A high temperature cell for investigating interfacial structure on the molecular scale in molten salt/alloy systems

2021 ◽  
Vol 92 (12) ◽  
pp. 123903
Author(s):  
James F. Browning ◽  
Joohyun Seo ◽  
John F. Wenzel ◽  
Gabriel M. Veith ◽  
Mathieu Doucet ◽  
...  
Keyword(s):  
High Temperature ◽  
Molten Salt ◽  
Interfacial Structure ◽  
Molecular Scale ◽  
Alloy Systems

scholarly journals Insight into the Mechanical Performance of the UHPC Repaired Cementitious Composite System after Exposure to High Temperatures

Materials ◽  
2021 ◽  
Vol 14 (15) ◽  
pp. 4095
Author(s):  
Qing Chen ◽  
Zhiyuan Zhu ◽  
Rui Ma ◽  
Zhengwu Jiang ◽  
Yao Zhang ◽  
...  
Keyword(s):  
Compressive Strength ◽  
High Temperature ◽  
High Temperatures ◽  
Bonding Strength ◽  
Composite System ◽  
Mechanical Performance ◽  
High Performance Concrete ◽  
Interfacial Structure ◽  
Cementitious Composite ◽  
Average Percentage

In this paper, the mechanical performance of an ultra-high-performance concrete (UHPC) repaired cementitious composite system, including the old matrix and the new reinforcement (UHPC), under various high temperature levels (20 °C, 100 °C, 300 °C, and 500 °C) was studied. In this system, UHPC reinforced with different contents of steel fibers and polypropylene (PP) fibers was utilized. Moreover, the physical, compressive, bonding, and flexural behaviors of the UHPC repaired system after being exposed to different high temperatures were investigated. Meanwhile, X-ray diffraction (XRD), baseline evaluation test (BET), and scanning electron microscope (SEM) tests were conducted to analyze the effect of high temperature on the microstructural changes in a UHPC repaired cementitious composite system. Results indicate that the appearance of the bonded system changed, and its mass decreased slightly. The average percentage of residual mass of the system was 99.5%, 96%, and 94–95% at 100 °C, 300 °C, and 500 °C, respectively. The residual compressive strength, bonding strength, and flexural performance improved first and then deteriorated with the increase of temperature. When the temperature reached 500 °C, the compressive strength, bonding strength, and flexural strength decreased by about 20%, 30%, and 15% for the UHPC bonded system, respectively. Under high temperature, the original components of UHPC decreased and the pore structure deteriorated. The cumulative pore volume at 500 °C could reach more than three times that at room temperature (about 20 °C). The bonding showed obvious deterioration, and the interfacial structure became looser after exposure to high temperature.

Absorption and Stripping of CO2 with a Molten Salt Slurry in a Bubble Column at High Temperature

2006 ◽  
Vol 29 (9) ◽  
pp. 1118-1121 ◽  
Author(s):  
K. Terasaka ◽  
Y. Suyama ◽  
K. Nakagawa ◽  
M. Kato ◽  
K. Essaki
Keyword(s):  
High Temperature ◽  
Molten Salt ◽  
Bubble Column

Study on interfacial structure and high temperature mechanical properties of CF/PPEK and CF/PPES composites

2004 ◽  
Vol 11 (7) ◽  
pp. 441-452 ◽  
Author(s):  
Liu Wenbo ◽  
Wang Rongguo ◽  
Zhang Hongtao ◽  
Jia Jin ◽  
Jiao Weicheng ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
High Temperature ◽  
Interfacial Structure ◽  
High Temperature Mechanical Properties

Electrochemical Studies on High-Temperature Corrosion of Silicon-Iron Coatings and Iron Aluminide Intermetallic Alloys by Molten Salts

CORROSION ◽  
2001 ◽  
Vol 57 (6) ◽  
pp. 489-496 ◽  
Author(s):  
M. Amaya ◽  
J. Porcayo-Calderon ◽  
L. Martinez
Keyword(s):  
High Temperature ◽  
Molten Salt ◽  
Electric Power ◽  
Molten Salts ◽  
Corrosion Current ◽  
High Temperature Corrosion ◽  
Iron Aluminide ◽  
Fuel Oil ◽  
Silicon Iron ◽  
Salt Corrosion

Abstract The performance of Fe-Si coatings and an iron aluminide (FeAl) intermetallic alloy (FeAl40at%+0.1at%B+10vol%Al2O3) in molten salts containing vanadium pentoxide (V2O5) and sodium sulfate (Na2SO4) is reported. Corrosion and fouling by ash deposits containing V2O5 and Na2SO4 are typical corrosion problems in fuel oil-fired electric power units. High-temperature corrosion tests were performed using both electrochemical polarization and immersion techniques. The temperature interval of this study was 600°C to 900°C, and the molten salts were 80wt%V2O5-20wt%Na2SO4. Curves of corrosion current density vs temperature obtained by the potentiodynamic studies are reported, as well as the weight loss vs temperature curves from molten salt immersion tests. Both Fe-Si coatings and FeAl40at%+0.1at%B+10vol%Al2O3 showed good behavior against molten salt corrosion. The final results show the potential of these coatings and alloys to solve the high-temperature corrosion in fuel oil-fired electric power units.

Molten salt electrolytes for high-temperature lithium cells

1989 ◽  
Vol 26 (1-2) ◽  
pp. 37-48 ◽  
Author(s):  
D.R. Vissers ◽  
L. Redey ◽  
T.D. Kaun
Keyword(s):  
High Temperature ◽  
Molten Salt ◽  
Molten Salt Electrolytes ◽  
Lithium Cells

Electrolytic synthesis of ZrSi/ZrC nanocomposites from ZrSiO4 and carbon black powder in molten salt

2020 ◽  
Vol 111 (7) ◽  
pp. 581-586
Author(s):  
Li Ming ◽  
Wu Xiufeng
Keyword(s):  
Electron Microscopy ◽  
High Temperature ◽  
Carbon Black ◽  
Molten Salt ◽  
Cell Voltage ◽  
Black Powder ◽  
X Ray ◽  
Carbon Black Powder ◽  
Transmission Electron ◽  
A Cell

Abstract ZrSi/ZrC nanocomposites have stable high-temperature properties, where conventional materials cannot meet increasingly demanding high-temperature environments. In this paper, the microstructure and electrochemical reduction mechanism of ZrSi/ZrC nanocomposites have been studied. A mixture of ZrSiO4 and carbon black powder was processed using ball grinding, sheet pressing, and sintering, and cylindrically-sintered sheet was prepared as the cathode for the electrolytic work. A high purity graphite rod was utilized as the anode.The microstructure of the electrolytic product was characterized and analyzed using X-ray diffraction, scanning electron microscopy equipped with energy-dispersive X-ray spectroscopy, and transmission electron microscopy. The experimental results showed that the diameter of the as-synthesized ZrSi/ ZrC fibers typically range between 100-400 nm when produced by the electrolysis of sintered pellets in equimolar CaCl2-NaCl molten salt at 850°C with a cell voltage of 2.8 V for 20 h under an argon atmosphere. The nanofibers were formed in core-shell microstructures that overlap and grow.

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