scholarly journals Ultrasonic investigation of the evaporation dynamics of subnanoliter droplets

2021 ◽  
Vol 130 (22) ◽  
pp. 224702
Author(s):  
Quy Raven Luong ◽  
Andreas Hefele ◽  
Alexander Reiner ◽  
Andreas Hörner ◽  
Achim Wixforth
Langmuir ◽  
2013 ◽  
Vol 29 (34) ◽  
pp. 10785-10795 ◽  
Author(s):  
Susmita Dash ◽  
Suresh V. Garimella

2012 ◽  
Vol 12 (8) ◽  
pp. 3591-3599 ◽  
Author(s):  
O. Kupiainen ◽  
I. K. Ortega ◽  
T. Kurtén ◽  
H. Vehkamäki

Abstract. The substitution of ammonia by dimethylamine in sulfuric acid – ammonia – dimethylamine clusters was studied using a collision and evaporation dynamics model. Quantum chemical formation free energies were computed using B3LYP/CBSB7 for geometries and frequencies and RI-CC2/aug-cc-pV(T+d)Z for electronic energies. We first demonstrate the good performance of our method by a comparison with an experimental study investigating base substitution in positively charged clusters, and then continue by simulating base exchange in neutral clusters, which cannot be measured directly. Collisions of a dimethylamine molecule with an ammonia containing positively charged cluster result in the instantaneous evaporation of an ammonia molecule, while the dimethylamine molecule remains in the cluster. According to our simulations, a similar base exchange can take place in neutral clusters, although the overall process is more complicated. Neutral sulfuric acid – ammonia clusters are significantly less stable than their positively charged counterparts, resulting in a competition between cluster evaporation and base exchange.


2021 ◽  
Vol 62 (7) ◽  
Author(s):  
A. Alperen Günay ◽  
Moon-Kyung Kim ◽  
Xiao Yan ◽  
Nenad Miljkovic ◽  
Soumyadip Sett

2017 ◽  
Vol 121 ◽  
pp. 04001 ◽  
Author(s):  
Cătălin Gheorghe Amza ◽  
Aurelian Zapciu ◽  
Diana Popescu ◽  
Octav Teodorescu

2004 ◽  
Vol 77 (4) ◽  
pp. 345-358 ◽  
Author(s):  
J. Banys ◽  
J. Macutkevic ◽  
V. Samulionis ◽  
A. Brilingas ◽  
Yu. Vysochanskii

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