scholarly journals The impact of water vapor on the OH reactivity toward CH3CHO at ultra-low temperatures (21.7–135.0 K): Experiments and theory

2021 ◽  
Vol 155 (3) ◽  
pp. 034306
Author(s):  
E. M. Neeman ◽  
D. González ◽  
S. Blázquez ◽  
B. Ballesteros ◽  
A. Canosa ◽  
...  
Keyword(s):  
Water Vapor ◽  
Low Temperatures ◽  
The Impact

scholarly journals The Impact of the Electric Field on Surface Condensation of Water Vapor: Insight from Molecular Dynamics Simulation

Nanomaterials ◽  
2019 ◽  
Vol 9 (1) ◽  
pp. 64 ◽  
Author(s):  
Qin Wang ◽  
Hui Xie ◽  
Zhiming Hu ◽  
Chao Liu
Keyword(s):  
Molecular Dynamics ◽  
Water Vapor ◽  
Electric Field ◽  
Intermolecular Forces ◽  
Dynamics Simulation ◽  
Water Molecules ◽  
Attraction Force ◽  
Condensation Rate ◽  
Shape Transformation ◽  
The Impact

In this study, molecular dynamics simulations were carried out to study the coupling effect of electric field strength and surface wettability on the condensation process of water vapor. Our results show that an electric field can rotate water molecules upward and restrict condensation. Formed clusters are stretched to become columns above the threshold strength of the field, causing the condensation rate to drop quickly. The enhancement of surface attraction force boosts the rearrangement of water molecules adjacent to the surface and exaggerates the threshold value for shape transformation. In addition, the contact area between clusters and the surface increases with increasing amounts of surface attraction force, which raises the condensation efficiency. Thus, the condensation rate of water vapor on a surface under an electric field is determined by competition between intermolecular forces from the electric field and the surface.

scholarly journals Reciprocal hemizygosity analysis reveals that the Saccharomyces cerevisiae CGI121 gene affects lag time duration in synthetic grape must

2021 ◽  
Author(s):  
Runze Li ◽  
Rebecca C Deed
Keyword(s):  
Saccharomyces Cerevisiae ◽  
Low Temperatures ◽  
Lag Time ◽  
Lag Phase ◽  
Phenotypic Traits ◽  
Time Duration ◽  
Phase Duration ◽  
Grape Must ◽  
The Impact ◽  
Reciprocal Hemizygosity Analysis

Abstract It is standard practice to ferment white wines at low temperatures (10-18 °C). However, low temperatures increase fermentation duration and risk of problem ferments, leading to significant costs. The lag duration at fermentation initiation is heavily impacted by temperature; therefore, identification of Saccharomyces cerevisiae genes influencing fermentation kinetics is of interest for winemaking. We selected 28 S. cerevisiae BY4743 single deletants, from a prior list of open reading frames (ORFs) mapped to quantitative trait loci (QTLs) on chromosomes VII and XIII, influencing the duration of fermentative lag time. Five BY4743 deletants, Δapt1, Δcgi121, Δclb6, Δrps17a, and Δvma21, differed significantly in their fermentative lag duration compared to BY4743 in synthetic grape must (SGM) at 15 °C, over 72 h. Fermentation at 12.5 °C for 528 h confirmed the longer lag times of BY4743 Δcgi121, Δrps17a, and Δvma21. These three candidate ORFs were deleted in S. cerevisiae RM11-1a and S288C to perform single reciprocal hemizygosity analysis (RHA). RHA hybrids and single deletants of RM11-1a and S288C were fermented at 12.5 °C in SGM and lag time measurements confirmed that the S288C allele of CGI121 on chromosome XIII, encoding a component of the EKC/KEOPS complex, increased fermentative lag phase duration. Nucleotide sequences of RM11-1a and S288C CGI121 alleles differed by only one synonymous nucleotide, suggesting that intron splicing, codon bias, or positional effects might be responsible for the impact on lag phase duration. This research demonstrates a new role of CGI121 and highlights the applicability of QTL analysis for investigating complex phenotypic traits in yeast.

scholarly journals Impacts of Ozone Changes in the Tropopause Layer on Stratospheric Water Vapor

Atmosphere ◽  
2021 ◽  
Vol 12 (3) ◽  
pp. 291
Author(s):  
Jinpeng Lu ◽  
Fei Xie ◽  
Hongying Tian ◽  
Jiali Luo
Keyword(s):  
Water Vapor ◽  
Ozone Depletion ◽  
Climate Model ◽  
Global Climate ◽  
Stratospheric Water Vapor ◽  
Radiative Processes ◽  
Low Latitudes ◽  
Cold Point ◽  
The Impact ◽  
Tropopause Temperature

