scholarly journals Odour, dust and non-methane volatile organic-compound emissions from tunnel-ventilated layer-chicken sheds: a case study of two farms

2013 ◽  
Vol 53 (12) ◽  
pp. 1309 ◽  
Author(s):  
Mark Dunlop ◽  
Zoran D. Ristovski ◽  
Erin Gallagher ◽  
Gavin Parcsi ◽  
Robin L. Modini ◽  
...  
Keyword(s):  
Dust Emission ◽  
Ventilation Rate ◽  
Gas Chromatography Mass Spectrometry ◽  
Emission Rates ◽  
Layer Chicken ◽  
Volatile Organic ◽  
Different Seasons ◽  
Odour Emissions ◽  
Cleaning Cycle ◽  
Study Sites

An observational study was undertaken to measure odour and dust (PM10 and PM2.5) emission rates and identify non-methane volatile organic compounds (NMVOCs) and odorants in the exhaust air from two tunnel-ventilated layer-chicken sheds that were configured with multi-tiered cages and manure belts. The study sites were located in south-eastern Queensland and the West Gippsland region of Victoria, Australia. Samples were collected in summer and winter on sequential days across the manure-belt cleaning cycle. Odour emissions ranged from 58 to 512 ou/s per 1000 birds (0.03–0.27 ou/s.kg) and dust emission rates ranged 0.014–0.184 mg/s per 1000 birds for PM10 and 0.001–0.190 mg/s per 1000 birds for PM2.5. Twenty NMVOCs were identified, including three that were also identified as odorants using thermal desorption–gas chromatography–mass spectrometry/olfactometry analysis. Odour emission rates were observed to vary with the amount of manure accumulation on the manure belts, being lowest 2–4 days after removing manure. Odour emission rates were also observed to vary with diurnal and seasonal changes in ventilation rate. Dust emissions were observed to increase with ventilation rate but not with manure accumulation. Some NMVOCs were identified at both farms and in different seasons whereas others were observed only at one farm or in one season, indicating that odorant composition was influenced by farm-specific practices and season.

scholarly journals A statistical approach for estimating representative emission rates of biogenic volatile organic compounds and their determination for 192 plant species/genera in China

2017 ◽  
Author(s):  
Lingyu Li ◽  
Yaqi Li ◽  
Shaodong Xie
Keyword(s):  
Plant Species ◽  
Statistical Approach ◽  
Emission Rate ◽  
Field Measurements ◽  
Gas Chromatography Mass Spectrometry ◽  
Emission Rates ◽  
Crop Species ◽  
Volatile Organic ◽  
Monoterpene Emission ◽  
High Emission

Abstract. To obtain more and accurate biogenic volatile organic compound (BVOC) emission rates for more plant species in China and further improve the accuracy of emission rates used in BVOC emission inventories, we conducted field measurements and developed a statistical approach for estimating representative emission rates. We performed field measurements of BVOC emissions from 50 plant species at nine locations in China using our established semi-static enclosure system. The emissions of 102 VOCs, including isoprene, α-pinene, β-pinene, and other VOC species, were analyzed with a custom-built online gas chromatography-mass spectrometry/flame ionization detector system. From the results, broadleaf trees were the greatest potential emitters of isoprene, while needle-leaf trees emitted more pinene. Shrubs had lower isoprene and pinene emission potentials, but higher emission potentials for other VOCs. Methyl methacrylate, isopropylbenzene, isopentane, acetone, ethane, propane, toluene, and xylene were the dominant species among other VOCs, probably with high emission intensities. Therefore, their emissions should be considered in future global and regional BVOC estimation studies. Next, we summarized our field measurements along with reported emission rates from China and abroad. The emission intensity categories were produced based on statistics, with more detailed categories, accurate emission rate intervals and representative rates compared to previous studies. The results showed that the BVOC emission intensities of plants displayed different categories, such as lowest, lower, low, moderate, high, higher, and highest. The isoprene emission rate intervals and representative rates were: lowest, 0.08–0.11 and 0.1 μg C gdw−1 h−1; lower, 0.9–1.3 and 1.0 μg C gdw−1 h−1; low, 5.2–6.5 and 5.8 μg C gdw−1 h−1; moderate, 13.1–15.3 and 14.4 μg C gdw−1 h−1; high, 31.1–37.0 and 33.6 μg C gdw−1 h−1; higher, 67.2–75.1 and 70.1 μg C gdw−1 h−1; and highest, 135.1–157.6 and 142.5 μg C gdw−1 h−1. The monoterpene emission rate intervals and representative rates were: lowest, 0.08–0.11 and 0.1 μg C gdw−1 h−1; lower, 0.17–0.22 and 0.2 μg C gdw−1 h−1; low, 0.5–0.7 and 0.6 μg C gdw−1 h−1; moderate, 1.2–1.5 and 1.4 μg C gdw−1 h−1; high, 2.8–3.3 and 3.0 μg C gdw−1 h−1; and higher, 11.1–14.9 and 12.6 μg C gdw−1 h−1. Using these established emission intervals, we determined the isoprene and monoterpene emission rates for 192 plant species/genera in China, including 30 dominant tree species, 149 shrub and grass genera, and 13 crop species. These estimations would be further improved by integrating larger quantities of rigorous field measurements from China in the future.

