastern Canada than in the Chernozemic soils; they also showed the effect of the predominant illite mineral found in the clay fractions compared to montmorillonite in Western Canada.

scholarly journals Chemical properties of long-term irrigated Fluvisols of the Beli Drim river valley in the Klina region (Serbia)

2021 ◽  
Vol 70 (1) ◽  
pp. 13-26
Author(s):  
Miodrag Tolimir ◽  
Branka Kresović ◽  
Borivoj Pejić ◽  
Katarina Gajić ◽  
Angelina Tapanarova ◽  
...  
Keyword(s):  
Cation Exchange ◽  
Cation Exchange Capacity ◽  
Humus Content ◽  
Chemical Properties ◽  
Base Cations ◽  
Exchange Capacity ◽  
Base Saturation ◽  
Basic Cations ◽  
Hydrolytic Acidity

The impact of long-term (> 100 yr) irrigation on soil chemical properties was studied on eight plots in the Beli Drim river valley in Kosovo and Metohija near Klina, Serbia. For these studies, soil samples from shallow profiles were collected from only one or two depth zones of the Ah horizon; and from moderately deep and deep profiles, from two to three depth zones for the purpose of comparing irrigated field and non-irrigated meadow lands. Water from the Beli Drim River and surface gravity systems (irrigation furrows or border strip irrigation) were used for irrigation. Chemical variables included determination of pH-H2O, content of CaCO3, content of humus, hydrolytic acidity, sum of basic cations, cation exchange capacity, and base saturation. On irrigated soils, the results of chemical analysis showed on average a small increase in pH-H2O (0.07 pH units), as well as a significant decrease in humus content (2.00-4.75%), sum of basic cations (4.98-12.98%) and cation exchange capacity (12.8%) compared to the non-irrigated land of the study area. Long-term irrigation had no effect on hydrolytic acidity and base saturation in the Ah horizon of the investigated lands. Namely, the mentioned variations in the chemical properties of the investigated soils show that slight processes of reduction in the humus content and reduction of the content of base cations occured. Data on the chemical properties of the investigated soils indicate that the destructive processes of reduction in the humus content and leaching of base cations must be controlled in order to achieve a stable sustainable system of high productivity and prevent their further deterioration.

Adsorption of Ametryne and Diuron by Soils

Weed Science ◽  
1970 ◽  
Vol 18 (4) ◽  
pp. 470-474 ◽  
Author(s):  
L. C. Liu ◽  
H. Cibes-Viadé ◽  
F. K. S. Koo
Keyword(s):  
Organic Matter ◽  
Cation Exchange ◽  
Puerto Rican ◽  
Cation Exchange Capacity ◽  
Equilibrium Solution ◽  
Soil Property ◽  
Organic Matter Content ◽  
Exchange Capacity ◽  
Matter Content ◽  
Highly Correlated

The adsorption of 2-(ethylamino)-4-(isopropylamino)-6-(methylthio)-s-triazine (ametryne) and 3-(3,4-dichlorophenyl)-1,1-dimethylurea (diuron) varied greatly among 34 Puerto Rican soils was studied using the agitated slurry technique. Adsorption was expressed as a distribution coefficient (Kd), which is the ratio of the amount of herbicide adsorbed to the amount in the equilibrium solution. In general, diuron was adsorbed to a greater degree than ametryne. Adsorption of ametryne was positively correlated with organic matter and silt content but negatively correlated with pH of the soil. The inclusion of soil pH in a multiple regression analysis contributed the highest increase in explanation for adsorption of ametryne. Adsorption of diuron was highly correlated with organic matter content and cation exchange capacity. A correlation was found between adsorption of diuron and content of magnesium, and soil texture. Cation exchange capacity was the only inclusion soil property which, in addition to organic matter, significantly contributed to the adsorption of diuron. Temperature appeared to have a greater effect on the adsorption of diuron than on the adsorption of ametryne. Conversely, the effect of pH on the adsorption of ametryne was significantly greater than that of diuron.

