ACIDIZING KINETICS AND ITS APPLICATION TO PLANNING AND OPTIMISATION OF RESERVOIR STIMULATION AND FORMATION DAMAGE REMOVAL

1995 ◽  
Vol 35 (1) ◽  
pp. 707
Author(s):  
S.S. Rahman ◽  
D. Nguyen ◽  
G.Y. Wang

Kinetic aspects of sandstone acidizing with mixtures of hydrofluoric (HF) and hydrochloric (HC1) acids have been studied experimentally using cores taken from a natural sandstone reservoir rock. The matrix reactivity and the resulting changes in porosity and permeability due to acid reactions were measured as a function of experimental conditions: (1) acid concentration, (2) injection rate and (3) temperature. The model parameters were correlated by a power law model. A numerical simulator was developed for linear flow to predict changes in core properties due to acidizing. Values from the simulator were verified by experimental results. This simulator was subsequently extended to radial flow, and therefore can be used to simulate field acid jobs of sandstone formations.

1999 ◽  
Vol 39 (1) ◽  
pp. 548
Author(s):  
T. Azizi ◽  
M.M. Rahman ◽  
S.S. Rahman

The matrix reactivity of sandstone formations with mixtures of hydrofluoric (HF) and hydrochloric (HC1) acids has been studied experimentally using natural cores. A systematic approach, which includes laboratory analysis and computer modelling, has been used to design and plan acid treatment for sandstone formations. Matrix reactivity to acid mixtures (reaction rate) and the relationship between the porosity and permeability are established by subjecting the Pacoota Sandstone core samples to different acid concentrations and injection rates at different temperatures. Based on material balance and reaction kinetics a numerical simulator has been developed and verified in the laboratory. This simulator can adequately predict spent-acid concentration and changes in porosity and permeability as a function of acid penetration depth for given acid treatment conditions (acid concentrations, injection rates and treatment temperatures).


Author(s):  
F. I. Grace ◽  
L. E. Murr

During the course of electron transmission investigations of the deformation structures associated with shock-loaded thin foil specimens of 70/30 brass, it was observed that in a number of instances preferential etching occurred along grain boundaries; and that the degree of etching appeared to depend upon the various experimental conditions prevailing during electropolishing. These included the electrolyte composition, the average current density, and the temperature in the vicinity of the specimen. In the specific case of 70/30 brass shock-loaded at pressures in the range 200-400 kilobars, the predominant mode of deformation was observed to be twin-type faults which in several cases exhibited preferential etching similar to that observed along grain boundaries. A novel feature of this particular phenomenon was that in certain cases, especially for twins located in the vicinity of the specimen edge, the etching or preferential electropolishing literally isolated these structures from the matrix.


1965 ◽  
Vol 5 (04) ◽  
pp. 329-332 ◽  
Author(s):  
Larman J. Heath

Abstract Synthetic rock with predictable porosity and permeability bas been prepared from mixtures of sand, cement and water. Three series of mixes were investigated primarily for the relation between porosity and permeability for certain grain sizes and proportions. Synthetic rock prepared of 65 per cent large grains, 27 per cent small grains and 8 per cent Portland cement, gave measurable results ranging in porosity from 22.5 to 40 per cent and in permeability from 0.1 darcies to 6 darcies. This variation in porosity and permeability was caused by varying the amount of blending water. Drainage- cycle relative permeability characteristics of the synthetic rock were similar to those of natural reservoir rock. Introduction The fundamental behavior characteristics of fluids flowing through porous media have been described in the literature. Practical application of these flow characteristics to field conditions is too complicated except where assumptions are overly simplified. The use of dimensionally scaled models to simulate oil reservoirs has been described in the literature. These and other papers have presented the theoretical and experimental justification for model design. Others have presented elements of model construction and their operation. In most investigations the porous media have consisted of either unconsolidated sand, glass beads, broken glass or plastic-impregnated granular substances-materials in which the flow behavior is not identical to that in natural reservoir rock. The relative permeability curves for unconsolidated sands differ from those for consolidated sandstone. The effect of saturation history on relative permeability measurements A discussed by Geffen, et al. Wygal has shown quite conclusively that a process of artificial cementation can be used to render unconsolidated packs into synthetic sandstones having properties similar to those of natural rock. Many theoretical and experimental studies have been made in attempts to determine the structure and properties of unconsolidated sand, the most notable being by Naar and Wygal. Others have theorized and experimented with the fundamental characteristics of reservoir rocks. This study was conducted to determine if some general relationship could be established between the size of sand grains and the porosity and permeability in consolidated binary packs. This paper presents the results obtained by changing some of the factors which affect the porosity and permeability of synthetically prepared sandstone. In addition, drainage relative permeability curves are presented. EXPERIMENTAL PROCEDURE Mixtures of Portland cement with water and aggregate generally are designed to have certain characteristics, but essentially all are planned to be impervious to water or other liquids. Synthetic sandstone simulating oil reservoir rock, however, must be designed to have a given permeability (sometimes several darcies), a porosity which is primarily the effective porosity but quantitatively similar to natural rock, and other characteristics comparable to reservoir rock, such as wettability, pore geometry, tortuosity, etc. Unconsolidated ternary mixtures of spheres gave both a theoretically computed and an experimentally observed minimum porosity of about 25 per cent. By using a particle-distribution system, one-size particle packs had reproducible porosities in the reproducible range of 35 to 37 per cent. For model reservoir studies of the prototype system, a synthetic rock having a porosity of 25 per cent or less and a permeability of 2 darcies was required. The rock bad to be uniform and competent enough to handle. Synthetic sandstone cores mere prepared utilizing the technique developed by Wygal. Some tight variations in the procedure were incorporated. The sand was sieved through U.S. Standard sieves. SPEJ P. 329ˆ


