Strong mutual increase in the efficiency of isotope-selective laser IR dissociation of molecules under nonequilibrium thermodynamic conditions of the compression shock under irradiation in a bimolecular mixture

2020 ◽  
Vol 50 (11) ◽  
pp. 1036-1042
Author(s):  
G N Makarov ◽  
A N Petin
Keyword(s):  
Nonequilibrium Thermodynamic ◽  
Compression Shock ◽  
Thermodynamic Conditions

scholarly journals Voltage rise anemometry in turbulent flows applied to internal combustion engines

2021 ◽  
Vol 62 (6) ◽  
Author(s):  
Michael Wörner ◽  
Gregor Rottenkolber
Keyword(s):  
Turbulent Flows ◽  
Internal Combustion Engines ◽  
Clear Correlation ◽  
Combustion Engines ◽  
Mean Flow ◽  
Voltage Rise ◽  
Mathematical Correlation ◽  
Thermodynamic Conditions ◽  
Secondary Voltage ◽  
Cylinder Flow

AbstractIn an experimental procedure, a voltage rise anemometry is developed as a measurement technique for turbulent flows. Initially, fundamental investigations on a specific wind tunnel were performed for basic understanding and calibration purpose. Thus, a mathematical correlation is derived for calculating flow from measured secondary voltage of an ignition system under different thermodynamic conditions. Subsequently, the derived method was applied on a spark-ignited engine to measure in-cylinder flow. Therefore, no changes on combustion chamber were necessary avoiding any interferences of the examined flow field. Comparing four different engine configurations, a study of mean flow and turbulence was performed. Moreover, the results show a clear correlation between measured turbulence and analysed combustion parameters. Graphic abstract

scholarly journals Crystal growth of clathrate hydrate formed with H2 + CO2 mixed gas and tetrahydropyran

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Meku Maruyama ◽  
Riku Matsuura ◽  
Ryo Ohmura
Keyword(s):  
Crystal Growth ◽  
Synthesis Gas ◽  
Water System ◽  
Hydrate Formation ◽  
Growth Dynamics ◽  
Operating Conditions ◽  
Mixed Gas ◽  
Thermodynamic Conditions ◽  
The Individual ◽  
And Storage

AbstractHydrate-based gas separation technology is applicable to the CO2 capture and storage from synthesis gas mixture generated through gasification of fuel sources including biomass. This paper reports visual observations of crystal growth dynamics and crystal morphology of hydrate formed in the H2 + CO2 + tetrahydropyran (THP) + water system with a target for developing the hydrate-based CO2 separation process design. Experiments were conducted at a temperature range of 279.5–284.9 K under the pressure of 4.9–5.3 MPa. To simulate the synthesis gas, gas composition in the gas phase was maintained around H2:CO2 = 0.6:0.4 in mole fraction. Hydrate crystals were formed and extended along the THP/water interface. After the complete coverage of the interface to shape a polycrystalline shell, hydrate crystals continued to grow further into the bulk of liquid water. The individual crystals were identified as hexagonal, tetragonal and other polygonal-shaped formations. The crystal growth rate and the crystal size varied depending on thermodynamic conditions. Implications from the obtained results for the arrangement of operating conditions at the hydrate formation-, transportation-, and dissociation processes are discussed.

scholarly journals Phase Diagram of Binary Alloy Nanoparticles under High Pressure

Materials ◽  
2021 ◽  
Vol 14 (11) ◽  
pp. 2929
Author(s):  
Han Gyeol Kim ◽  
Joonho Lee ◽  
Guy Makov
Keyword(s):  
Phase Diagram ◽  
Phase Diagrams ◽  
Interaction Parameter ◽  
Excess Volume ◽  
Eutectic Temperature ◽  
Calphad Method ◽  
Alloy Nanoparticles ◽  
Thermodynamic Conditions ◽  
Nanoparticle System ◽  
Pressure Phase

CALPHAD (CALculation of PHAse Diagram) is a useful tool to construct phase diagrams of various materials under different thermodynamic conditions. Researchers have extended the use of the CALPHAD method to nanophase diagrams and pressure phase diagrams. In this study, the phase diagram of an arbitrary A–B nanoparticle system under pressure was investigated. The effects of the interaction parameter and excess volume were investigated with increasing pressure. The eutectic temperature was found to decrease in most cases, except when the interaction parameter in the liquid was zero and that in the solid was positive, while the excess volume parameter of the liquid was positive. Under these conditions, the eutectic temperature increased with increasing pressure.

scholarly journals Coupled Preparation of Ferronickel and Cementitious Material from Laterite Nickel Ores

Materials ◽  
2020 ◽  
Vol 13 (21) ◽  
pp. 4992
Author(s):  
Ruimeng Shi ◽  
Xiaoming Li ◽  
Yaru Cui ◽  
Junxue Zhao ◽  
Chong Zou ◽  
...  
Keyword(s):  
Direct Reduction ◽  
Cementitious Materials ◽  
Tricalcium Silicate ◽  
Cementitious Material ◽  
Raw Material ◽  
Tricalcium Aluminate ◽  
Thermodynamic Conditions ◽  
Nickel Ores ◽  
Main Components ◽  
Factsage Software

