A study on dielectric behavior, AC and DC conductivities of PANI-Al2O3 composites

2021 ◽  
Author(s):  
Shweta C. Gumma ◽  
Anil Kumar G. Bidve ◽  
Nirdosh Patil ◽  
Bharati Basavaraj
2019 ◽  
Author(s):  
Johannes P. Dürholt ◽  
Babak Farhadi Jahromi ◽  
Rochus Schmid

Recently the possibility of using electric fields as a further stimulus to trigger structural changes in metal-organic frameworks (MOFs) has been investigated. In general, rotatable groups or other types of mechanical motion can be driven by electric fields. In this study we demonstrate how the electric response of MOFs can be tuned by adding rotatable dipolar linkers, generating a material that exhibits paralectric behavior in two dimensions and dielectric behavior in one dimension. The suitability of four different methods to compute the relative permittivity κ by means of molecular dynamics simulations was validated. The dependency of the permittivity on temperature T and dipole strength μ was determined. It was found that the herein investigated systems exhibit a high degree of tunability and substantially larger dielectric constants as expected for MOFs in general. The temperature dependency of κ obeys the Curie-Weiss law. In addition, the influence of dipolar linkers on the electric field induced breathing behavior was investigated. With increasing dipole moment, lower field strength are required to trigger the contraction. These investigations set the stage for an application of such systems as dielectric sensors, order-disorder ferroelectrics or any scenario where movable dipolar fragments respond to external electric fields.


2015 ◽  
Vol 241 ◽  
pp. 226-236 ◽  
Author(s):  
Neha Solanki ◽  
Rajshree B. Jotania

Influence of Ca substitution on structural, magnetic and dielectric properties of Ba3Co2-xCaxFe24O41(where x = 0.0, 0.2, 0.4, 0.6, 0.8 and 1.0), prepared by Sol-Gel auto-combustion method, has been investigated in present studies. The obtained powder was sintered at 950 oC for 4 hrs. in the static air atmosphere. Structural analysis of Ca-doped Ba3Co2-xCaxFe24O41powders revealed pure Z-type hexaferrite phase at low temperature. The frequency dependent dielectric constant (Єʹ) and magnetic properties such as remanent magnetization (Mr), saturation magnetization (Ms) and coercivity (Hc) were studied. It is observed that coercivity increased gradually with increase in calcium content. The real dielectric constant (Єʹ) and dielectric loss tangent (tan δ) were studied in the frequency range of 20Hz to 2MHz. The dielectric parameters for all samples show normal dielectric behavior as observed in hexaferrites. Contents of Paper


Author(s):  
Qaisar Khan ◽  
Abdul Majeed ◽  
Nisar Ahmad ◽  
Iftikhar Ahmad ◽  
Rashid Ahmad

2015 ◽  
Vol 2015 (10) ◽  
Author(s):  
Elliot Banks ◽  
Aristomenis Donos ◽  
Jerome P. Gauntlett

2006 ◽  
Vol 13 (3) ◽  
pp. 532-538 ◽  
Author(s):  
A.A. Shayegani Akmal ◽  
H. Borsi ◽  
E. Gockenbach ◽  
V. Wasserberg ◽  
H. Mohseni

2002 ◽  
Vol 751 ◽  
Author(s):  
Qinglei Wang ◽  
Guoda D. Lian ◽  
Elizabeth C. Dickey

ABSTRACTSolute segregation to grain boundaries is a fundamental phenomenon in polycrystalline metal-oxide electroceramics that has enormous implications for the macroscopic dielectric behavior of the materials. This paper presents a systematic study of solute segregation in a model dielectric, titanium dioxide. We investigate the relative role of the electrostatic versus strain energy driving forces for segregation by studying yttrium-doped specimens. Through analytical transmission electron microscopy studies, we quantitatively determine the segregation behavior of the material. The measured Gibbsian interfacial excesses are compared to thermodynamic predictions.


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