Seasonal Variations of BVOCs Emission from Ginkgo biloba Linn in Urban Area

2011 ◽  
Vol 71-78 ◽  
pp. 2891-2894 ◽  
Author(s):  
De Wen Li ◽  
Yi Shi ◽  
Xing Yuan He ◽  
Guang Yu Chi
Keyword(s):  
Mass Spectrometry ◽  
Gas Chromatography ◽  
Organic Compound ◽  
Ginkgo Biloba ◽  
Aromatic Compounds ◽  
Emission Rate ◽  
Gas Chromatography Mass Spectrometry ◽  
Emission Rates ◽  
Volatile Organic ◽  
Methyl Cyclohexane

In this study, seasonal biogenic volatile organic compound (BVOC) emission rates and emission patterns of Ginkgo biloba linn are estimated. The released volatiles were collected from branches onto cartridges filled with Tenax TA, and quantified by thermal desorption gas chromatography mass spectrometry (GC-MS). The result showed that the main BVOCs emitted from Ginkgo biloba linn were alkanes, aldehydes, alkenes, aromatic compounds, esters, terpenes and ketones. The total BVOC emission rate increased from May, and reached its maximum 27.96 μg C g-1dw h-1 in July, then decreased quickly. The emissions of α-pinene, isoprene, cyclohexane, methyl-cyclohexane and 2-methyl-hexane were significantly correlated to both temperature (p<0.05) and light (p<0.05).

Comparison of the Effects of Silver in Nanostructured and Ultrahigh Diluted Form on Growth and Volatile Compounds Produced by Escherichia coli and Staphylococcus aureus

2020 ◽  
Vol 10 (3) ◽  
pp. 316-329
Author(s):  
Fateme Mirzajani ◽  
Amin Hamidi
Keyword(s):  
Escherichia Coli ◽  
Staphylococcus Aureus ◽  
Life Cycles ◽  
Gas Chromatography Mass Spectrometry ◽  
Untreated Sample ◽  
E Coli ◽  
Volatile Metabolites ◽  
Octyl Acetate ◽  
Volatile Organic ◽  
And Staphylococcus Aureus

Introduction: In this project, the growth and volatile metabolites profiles of Escherichia coli (E. coli ) and Staphylococcus aureus were monitored under the influence of silver base chemical, nanoparticle and ultra-highly diluted compounds. Materials & Methods: The treatments were done for 12000 life cycles using silver nanoparticles (AgNPs) as well as ultra-highly diluted Argentum nitricum (Arg-n). Volatile organic metabolites analysis was performed using gas chromatography mass spectrometry (GC-MS). The results indicated that AgNPs treatment made the bacteria resistant and adapted to growth in the nanoparticle condition. The use of ultra-highly diluted Arg-n initially increased growth but it decreased later. Also, with the continuous usage of these materials, no more bacterial growth was observed. Results: The most important compounds produced by E. coli are Acetophenone, Octyl acetate, Styrene, 1,8-cineole, 4-t-butyl-2-(1-methyl-2-nitroethyl)cyclohexane, hexadecane and 2-Undecanol. The main compounds derived from S. aureus are Acetophenone,1,8-cineole, Benzaldehyde, 2-Hexan-1-ol, Tridecanol, Dimethyl Octenal and tetradecane. Acetophenone and 1,8-cineole were common and produced by both organisms. Conclusion: Based on the origin of the produced volatiles, main volatiles percentage of untreated sample is hydrocarbon (>50%), while bacteria treatments convert the ratio in to aldehydes, ketones and alcohols in the case of AgNPs, (>80%) and aldehydes, ketones and terpenes in the case of Arg-n (>70%).

scholarly journals The Stool Volatile Metabolome of Pre-Term Babies

Molecules ◽  
2021 ◽  
Vol 26 (11) ◽  
pp. 3341
Author(s):  
Alessandra Frau ◽  
Lauren Lett ◽  
Rachael Slater ◽  
Gregory R. Young ◽  
Christopher J. Stewart ◽  
...  
Keyword(s):  
Early Life ◽  
Solid Phase ◽  
Mass Spectrometry Data ◽  
Gas Chromatography Mass Spectrometry ◽  
Mass Spectral ◽  
Branched Chain Fatty Acids ◽  
Volatile Organic ◽  
Stool Samples ◽  
Branched Chain ◽  
Mixed Modelling

The fecal metabolome in early life has seldom been studied. We investigated its evolution in pre-term babies during their first weeks of life. Multiple (n = 152) stool samples were studied from 51 babies, all <32 weeks gestation. Volatile organic compounds (VOCs) were analyzed by headspace solid phase microextraction gas chromatography mass spectrometry. Data were interpreted using Automated Mass Spectral Deconvolution System (AMDIS) with the National Institute of Standards and Technology (NIST) reference library. Statistical analysis was based on linear mixed modelling, the number of VOCs increased over time; a rise was mainly observed between day 5 and day 10. The shift at day 5 was associated with products of branched-chain fatty acids. Prior to this, the metabolome was dominated by aldehydes and acetic acid. Caesarean delivery showed a modest association with molecules of fungal origin. This study shows how the metabolome changes in early life in pre-term babies. The shift in the metabolome 5 days after delivery coincides with the establishment of enteral feeding and the transition from meconium to feces. Great diversity of metabolites was associated with being fed greater volumes of milk.