Stratospheric water vapor (SWV) changes play an important role in regulating global climate change, and its variations are controlled by tropopause temperature. This study estimates the impacts of tropopause layer ozone changes on tropopause temperature by radiative process and further influences on lower stratospheric water vapor (LSWV) using the Whole Atmosphere Community Climate Model (WACCM4). It is found that a 10% depletion in global (mid-low and polar latitudes) tropopause layer ozone causes a significant cooling of the tropical cold-point tropopause with a maximum cooling of 0.3 K, and a corresponding reduction in LSWV with a maximum value of 0.06 ppmv. The depletion of tropopause layer ozone at mid-low latitudes results in cooling of the tropical cold-point tropopause by radiative processes and a corresponding LSWV reduction. However, the effect of polar tropopause layer ozone depletion on tropical cold-point tropopause temperature and LSWV is opposite to and weaker than the effect of tropopause layer ozone depletion at mid-low latitudes. Finally, the joint effect of tropopause layer ozone depletion (at mid-low and polar latitudes) causes a negative cold-point tropopause temperature and a decreased tropical LSWV. Conversely, the impact of a 10% increase in global tropopause layer ozone on LSWV is exactly the opposite of the impact of ozone depletion. After 2000, tropopause layer ozone decreased at mid-low latitudes and increased at high latitudes. These tropopause layer ozone changes at different latitudes cause joint cooling in the tropical cold-point tropopause and a reduction in LSWV. Clarifying the impacts of tropopause layer ozone changes on LSWV clearly is important for understanding and predicting SWV changes in the context of future global ozone recovery.

Assessment of the Impact of Simulated Satellite Lidar Wind and Retrieved 183 GHz Water Vapor Observations on a Global Data Assimilation System

1990 ◽  
Vol 118 (12) ◽  
pp. 2513-2542 ◽  
Author(s):  
Ross N. Hoffman ◽  
Christopher Grassotti ◽  
Ronald G. Isaacs ◽  
Jean-Francois Louis ◽  
Thomas Nehrkorn ◽  
...  
Keyword(s):  
Water Vapor ◽  
Data Assimilation ◽  
Global Data Assimilation System ◽  
The Impact ◽  
Data Assimilation System ◽  
Global Data ◽  
Assimilation System

Analysis of Ferroelectric Microcapacitors by Scanning Probe Microscope

2004 ◽  
Vol 811 ◽  
Author(s):  
Nobuhiro Kin ◽  
Koichiro Honda
Keyword(s):  
High Temperatures ◽  
Low Temperatures ◽  
Evaluation System ◽  
Ferroelectric Material ◽  
Scanning Probe Microscope ◽  
Scanning Probe ◽  
Electrical Heater ◽  
Device Processing ◽  
Probe Microscope ◽  
The Impact

ABSTRACTTo develop higher density FRAM requires reducing cell size. Therefore, the size effects resulting from device processing and the material's physical properties must be measured. Therefore, analyzing the electric characteristics of a single bit cell capacitor has become important. Two known characteristics of ferroelectric material are that the Vc increases at low temperatures, and the Pr falls at high temperatures. To further evaluate the impact of temperature on ferroelectrics, we constructed a new evaluation system based on a scanning probe microscope, that can measure the electric characteristics of a single bit cell capacitor. This system can be used in the temperature range from −120 degrees to 300 degrees C. We accomplished this by circulating liquid nitrogen around a SPM stage and by using an electrical heater. We measured the electrical properties of ferroelectric microcapacitors by using a sample with IrOx/PZT/Pt structure. Our measurements revealed that 2Pr really increases at low temperatures, and Pr decreases at high temperatures. That is, we have shown that Vc increases 30% at low temperatures and Pr decreases 10% also in an actual FRAM single bit cell capacitor.

Real-time and near real-time ZTD from a local network of low-cost dual-frequency GNSS receivers.

