scholarly journals Magnetization relaxation and search for the magnetic gap in bulk-insulating V-doped (Bi, Sb)2Te3

2021 ◽  
Vol 119 (13) ◽  
pp. 132404
Author(s):  
E. Golias ◽  
E. Weschke ◽  
T. Flanagan ◽  
E. Schierle ◽  
A. Richardella ◽  
...  
2013 ◽  
Vol 3 (2) ◽  
pp. 161-171 ◽  
Author(s):  
Dimitris Alexandropoulos ◽  
Chaoran Li ◽  
Catherine Raptopoulou ◽  
Vassilis Psycharis ◽  
Wolfgang Wernsdorfer ◽  
...  

2020 ◽  
Vol 7 (1) ◽  
pp. 1
Author(s):  
Joydev Acharya ◽  
Pankaj Kalita ◽  
Vadapalli Chandrasekhar

Single-molecule magnets involving monometallic 4f complexes have been investigated extensively in last two decades to understand the factors that govern the slow magnetization relaxation behavior in these complexes and to establish a magneto-structural correlation. The prime goal in this direction is to suppress the temperature independent quantum tunneling of magnetization (QTM) effect via fine-tuning the coordination geometry/microenvironment. Among the various coordination geometries that have been pursued, complexes containing high coordination number around Ln(III) are sparse. Herein, we present a summary of the various synthetic strategies that were used for the assembly of 10- and 12-coordinated Ln(III) complexes. The magnetic properties of such complexes are also described.


2003 ◽  
Vol 125 (12) ◽  
pp. 3576-3588 ◽  
Author(s):  
Monica Soler ◽  
Wolfgang Wernsdorfer ◽  
Khalil A. Abboud ◽  
John C. Huffman ◽  
Ernest R. Davidson ◽  
...  

1997 ◽  
Vol 58 (2) ◽  
pp. 89-92
Author(s):  
Rodica Bădescu ◽  
E. Luca ◽  
V. Bădescu ◽  
N. Rezlescu

2021 ◽  
Author(s):  
Maria-Gabriela Alexandru ◽  
Diana Visinescu ◽  
Beatrice Cula ◽  
Sergiu Shova ◽  
Renato Rabelo ◽  
...  

A rare isostructural series of cyanido-bridged {FeIIILnIII}2 square-shaped heterobimetallic complexes were obtained, in which TbIII, DyIII and ErIII derivatives show slow magnetization relaxation under zero and non-zero static fields.


2008 ◽  
Vol 83 (3) ◽  
pp. 37006 ◽  
Author(s):  
G. de Loubens ◽  
D. A. Garanin ◽  
C. C. Beedle ◽  
D. N. Hendrickson ◽  
A. D. Kent

1995 ◽  
Vol 88 (5) ◽  
pp. 953-956
Author(s):  
A.M. Witowski ◽  
H.P. Moll ◽  
P. Wyder ◽  
G. Karczewski ◽  
T. Wojtowicz ◽  
...  

2020 ◽  
Author(s):  
Maciej Korzynski ◽  
Zachariah Berkson ◽  
Boris Le Guennic ◽  
Olivier Cador ◽  
Christophe Copéret

Single-molecule magnets (SMMs) hold promise for unmatched information storage density as well as applications in quantum computing and spintronics. To date, the most successful SMMs are organometallic lanthanide complexes. However, their surface immobilization, one of the requirements for device fabrication and commercial application, remains challenging due to sensitivity of magnetic properties to small changes in the electronic structure of the parent SMM. Thus, finding controlled approaches to SMM surface deposition is a timely challenge. In this contribution we apply the concept of isolobality to identify siloxides present at the surface of partially dehydroxylated silica as a suitable replacement for archetypal ligand architectures in organometallic SMMs. We demonstrate theoretically and experimentally that isolated siloxide anchorages not only enable successful immobilization, but also lead to two-orders-of-magnitude increase in magnetization relaxation times and provide magnetic site dilution.


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