Loss of soil organic matter following cultivation of long-term pasture: effects on major exchangeable cations and cation exchange capacity

Soil Research ◽  
2015 ◽  
Vol 53 (4) ◽  
pp. 377 ◽  
Author(s):  
D. Curtin ◽  
P. M. Fraser ◽  
M. H. Beare
Keyword(s):  
Organic Matter ◽  
Soil Organic Matter ◽  
Cation Exchange ◽  
Cation Exchange Capacity ◽  
Crop Production ◽  
Exchange Capacity ◽  
Exchangeable Cations ◽  
Exchangeable Cation ◽  
C Stocks

Cultivation of grassland is known to lead to the depletion of soil organic matter (SOM), but the effect on the size and composition of the exchangeable cation suite has not been documented. We measured cation exchange capacity (CEC) and exchangeable cations (calcium, Ca; magnesium, Mg; potassium, K; sodium, Na), as well as soil carbon (C) and nitrogen (N) (0–7.5, 7.5–15, and 15–25 cm), 8 years after conversion of long-term ryegrass–white clover pasture (grazed by sheep) to annual crop production. The trial was near Lincoln, Canterbury, New Zealand. The trial included three tillage treatments: crops established using intensive cultivation (mouldboard ploughing), minimum tillage (shallow cultivation, ~10 cm), or no-tillage. The 8-year rotation was barley, wheat, pea, barley, pea, barley, barley, barley. A sheep-grazed pasture was maintained as an experimental control. The experiment also included a permanent fallow treatment (maintained plant-free using herbicides; not cultivated). After 8 years under arable cropping, soil C stocks (0–25 cm) were 10 t ha–1 less, on average, than under pasture. The vertical distribution of soil organic matter (SOM) was affected by tillage type, but the total amount of organic matter in the top 25 cm did not differ (P > 0.05) among the tillage treatments. Under permanent fallow (C loss of 13 t ha–1 relative to pasture), total exchangeable cation (Ca + Mg + K +Na) equivalents declined by 47 kmolc ha–1, a 20% decrease compared with pasture. Loss of exchange capacity resulted in the selective release of cations with lower affinity for SOM (K, Na, Mg). Smaller losses of exchangeable cations were recorded under the arable cropping rotation (average 31 kmolc ha–1), with no differences among tillage treatments. Effective CEC (at field pH) decreased under permanent fallow and cultivated treatments because of: (1) depletion of SOM (direct effect); and (2) soil acidification, which eliminated some of the remaining exchange sites (indirect effect). Acidification in the permanent fallow can be attributed to the N mineralisation process, whereas in the cropped systems, excess cation removal in harvested straw and grain accounted for about half of the measured acidification. There was evidence that the organic matter lost under arable cropping and fallow had lower CEC than SOM as a whole.

scholarly journals Soil chemical and microbiological attributes under integrated production system in Oxisol of degraded pasture

2020 ◽  
pp. 1772-1778
Author(s):  
Nayara Christina Almeida Araújo ◽  
Leidivan Almeida Frazão ◽  
Igor Costa de Freitas ◽  
Evander Alves Ferreira ◽  
Daniela Aparecida Freitas ◽  
...  
Keyword(s):  
Organic Matter ◽  
Cation Exchange ◽  
Production System ◽  
Cation Exchange Capacity ◽  
Soil Depth ◽  
Exchange Capacity ◽  
Base Saturation ◽  
Integrated Production ◽  
Horse Gram ◽  
Degraded Pasture

The objective of this study was to evaluate the chemical attributes and quality of an Oxisol after one year of conversion of degraded pasture into integrated production system. The evaluated treatments were degraded pasture (PAST-Control); Eucalyptus, clone Urograndis 144 (Eucalyptus grandis x E. urophylla hybrid) intercropped with cor and marandu grass (Brachiaria brizantha) (integration crop-livestock-forest system - ICLFS-M); with maize and perennial horse gram (Macrotyloma axillare) (ICLFS-HG); and with maize, java and marandu grass (ICLFS-M+J); Monoculture of marandu grass (MAR) and perennial horse gram (HG); and marandu grass intercropped with Java/ perennial horse gram (H+M). Soil samples were collected in July/2015 and January/2016 in 0-5, 5-10, 10-20 and 20-30 cm soil depth layers. The soil attributes such as pH, organic matter, phosphorus, sum of bases, effective and potential cation exchange capacity and base saturation were evaluated. The implantation of ICLFS system contributed to increase of soil organic matter, sum of bases, effective and potential cation exchange capacity and soil base saturation. The soil biological activity was increased in the rainy season, and the soil microbial carbon increased in ICLFS-HG+M, ICLFS- HG, ICLFS-M and HG+M when compared to monocultures and PAST. Integrated production systems provide improved in soil quality even with a short time implementation.