2021 ◽  
Author(s):  
Tomasz Hadas ◽  
Grzegorz Marut ◽  
Jan Kapłon ◽  
Witold Rohm
Keyword(s):  
Water Vapor ◽  
Real Time ◽  
Low Cost ◽  
Weather Prediction ◽  
Local Network ◽  
System Component ◽  
Dual Frequency ◽  
Lower Accuracy ◽  
Gnss Receivers ◽  
The Impact

<p>The dynamics of water vapor distribution in the troposphere, measured with Global Navigation Satellite Systems (GNSS), is a subject of weather research and climate studies. With GNSS, remote sensing of the troposphere in Europe is performed continuously and operationally under the E-GVAP (http://egvap.dmi.dk/) program with more than 2000 permanent stations. These data are one of the assimilation system component of mesoscale weather prediction models (10 km scale) for many nations across Europe. However, advancing precise local forecasts for severe weather requires high resolution models and observing system.   Further densification of the tracking network, e.g. in urban or mountain areas, will be costly when considering geodetic-grade equipment. However, the rapid development of GNSS-based applications results in a dynamic release of mass-market GNSS receivers. It has been demonstrated that post-processing of GPS-data from a dual-frequency low-cost receiver allows retrieving ZTD with high accuracy. Although low-cost receivers are a promising solution to the problem of densifying GNSS networks for water vapor monitoring, there are still some technological limitations and they require further development and calibration.</p><p>We have developed a low-cost GNSS station, dedicated to real-time GNSS meteorology, which provides GPS, GLONASS and Galileo dual-frequency observations either in RINEX v3.04 format or via RTCM v3.3 stream, with either Ethernet or GSM data transmission. The first two units are deployed in a close vicinity of permanent station WROC, which belongs to the International GNSS Service (IGS) network. Therefore, we compare results from real-time and near real-time processing of GNSS observations from a low-cost unit with IGS Final products. We also investigate the impact of replacing a standard patch antenna with an inexpensive survey-grade antenna. Finally, we deploy a local network of low-cost receivers in and around the city of Wroclaw, Poland, in order to analyze the dynamics of troposphere delay at a very high spatial resolution.</p><p>As a measure of accuracy, we use the standard deviation of ZTD differences between estimated ZTD and IGS Final product. For the near real-time mode, that accuracy is 5 mm and 6 mm, for single- (L1) and dual-frequency (L1/L5,E5b) solution, respectively. Lower accuracy of the dual-frequency relative solution we justify by the missing antenna phase center correction model for L5 and E5b frequencies. With the real-time Precise Point Positioning technique, we estimate ZTD with the accuracy of 7.5 – 8.6 mm. After antenna replacement, the accuracy is improved almost by a factor of 2 (to 4.1 mm), which is close to the 3.1 mm accuracy which we obtain in real-time using data from the WROC station.</p>

The Impact of Assimilating GPS Precipitable Water Vapor in Convective-Permitting WRF-ARW on North American Monsoon Precipitation Forecasts over Northwest Mexico

2021 ◽  
Author(s):  
Christoforus Bayu Risanto ◽  
Christopher L. Castro ◽  
Avelino F. Arellano ◽  
James M. Moker ◽  
David K. Adams
Keyword(s):  
Water Vapor ◽  
Data Assimilation ◽  
North American ◽  
Precipitable Water ◽  
Precipitable Water Vapor ◽  
North American Monsoon ◽  
Convective Systems ◽  
Northwest Mexico ◽  
Dewpoint Temperature ◽  
The Impact

AbstractWe assess the impact of GPS precipitable water vapor (GPS-PWV) data assimilation (DA) on short-range North American monsoon (NAM) precipitation forecasts, across 38 days with weak synoptic forcing, during the NAM GPS Hydrometeorological Network field campaign in 2017 over northwest Mexico. Utilizing an ensemble-based data assimilation technique, the GPS-PWV data retrieved from 18 observation sites are assimilated every hour for 12 hours into a 30-member ensemble convective-permitting (2.5 km) Advanced Research version of the Weather Research and Forecasting (WRF-ARW) model. As the assimilation of the GPS-PWV improves the initial condition of WRF by reducing the root mean square error and bias of PWV across 1200-1800 UTC, this also leads to an improvement in capturing nocturnal convection of mesoscale convective systems (MCSs; after 0300 UTC) and to an increase by 0.1 mm h-1 in subsequent precipitation during the 0300-0600 UTC period relative to no assimilation of the GPS-PWV (NODA) over the area with relatively more observation sites. This response is consistent with observed precipitation from the Integrated Multi-satellitE Retrievals for Global Precipitation Measurement Final Precipitation product. Moreover, compared to the NODA, we find that the GPS-PWV DA decreases cloud top temperature, increases most unstable convective available energy and surface dewpoint temperature, and thus creates a more favorable condition for convective organization in the region.

