The rGO/CuO composite materials as photocatalyst for CO2 conversion into methanol under UV light

2021 ◽  
Author(s):  
Diah Susanti ◽  
Yeny Widya Rakhmawati ◽  
Lukman Noerochim ◽  
Hariyati Purwaningsih ◽  
Haniffudin Nurdiansah
2018 ◽  
Vol 85 (13) ◽  
pp. 1203-1217 ◽  
Author(s):  
Ketsuda Kongsawatvoragul ◽  
Saran Kalasina ◽  
Montakan Suksomboon ◽  
Nutthaphon Phattharasupakun ◽  
Juthaporn Wutthiprom ◽  
...  

RSC Advances ◽  
2020 ◽  
Vol 10 (26) ◽  
pp. 15072-15078 ◽  
Author(s):  
Mohsen Lashgari ◽  
Sanaz Soodi

CNT-based nanocomposite photocatalyst/solar-energy materials serving as in situ hydrogen generators for selective conversion [hydrogenation] of CO2 into methanol: a mechanistic/photoelectrochemical outlook.


Author(s):  
Amir Hussain Idrisi ◽  
Abdel-Hamid Ismail Mourad ◽  
Beckry Abdel-Magid ◽  
Mohammad Mozumder ◽  
Yaser Afifi

Abstract Composite materials are being used in many industrial applications such as automobile, aerospace, marine, oil and gas industries due to their high strength to weight ratio. The long-term effect of sustained loads and environmental factors that include exposure to UV light, temperature, and moisture have been under investigation by many researchers. The major objective of this study is to evaluate the effects of harsh environment (e.g. seawater and high temperature) on the structural properties of E-glass epoxy composite materials. These effects were studied in terms of seawater absorption, permeation of salt and contaminants, chemical and physical bonds at the interface and degradation in mechanical properties. Samples were immersed in seawater at room temperature (23°C), 65°C and 90°C for the duration of 6 months. Results show that seawater absorption increased with immersion time at 23°C and 65°C, whereas the weight of the specimens decreased at 90°C. The moisture causes swelling at 23°C and 65°C and breakdown of chemical bonds between fiber and matrix at 90°C. It is observed that high temperature accelerates the degradation of the E-glass epoxy composite. At 90°C, the tensile strength of E-glass epoxy sharply decreased by 72.92% but no significant change was observed in modulus of elasticity of the composite.


2015 ◽  
Vol 18 (4) ◽  
pp. 125-137
Author(s):  
Linh Nhut Ho ◽  
Tri Van Tran ◽  
Thu Hoai Nguyen ◽  
Nguyen Phuc Le

The objective of this study is to increase CO2 conversion into methanol by applying zeolite membrane technology for reaction, using catalytic component with 16 % CeO2 -30 % CuO - 30 % ZnO/ 24 % Al2O3. Different experiments were conducted to identify the appropriate zeolite membrane to separate by-products. The following experiments determined the appropriate conditions for synthesis of methanol process from CO2 in reaction system with chosen zeolite membrane. The results of study showed that, NaA membrane could separate water out of the gas mixture after reaction the most effectively. This will limit the influence of water by-product on the catalytic activity and produce larger methanol amount in comparison to the reaction system without zeolite membrane. NaA zeolite membrane has shown its good performance since the produced methanol is 1.4 to 1.7 times higher than of non-membrane reaction system. The optimal conditions for methanol synthesis reaction from CO2 using the NaA zeolite membrane are: temperature from 220 to 240 oC, pressure is 5 bar, flow of materials input is 200 ml/min, the ratio of H2:CO2 is 3:1. Potential applications of the methanol synthesis from CO2 using zeolite membrane reactor system is absolutely suitable.


2014 ◽  
Vol 548-549 ◽  
pp. 25-28
Author(s):  
Tian Shu Wang ◽  
Sarulaaodu Bao ◽  
Ling Xu ◽  
Zong Rui Liu ◽  
Li Mei Duan

In this paper, CdS sample and phosphotungstic acid/CdS composite materials were prepared by hydrothermal synthesis and impregnation method, respectively. These samples were characterized by FT-IR, XRD and TEM. The characteristic peaks of phosphotungstic acid and CdS appeared in IR spectra of phosphotungstic acid /CdS composite samples. Using the degradation of Rhodamine B and Methylene blue solutions as the model reaction, respectively, the photocatalytic degradation performance of CdS, phosphotungstic acid and their composite samples was discussed under the irradiation of UV light or sunlight. The results showed the degradation effect of phosphotungstic acid /CdS to Rhodamine B and Methylene blue solution was better than CdS under the irradiation of 250 W mercury lamp or sunlight. Composite sample 1 had the best photocatalytic activity and its degradation rate on Rhodamine B was 85.2 % at 120 mins with pH 3.5 under sunlight, and the degradation rate of Methylene blue reached about 92.1% at 120 mins with pH 6.0 under sunlight.


2015 ◽  
Vol 1112 ◽  
pp. 406-409
Author(s):  
Mega Nurhanisa ◽  
Mikrajuddin Abdullah

Various attempts have been made to solve problems of abundant solid wastes in big cities. One approach is the utilization of domestic waste to make composite materials, such as particle board. To increase the attractiveness of the product in this study we develop prototypes of statues using composites of domestic solid wastes and then coated the statues using carboneus phosphor material to produce artistic color under ultraviolet illumination. The composite materials were derived from domestic waste such as leaves, paper, and plastics as a filler and polyvinil acetate as a matrix. The coated material was a luminescent colloidal carbon particles that have been synthesized from urea ((NH2)2CO) and citric acid (C6H8O7) using a simple heating method. The colloidan carbon emits a luminescence peak at around 457 nm (blue color) under UV illumination. The produced statue from the domectic wastes composites we simply coated by a mixture of epoxy resin and phosphor material. Under UV light, the statue surface shows a bluish white luminescence.


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