Author(s):  
S. Kaizerman ◽  
B. Benhabib ◽  
R. G. Fenton ◽  
G. Zak

Abstract A new robot kinematic calibration procedure is presented. The parameters of the kinematic model are estimated through a relationship established between the deviations in the joint variables and the deviations in the model parameters. Thus, the new method can be classified as an inverse calibration procedure. Using suitable sensitivity analysis methods, the matrix of the partial derivatives of joint variables with respect to robot parameters is calculated without having explicit expressions of joint variables as a function of task space coordinates (closed inverse kinematic solution). This matrix provides the relationship between the changes in the joint variables and the changes in the parameter values required for the calibration. Two deterministic sensitivity analysis methods are applied, namely the Direct Sensitivity Approach and the Adjoint Sensitivity Method. The new calibration procedure was successfully tested by the simulated calibrations of a two degree of freedom revolute-joint planar manipulator.


2005 ◽  
Vol 475-479 ◽  
pp. 1137-1140
Author(s):  
Lili Zhao ◽  
Feng Gao ◽  
Wei Min Wang ◽  
Chang Sheng Tian

The oriented 0.67Pb (Mg1/3Nb2/3)O3-0.33PbTiO3 (PMNT) polycrystals were prepared by the conventional ceramic technique and the templated grain growth method adding excess PbO in the matrix. Kinetics of the development of oriented structure was investigated systemically. In the presence of PbO liquid phase, the oriented PMNT polycrystals mainly grow by the dissolution-precipitation mechanism. The diffusion is determined by the sintering temperature and the PbO-excess content in the matrix. The thickness of oriented PMNT polycrystals displays a t1/3 dependence, which is characteristic of diffusion-controlled growth. For the thicker oriented structure, 20% excess PbO in the PMNT matrix and 1150oC for 10h are the proper experimental conditions. Moreover, the addition of PbO in the matrix hardly affects the final composition of ceramic matrix.


GeoArabia ◽  
1996 ◽  
Vol 1 (2) ◽  
pp. 267-284
Author(s):  
John L. Douglas ◽  

ABSTRACT The North ‘Ain Dar 3-D geocellular model consists of geostatistical models for electrofacies, porosity and permeability for a portion of the Jurassic Arab-D reservoir of Ghawar field, Saudi Arabia. The reservoir consists of a series of shallow water carbonate shelf sediments and is subdivided into 10 time-stratigraphic slices on the basis of core descriptions and gamma/porosity log correlations. The North ‘Ain Dar model includes an electrofacies model and electrofacies-dependent porosity and permeability models. Sequential Indicator Simulations were used to create the electrofacies and porosity models. Cloud Transform Simulations were used to generate permeability models. Advantages of the geostatistical modeling approach used here include: (1) porosity and permeability models are constrained by the electrofacies model, i.e. by the distribution of reservoir rock types; (2) patterns of spatial correlation and variability present in well log and core data are built into the models; (3) data extremes are preserved and are incorporated into the model. These are critical when it comes to determining fluid flow patterns in the reservoir. Comparison of model Kh with production data Kh indicates that the stratigraphic boundaries used in the model generally coincide with shifts in fluid flow as indicated by flowmeter data, and therefore represent reasonable flow unit boundaries. Further, model permeability and production estimated permeability are correlated on a Kh basis, in terms of vertical patterns of distribution and cumulative Kh values at well locations. This agreement between model and well test Kh improves on previous, deterministic models of the Arab-D reservoir and indicates that the modeling approach used in North ‘Ain Dar should be applicable to other portions of the Ghawar reservoir.


2021 ◽  
Author(s):  
E. P. Putra

The Globigerina Limestone (GL) is the main reservoir of the seven gas fields that will be developed in the Madura Strait Block. The GL is a heterogeneous and unique clastic carbonate. However, the understanding of reservoir rock type of this reservoir are quite limited. Rock type definition in heterogeneous GL is very important aspect for reservoir modeling and will influences field development strategy. Rock type analysis in this study is using integration of core data, wireline logs and formation test data. Rock type determination applies porosity and permeability relationship approach from core data, which related to pore size distribution, lithofacies, and diagenesis. The analysis resulted eight rock types in the Globigerina Limestone reservoir. Result suggests that rock type definition is strongly influenced by lithofacies, which is dominated by packstone and wackestone - packstone. The diagenetic process in the deep burial environment causes decreasing of reservoir quality. Then the diagenesis process turns to be shallower in marine phreatic zone and causes dissolution which increasing the reservoir quality. Moreover, the analysis of rock type properties consist of clay volume, porosity, permeability, and water saturation. The good quality of a rock type will have the higher the porosity and permeability. The dominant rock type in this study area is RT4, which is identical to packstone lithofasies that has 0.40 v/v porosity and 5.2 mD as average permeability. The packstone litofacies could be found in RT 5, 6, 7, even 8 due to the increased of secondary porosity. It could also be found at a lower RT which is caused by intensive cementation.


