Slip behavior of high-density polyethylene at small shear stresses in the presence of esterified polyethylene glycol

2021 ◽  
Vol 33 (6) ◽  
pp. 063101
Author(s):  
Samaneh Dehghani ◽  
Mahdi Salami Hosseini ◽  
Ehsan Behzadfar
Keyword(s):  
Polyethylene Glycol ◽  
High Density Polyethylene ◽  
High Density ◽  
Shear Stresses ◽  
Small Shear

scholarly journals Thermal and mechanical properties of ultrahigh molecular weight polyethylene/high-density polyethylene/polyethylene glycol blends

2013 ◽  
Vol 33 (7) ◽  
pp. 599-614 ◽  
Author(s):  
Mazatusziha Ahmad ◽  
Mat Uzir Wahit ◽  
Mohammed Rafiq Abdul Kadir ◽  
Khairul Zaman Mohd Dahlan ◽  
Mohammad Jawaid
Keyword(s):  
Mechanical Properties ◽  
Molecular Weight ◽  
Polyethylene Glycol ◽  
Impact Strength ◽  
High Density Polyethylene ◽  
Ultrahigh Molecular Weight Polyethylene ◽  
High Density ◽  
Mechanical And Thermal Properties ◽  
Degradation Temperature ◽  
Ultrahigh Molecular Weight

Abstract Blends of ultrahigh molecular weight polyethylene (UHMWPE) with high-density polyethylene (HDPE) provide adequate mechanical properties for biomedical application. In this study, the mechanical and thermal properties of UHMWPE/HDPE blends with the addition of polyethylene glycol (PEG) prepared via single-screw extruder nanomixer were investigated. The UHMWPE/HDPE blends exhibit a gradual increase in strength, modulus, and impact strength over pure polymers, suggesting synergism in the polymer blends. The elastic and flexural modulus was increased at the expense of tensile, flexural, and impact strength for the blends containing PEG. The degradation temperature of UHMWPE was improved with the incorporation of HDPE due to good thermal stability of HDPE. HDPE improved the dispersibility of PEG in matrix, consequently reduced the surface area available for the kinetic effects, and reduced the degradation temperature. The morphology analysis confirmed the miscibility between UHMWPE and HDPE and the changes in polymer structure with the presence of PEG modify the thermal behavior of the blends. The mechanical properties of the blends that are underlying values for the design of implant material show the potential used as biomedical devices.

Composition and Surface Topography Effects on Apatite-Forming Ability of Ceramic-Polymer Composites

2003 ◽  
Vol 774 ◽  
Author(s):  
Susan M. Rea ◽  
Serena M. Best ◽  
William Bonfield
Keyword(s):  
Surface Topography ◽  
High Density Polyethylene ◽  
High Density ◽  
Apatite Layer ◽  
Biologically Active ◽  
Human Blood Plasma ◽  
Apatite Formation ◽  
Polyethylene Matrix ◽  
Composite Surface ◽  
X Ray

AbstractHAPEXTM (40 vol% hydroxyapatite in a high-density polyethylene matrix) and AWPEX (40 vol% apatite-wollastonite glass ceramic in a high density polyethylene matrix) are composites designed to provide bioactivity and to match the mechanical properties of human cortical bone. HAPEXTM has had clinical success in middle ear and orbital implants, and there is great potential for further orthopaedic applications of these materials. However, more detailed in vitro investigations must be performed to better understand the biological interactions of the composites and so the bioactivity of each material was assessed in this study. Specifically, the effects of controlled surface topography and ceramic filler composition on apatite layer formation in acellular simulated body fluid (SBF) with ion concentration similar to those of human blood plasma were examined. Samples were prepared as 1 cm × 1 cm × 1 mm tiles with polished, roughened, or parallel-grooved surface finishes, and were incubated in 20 ml of SBF at 36.5 °C for 1, 3, 7, or 14 days. The formation of a biologically active apatite layer on the composite surface after immersion was demonstrated by thin-film x-ray diffraction (TF-XRD), environmental scanning electron microscopy (ESEM) imaging and energy dispersive x-ray (EDX) analysis. Variations in sample weight and solution pH over the period of incubation were also recorded. Significant differences were found between the two materials tested, with greater bioactivity in AWPEX than HAPEXTM overall. Results also indicate that within each material the surface topography is highly important, with rougher samples correlated to earlier apatite formation.

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