scholarly journals Volatile metabolites of willows determining host discrimination by adult Plagiodera versicolora

2021 ◽  
Author(s):  
Jiahao Ling ◽  
Xiaoping Li ◽  
Guo Yang ◽  
Tongming Yin
Keyword(s):  
Volatile Organic Compounds ◽  
Organic Compounds ◽  
Insect Pests ◽  
Leaf Beetle ◽  
Gas Chromatography Mass Spectrometry ◽  
Host Discrimination ◽  
Plagiodera Versicolora ◽  
Volatile Metabolites ◽  
Hexenyl Acetate ◽  
Volatile Organic

AbstractPlagiodera versicolora Laicharting is a highly damaging leaf beetle foraging on willow leaves. In willow germplasm collections, observation has shown that Salix suchowensis Cheng was severely foraged by this leaf beetle while Salix triandra L. was damage free or only slightly damaged. Results of olfactometer bioassays show that the headspace volatiles from leaves of S. triandra significantly repelled adult beetles, suggesting that this species produces volatile repellents against P. versicolora. S. suchowensis had no effect on the beetles. Gas chromatography-mass spectrometry was carried out to profile the headspace volatile organic compounds and 23 compounds from leaves of the alternate species in significantly different concentrations were detected. The effects of 20 chemical analogs on host discrimination were examined. Olfactory response to these chemicals showed that o-cymene, a S. suchowensis specific constituent, significantly attracted adult P. versicolora. In contrast, cis-3-hexenyl acetate, a constituent concentrated more in S. triandra than in S. suchowensis, significantly repelled beetles. Mixing o-cymene and cis-3-hexenyl acetate in comparable concentrations as in the volatiles of S. suchowensis demonstrated that the latter could mask the attracting effect of the former, causing a neutral response by adult beetles to leaves of S. suchowensis against clean air. In addition, chemical analogs have the same effect as plants when resembling volatile organic compounds in real samples. Two volatile metabolites were detected triggering host discrimination by one of the most damaging insect pests to host and non-host willows. The two metabolites are of considerable potential for use as olfactory signs in managing the beetles.

scholarly journals Trichoderma Strains and Metabolites Selectively Increase the Production of Volatile Organic Compounds (VOCs) in Olive Trees

Metabolites ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 213
Author(s):  
Irene Dini ◽  
Roberta Marra ◽  
Pierpaolo Cavallo ◽  
Angela Pironti ◽  
Immacolata Sepe ◽  
...  
Keyword(s):  
Volatile Organic Compounds ◽  
Organic Compounds ◽  
Gas Chromatography Mass Spectrometry ◽  
Lipid Signaling ◽  
Plant Interactions ◽  
Growth Promoters ◽  
Volatile Organic ◽  
Trichoderma Fungi ◽  
Olive Trees ◽  
Plant Plant

Plants emit volatile organic compounds (VOCs) that induce metabolomic, transcriptomic, and behavioral reactions in receiver organisms, including insect pollinators and herbivores. VOCs’ composition and concentration may influence plant-insect or plant-plant interactions and affect soil microbes that may interfere in plant-plant communication. Many Trichoderma fungi act as biocontrol agents of phytopathogens and plant growth promoters. Moreover, they can stimulate plant defense mechanisms against insect pests. This study evaluated VOCs’ emission by olive trees (Olea europaea L.) when selected Trichoderma fungi or metabolites were used as soil treatments. Trichoderma harzianum strains M10, T22, and TH1, T. asperellum strain KV906, T. virens strain GV41, and their secondary metabolites harzianic acid (HA), and 6-pentyl-α-pyrone (6PP) were applied to olive trees. Charcoal cartridges were employed to adsorb olive VOCs, and gas chromatography mass spectrometry (GC-MS) analysis allowed their identification and quantification. A total of 45 volatile compounds were detected, and among these, twenty-five represented environmental pollutants and nineteen compounds were related to olive plant emission. Trichoderma strains and metabolites differentially enhanced VOCs production, affecting three biosynthetic pathways: methylerythritol 1-phosphate (MEP), lipid-signaling, and shikimate pathways. Multivariate analysis models showed a characteristic fingerprint of each plant-fungus/metabolite relationship, reflecting a different emission of VOCs by the treated plants. Specifically, strain M10 and the metabolites 6PP and HA enhanced the monoterpene syntheses by controlling the MEP pathway. Strains GV41, KV906, and the metabolite HA stimulated the hydrocarbon aldehyde formation (nonanal) by regulating the lipid-signaling pathway. Finally, Trichoderma strains GV41, M10, T22, TH1, and the metabolites HA and 6PP improve aromatic syntheses at different steps of the shikimate pathway.

Sign in / Sign up

Export Citation Format

Share Document