SPE Journal ◽  
2019 ◽  
Vol 24 (06) ◽  
pp. 2889-2910 ◽  
Author(s):  
Pål Østebø Andersen ◽  
Dhruvit Satishchandra Berawala

Summary Numerical and analytical 1D solutions are presented to interpret the link between geochemical alterations and creep compaction (compaction under constant effective stress) in chalk cores. Chemically reactive flow enhancing chalk compaction is of significant importance for enhanced oil recovery (EOR), compaction, and subsidence in North Sea chalk reservoirs. The focus of this study is on Ca-, Mg-, and NaCl brines that interact with the chalk by the dissolution of calcite and the precipitation of magnesite. An explicit analytical solution is derived for the steady–state ion and dissolution–rate distributions at a given injected composition and injection rate. A mathematical description of creep compaction is proposed on the basis of applied affective stresses and rock ability to carry these stresses as a function of porosity. The reaction and compaction models are then coupled as follows: The compaction rate is assumed, which is enhanced by the dissolution rate, which can vary spatially. Furthermore, the solid volume changes by mineral dissolution and precipitation. Brine–dependent and nonuniform compaction is hence built into the model by means of the dissolution–rate distribution. The model is validated and parameterized against data from a total of 22 core samples from two chalk types (Åalborg and Liege) where reactive and inert brines were injected from ambient to Ekofisk–reservoir conditions (130°C). Experimentally measured effluent concentrations, distributions in mineralogy after flooding, and creep–compaction behavior were matched. Our model is the first to link a vast set of data on this subject and predict performance under new experimental conditions. This also represents a first step in upscaling such results from the laboratory toward the field. Our interpretations indicate that the two chalk types would respond differently chemically and by compaction to changes in the concentration and injection rate. Brines injected through Liege chalk appeared to approach stable oversaturation, while in Åalborg, the equilibrium condition was in agreement with geochemical calculations.


2020 ◽  
Vol 79 (18) ◽  
Author(s):  
Matthias Heidsiek ◽  
Christoph Butscher ◽  
Philipp Blum ◽  
Cornelius Fischer

Abstract The fluvial-aeolian Upper Rotliegend sandstones from the Bebertal outcrop (Flechtingen High, Germany) are the famous reservoir analog for the deeply buried Upper Rotliegend gas reservoirs of the Southern Permian Basin. While most diagenetic and reservoir quality investigations are conducted on a meter scale, there is an emerging consensus that significant reservoir heterogeneity is inherited from diagenetic complexity at smaller scales. In this study, we utilize information about diagenetic products and processes at the pore- and plug-scale and analyze their impact on the heterogeneity of porosity, permeability, and cement patterns. Eodiagenetic poikilitic calcite cements, illite/iron oxide grain coatings, and the amount of infiltrated clay are responsible for mm- to cm-scale reservoir heterogeneities in the Parchim formation of the Upper Rotliegend sandstones. Using the Petrel E&P software platform, spatial fluctuations and spatial variations of permeability, porosity, and calcite cements are modeled and compared, offering opportunities for predicting small-scale reservoir rock properties based on diagenetic constraints.


Water ◽  
2020 ◽  
Vol 12 (11) ◽  
pp. 3221
Author(s):  
Lucie Dal Soglio ◽  
Charles Danquigny ◽  
Naomi Mazzilli ◽  
Christophe Emblanch ◽  
Gérard Massonnat

The main outlets of karst systems are springs, the hydrographs of which are largely affected by flow processes in the unsaturated zone. These processes differ between the epikarst and transmission zone on the one hand and the matrix and conduit on the other hand. However, numerical models rarely consider the unsaturated zone, let alone distinguishing its subsystems. Likewise, few models represent conduits through a second medium, and even fewer do this explicitly with discrete features. This paper focuses on the interest of hybrid models that take into account both unsaturated subsystems and discrete conduits to simulate the reservoir-scale response, especially the outlet hydrograph. In a synthetic karst aquifer model, we performed simulations for several parameter sets and showed the ability of hybrid models to simulate the overall response of complex karst aquifers. Varying parameters affect the pathway distribution and transit times, which results in a large variety of hydrograph shapes. We propose a classification of hydrographs and selected characteristics, which proves useful for analysing the results. The relationships between model parameters and hydrograph characteristics are not all linear; some of them have local extrema or threshold limits. The numerous simulations help to assess the sensitivity of hydrograph characteristics to the different parameters and, conversely, to identify the key parameters which can be manipulated to enhance the modelling of field cases.


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