Characterization of primary precipitate composition formed during co-removal of Cr(VI) with Cu(II) in synthetic wastewater

2005 ◽  
Vol 13 (6) ◽  
pp. 379-385 ◽  
Author(s):  
Jing-Mei Sun ◽  
Wen-Ting Zhu ◽  
Ju-Chang Huang
1992 ◽  
Vol 57 (12) ◽  
pp. 2529-2538 ◽  
Author(s):  
Krasimir Ivanov ◽  
Penka Litcheva ◽  
Dimitar Klissurski

Mn-Mo-O catalysts with a different Mo/Mn ratio have been prepared by precipitation. The precipitate composition as a function of solution concentration and pH was studied by X-ray, IR, thermal and chemical methods. Formation of manganese molybdates with MnMoO4.1.5H2O, Mn3Mo3O12.2.5H2O, and Mn3Mo4O15.4H2O composition has been supposed. It is concluded that pure MnMoO4 may be obtained in both acid and alkaline media, the pH values depending on the concentration of the initial solutions. The maximum Mo/Mn ratio in the precipitates is 1.33. The formation of pure Mn3Mo4O15.4H2O is possible in weakly acidic media. This process is favoured by increasing the concentration of initial solutions.


2016 ◽  
Vol 102 ◽  
pp. 594-606 ◽  
Author(s):  
Dongqing Zhang ◽  
Antoine Prandota Trzcinski ◽  
Chinagarn Kunacheva ◽  
David C. Stuckey ◽  
Yu Liu ◽  
...  

2014 ◽  
Vol 32 (7) ◽  
pp. 1220-1226
Author(s):  
Yusheng SHE ◽  
Weihua SUN ◽  
Yingying ZHAN ◽  
Xingyi LIN ◽  
Qi ZHENG

2011 ◽  
Vol 63 (4) ◽  
pp. 583-589 ◽  
Author(s):  
Hainan Ai ◽  
Daijun Zhang ◽  
Peili Lu ◽  
Qiang He

Characterization of volatile fatty acid (VFA) in wastewater is significant for understanding the wastewater nature and the wastewater treatment process optimization based on the usage of Activated Sludge Models (ASMs). In this study, a nine-point pH titration method was developed for the determination of low-concentration VFA in municipal wastewater. The method was evaluated using synthetic wastewater containing VFA with the concentration of 10–50 mg/l and the possible interfering buffer systems of carbonate, phosphate and ammonium similar to those in real municipal wastewater. In addition, the further evaluation was conducted through the assay of real wastewater using chromatography as reference. The results showed that the recovery of VFA in the synthetic wastewater was 92%–102 and the coefficient of variance (CV) of reduplicate measurements 1.68%–4.72%. The changing content of the buffering substances had little effect on the accuracy of the method. Moreover, the titration method was agreed with chromatography in the determination of VFA in real municipal wastewater with R2= 0.9987 and CV =1.3-1.7. The nine-point pH titration method is capable of satisfied determination of low-concentration VFA in municipal wastewater.


Author(s):  
K. R. Kinsman

The prime function of transmission electron microscopy in the study of solid state precipitation phenomena is detailed structural characterization of the precipitate and matrix. It is fundamental that the investigator be aware of the possible structural anomalies associated with the technique. An illustration is the response to electrochemical thinning of iron-rich precipitates produced during isothermal reaction of a Cu-2.56%Fe alloy. Although the fcc(austenite) → bcc(martensite) transformation occurs at about 400°C in a bulk alloy of precipitate composition, precipitates in the copper matrix are constrained in their fee state to below 77°K, so long as the specimen remains plastically undeformed. Here it is shown that such precipitates can be induced to transform in carefully handled undeformed foils simply through reduction of the constraints offered by the surrounding matrix (Fig.1).


2020 ◽  
Vol 240 ◽  
pp. 116639 ◽  
Author(s):  
Fatemeh Sadat Hoseinian ◽  
Bahram Rezai ◽  
Elaheh Kowsari ◽  
Amutha Chinnappan ◽  
Seeram Ramakrishna

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