Nickel slags can be produced through ferronickel preparation by the pyrometallurgical processing of laterite nickel ores; however, such techniques are underutilized at present, and serious environmental problems arise from the stockpiling of such nickel ores. In this study, a modification to the process of ferronickel preparation by the direct reduction of carbon bases in laterite nickel ores is proposed. The gangue from the ore is used as a raw material to prepare a cementitious material, with the main components of tricalcium silicate and tricalcium aluminate. By using FactSage software, thermodynamic calculations are performed to analyze the reduction of nickel and iron and the effect of reduction on the formation of tricalcium silicate and tricalcium aluminate. The feasibility of a coupled process to prepare ferronickel and cementitious materials by the direct reduction of laterite nickel ore and gangue calcination, respectively, is discussed under varying thermodynamic conditions. Different warming strategies are applied to experimentally verify the coupled reactions. The coupled preparation of ferronickel and cementitious materials with calcium silicate and calcium aluminate as the main phases in the same experimental process is realized.

scholarly journals High-enthalpy hypersonic flows

2020 ◽  
Vol 2 (1) ◽  
Author(s):  
Joseph J. S. Shang ◽  
Hong Yan
Keyword(s):  
Hypersonic Flow ◽  
High Speed ◽  
Quantum Physics ◽  
Nonequilibrium Thermodynamic ◽  
Strong Shock ◽  
Hypersonic Flows ◽  
Electrically Conducting ◽  
High Enthalpy ◽  
Speed Range ◽  
Flow Theories

Abstract Nearly all illuminating classic hypersonic flow theories address aerodynamic phenomena as a perfect gas in the high-speed range and at the upper limit of continuum gas domain. The hypersonic flow is quantitatively defined by the Mach number independent principle, which is derived from the asymptotes of the Rankine-Hugoniot relationship. However, most hypersonic flows encounter strong shock-wave compressions resulting in a high enthalpy gas environment that always associates with nonequilibrium thermodynamic and quantum chemical-physics phenomena. Under this circumstance, the theoretic linkage between the microscopic particle dynamics and macroscopic thermodynamics properties of gas is lost. When the air mixture is ionized to become an electrically conducting medium, the governing physics now ventures into the regimes of quantum physics and electromagnetics. Therefore, the hypersonic flows are no longer a pure aerodynamics subject but a multidisciplinary science. In order to better understand the realistic hypersonic flows, all pertaining disciplines such as the nonequilibrium chemical kinetics, quantum physics, radiative heat transfer, and electromagnetics need to bring forth.

scholarly journals Octane Index Applicability over the Pressure-Temperature Domain

Energies ◽  
2021 ◽  
Vol 14 (3) ◽  
pp. 607
Author(s):  
Tommy R. Powell ◽  
James P. Szybist ◽  
Flavio Dal Forno Chuahy ◽  
Scott J. Curran ◽  
John Mengwasser ◽  
...  
Keyword(s):  
High Efficiency ◽  
National Laboratory ◽  
Operating Conditions ◽  
Dominant Factor ◽  
Compression Ignition ◽  
Oak Ridge ◽  
Operating Modes ◽  
Wide Range ◽  
Thermodynamic Conditions ◽  
Si Engines

Modern boosted spark-ignition (SI) engines and emerging advanced compression ignition (ACI) engines operate under conditions that deviate substantially from the conditions of conventional autoignition metrics, namely the research and motor octane numbers (RON and MON). The octane index (OI) is an emerging autoignition metric based on RON and MON which was developed to better describe fuel knock resistance over a broader range of engine conditions. Prior research at Oak Ridge National Laboratory (ORNL) identified that OI performs reasonably well under stoichiometric boosted conditions, but inconsistencies exist in the ability of OI to predict autoignition behavior under ACI strategies. Instead, the autoignition behavior under ACI operation was found to correlate more closely to fuel composition, suggesting fuel chemistry differences that are insensitive to the conditions of the RON and MON tests may become the dominant factor under these high efficiency operating conditions. This investigation builds on earlier work to study autoignition behavior over six pressure-temperature (PT) trajectories that correspond to a wide range of operating conditions, including boosted SI operation, partial fuel stratification (PFS), and spark-assisted compression ignition (SACI). A total of 12 different fuels were investigated, including the Co-Optima core fuels and five fuels that represent refinery-relevant blending streams. It was found that, for the ACI operating modes investigated here, the low temperature reactions dominate reactivity, similar to boosted SI operating conditions because their PT trajectories lay close to the RON trajectory. Additionally, the OI metric was found to adequately predict autoignition resistance over the PT domain, for the ACI conditions investigated here, and for fuels from different chemical families. This finding is in contrast with the prior study using a different type of ACI operation with different thermodynamic conditions, specifically a significantly higher temperature at the start of compression, illustrating that fuel response depends highly on the ACI strategy being used.

Sign in / Sign up

Export Citation Format

Share Document