Drought spatiotemporal propagation via land feedbacks

2021 ◽  
Author(s):  
Diego G. Miralles ◽  
Dominik L. Schumacher ◽  
Jessica Keune ◽  
Paul A. Dirmeyer
Keyword(s):  
Soil Moisture ◽  
Water Vapor ◽  
Mitigation Strategies ◽  
Soil Drought ◽  
The Usa ◽  
Forecast Models ◽  
Atmospheric Feedbacks ◽  
Dry Out ◽  
Water And Food Security ◽  
The Impact

<p>The predicted increase in drought occurrence and intensity will pose serious threats to global future water and food security. This was hinted by several historically unprecedented droughts over the last two decades, taking place in Europe, Australia, Amazonia or the USA. It has been hypothesised that the strength of these events responded to self-reinforcement processes related to land–atmospheric feedbacks: as rainfall deficits dry out soil and vegetation, the evaporation of land water is reduced, then the local air becomes too dry to yield rainfall, which further enhances drought conditions. Despite the 'local' nature of these feedbacks, their consequences can be remote, as downwind regions may rely on evaporated water transported by winds from drought-affected locations. Following this rationale, droughts may not only self-reinforce locally, due to land atmospheric feedbacks, but <em>self-propagate</em> in the downwind direction, always conditioned on atmospheric circulation. This propagation is not only meteorological but relies on soil moisture drought, and may lead to a downwind cascading of impacts on water resources. However, a global capacity to observe these processes is lacking, and thus our knowledge of how droughts start and evolve, and how this may change as climate changes, remains limited. Furthermore, climate and forecast models are still immature when it comes to representing the influences of land on rainfall.</p><p>Here, the largest global drought events are studied to unravel the role of land–atmosphere feedbacks during the spatiotemporal propagation of these events. We based our study on satellite and reanalysis records of soil moisture, evaporation, air humidity, winds and precipitation, in combination with a Lagrangian framework that can map water vapor trajectories and explore multi-dimensional feedbacks. We estimate the reduction in precipitation in the direction of drought propagation that is caused by the upwind soil moisture drought, and isolate this effect from the influence of potential evaporation and circulation changes. By doing so, the downwind lack of precipitation caused by upwind soil drought via water vapor deficits, and hence the impact of drought self-propagation, is determined. We show that droughts occurring in dryland regions are particularly prone to self-propagate, as evaporation there tends to respond strongly to enhanced soil stress and precipitation is frequently convective. This kind of knowledge may be used to improve climate and forecast models and can be exploited to develop geo-engineering mitigation strategies to help prevent drought events from aggravating during their early stages.</p>

scholarly journals Effect of tropical cyclones on the Stratosphere-Troposphere Exchange observed using satellite observations over north Indian Ocean

2016 ◽  
Author(s):  
M. Venkat Ratnam ◽  
S. Ravindra Babu ◽  
S. S. Das ◽  
Ghouse Basha ◽  
B. V. Krishnamurthy ◽  
...  
Keyword(s):  
Water Vapor ◽  
Indian Ocean ◽  
Tropical Cyclones ◽  
Lower Stratosphere ◽  
North Indian Ocean ◽  
Satellite Observations ◽  
Upper Troposphere ◽  
North West ◽  
The North ◽  
The Impact

Abstract. Tropical cyclones play an important role in modifying the tropopause structure and dynamics as well as stratosphere-troposphere exchange (STE) process in the Upper Troposphere and Lower Stratosphere (UTLS) region. In the present study, the impact of cyclones that occurred over the North Indian Ocean during 2007–2013 on the STE process is quantified using satellite observations. Tropopause characteristics during cyclones are obtained from the Global Positioning System (GPS) Radio Occultation (RO) measurements and ozone and water vapor concentrations in UTLS region are obtained from Aura-Microwave Limb Sounder (MLS) satellite observations. The effect of cyclones on the tropopause parameters is observed to be more prominent within 500 km from the centre of cyclone. In our earlier study we have observed decrease (increase) in the tropopause altitude (temperature) up to 0.6 km (3 K) and the convective outflow level increased up to 2 km. This change leads to a total increase in the tropical tropopause layer (TTL) thickness of 3 km within the 500 km from the centre of cyclone. Interestingly, an enhancement in the ozone mixing ratio in the upper troposphere is clearly noticed within 500 km from cyclone centre whereas the enhancement in the water vapor in the lower stratosphere is more significant on south-east side extending from 500–1000 km away from the cyclone centre. We estimated the cross-tropopause mass flux for different intensities of cyclones and found that the mean flux from stratosphere to troposphere for cyclonic stroms is 0.05 ± 0.29 × 10−3 kg m−2 and for very severe cyclonic stroms it is 0.5 ± 1.07 × 10−3 kg m−2. More downward flux is noticed in the north-west and south-west side of the cyclone centre. These results indicate that the cyclones have significant impact in effecting the tropopause structure, ozone and water vapour budget and consequentially the STE in the UTLS region.

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