scholarly journals Effect of Topography and Soil Depth on Clay Content, Organic Matter Content, Active Acidity, Reserve Acidity and Cation Exchange Capacity of Some Tea Soils of Bangladesh

2016 ◽  
Vol 8 (2) ◽  
pp. 229-235
Author(s):  
A. F. M. Sanaullah ◽  
M. Akhtaruzzaman ◽  
M. A. Uddin
Keyword(s):  
Organic Matter ◽  
Cation Exchange ◽  
Cation Exchange Capacity ◽  
Soil Depth ◽  
Organic Matter Content ◽  
Clay Content ◽  
Exchange Capacity ◽  
Matter Content ◽  
Soil Samples ◽  
Topographic Positions

Soil samples were collected from M. R. Khan tea-estate area of Moulvibazar district, Bangladesh. Organic matter, active acidity, reserve acidity, cation exchange capacity, clay content and textural class of the collected soil samples for different topographic positions and depths were determined. The percentage of sand, silt and clay varied from 59.75 to 70.50, 12.50 to 20.00 and 14.50 to 22.75, respectively. Active acidity and reserve acidity of the soils varied from 4.13 to 5.82 and 3.46 to 4.84, respectively.  Organic matter content varied from 0.37% to 1.93%. Cation exchange capacity (CEC) varied from 11.42 to 24.86 cmolKg-1. Soils were acidic in nature with considerably high reserve acidity. The measured parameters of the soil samples were plotted and analyzed with reference to topography and depth. The parameters have been found to vary with sampling sites, depths and topography.

Using pH-dependent CEC to determine lime requirement

2006 ◽  
Vol 86 (1) ◽  
pp. 133-139 ◽  
Author(s):  
Edouard Lemire ◽  
Kate M Taillon ◽  
William H. Hendershot
Keyword(s):  
Organic Matter ◽  
Soil Properties ◽  
Cation Exchange ◽  
Soil Ph ◽  
Cation Exchange Capacity ◽  
Soil Analysis ◽  
Organic Matter Content ◽  
Exchange Capacity ◽  
Ph Dependent ◽  
Ph Curve

Controlling soil pH is important to ensure good crop yield. This study was conducted to determine whether the accuracy of the existing Shoemaker-McLean-Pratt (SMP) pH-buffer method could be improved by using the pH-dependent cation exchange capacity curve (CECpd). Soil pH, SMP and CECpd measurements were performed on 18 acid surface horizon soil samples, with textures from sandy loam to clay loam. These soils were incubated with three levels of calcium carbonate for 12 wk, after which the soil pH and the effective cation exchange capacity (CECe) were measured. The correlation coefficient (R2) for the CECpd and CECe curves was 0.96. The main factor affecting the slope of the curves is the soil organic matter content. The increase of CECe in the soil was also found to be directly proportional to the amount of lime applied, regardless of the type of soil. By using the slope of the Qv versus pH curve for each soil and the relationship between CECe and lime application, we were able to determine the lime required to raise the soil pH in water to 6.5. As an alternative to the current practice of using the SMP buffer, we propose that it should be possible to estimate the pH-dependent CEC curve from measurable soil properties (e.g., organic matter) and to estimate the lime requirement as the difference in CECpd between the existing and desired pH values. Once the slope of the Qv/pH relationship has been determined or estimated for a soil, the only measurement necessary for calculating lime requirement in subsequent years would be the soil pH. The proposed method would provide lime requirement estimates while decreasing the annual cost of soil analysis. Key words: Lime requirement, cation exchange capacity, Non-Ideal Competitive Adsorption, soil properties, organic matter, Fe oxides

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