scholarly journals Parametric broadening of the molecular vibronic band due to zero-point oscillations and thermal fluctuations of interatomic bonds

AIP Advances ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 035115
Author(s):  
Peter Lebedev-Stepanov
Author(s):  
Arvind Narayanaswamy

Near–field force and energy exchange between two objects due to electrodynamic fluctuations give rise to dispersion forces such as Casimir and van der Waals forces, and thermal radiative transfer exceeding Plancks theory of blackbody radiation. The two phenomena dispersion forces and near–field enhancement of thermal radiation have common origins in the electromagnetic fluctuations. However, dispersion forces have contributions from quantum (zero–point) as well as thermal fluctuations whereas nearfield radiative transfer has contributions from thermal fluctuations alone. The forces are manifested through the Maxwell stress tensor of the electromagnetic field and radiative transfer through the Poynling vector. Both phenomena are elegantly described in terms of the Dyadic Greens function of the vector Helmholtz equation that governs the electromagnetic fields. In this talk, I will focus on the application of the Dyadic Greens function technique to near–field radiative transfer and dispersion forces. Despite the similarities, radiative transfer and forces have important differences that will be stressed on. I will end the talk with some open questions about the Dyadic Greens function formalism and its application to near–field radiative transfer.


2017 ◽  
Vol 16 (04) ◽  
pp. 1771002 ◽  
Author(s):  
L. Reggiani ◽  
E. Alfinito

The role played by zero-point contribution in black-body radiation spectrum is investigated in connection with the presence of Casimir force. We assert that once mechanical stability for the physical system is established, there is no further role for zero-point contribution to the spectrum in full agreement with experimental evidence. As a direct consequence, Johnson–Nyquist noise in dissipative conductors, should be interpreted just in terms of thermal fluctuations only, thus neglecting quantum fluctuations predicted by [H. Callen and T. Welton, Irreversibility and generalized noise, Phys. Rev. 83 (1951) 34]. Casimir force between opposite metallic plates can be independently measured by its equilibration through application of a mechanical force and measuring it at a mechanical equilibrium.


1993 ◽  
Vol 07 (01n03) ◽  
pp. 585-588 ◽  
Author(s):  
ALEXANDER SOLONTSOV

The spin fluctuation theory of weak itinerant magnets is critically reviewed and is shown to be well established in the weak spin anharmonicity limit. A new self—consistent approach is formulated in terms of the Landau theory of phase transitions to account for zero—point and thermal fluctuations in anharmonic itinerant magnets. The role of spin fluctuations and Fermi excitations in MnSi, Ni3Al and ZrZn2 is discussed using the inelastic neutron scattering experiments.


1978 ◽  
Vol 48 ◽  
pp. 31-35
Author(s):  
R. B. Hanson

Several outstanding problems affecting the existing parallaxes should be resolved to form a coherent system for the new General Catalogue proposed by van Altena, as well as to improve luminosity calibrations and other parallax applications. Lutz has reviewed several of these problems, such as: (A) systematic differences between observatories, (B) external error estimates, (C) the absolute zero point, and (D) systematic observational effects (in right ascension, declination, apparent magnitude, etc.). Here we explore the use of cluster and spectroscopic parallaxes, and the distributions of observed parallaxes, to bring new evidence to bear on these classic problems. Several preliminary results have been obtained.


2019 ◽  
Author(s):  
Riccardo Spezia ◽  
Hichem Dammak

<div> <div> <div> <p>In the present work we have investigated the possibility of using the Quantum Thermal Bath (QTB) method in molecular simulations of unimolecular dissociation processes. Notably, QTB is aimed in introducing quantum nuclear effects with a com- putational time which is basically the same as in newtonian simulations. At this end we have considered the model fragmentation of CH4 for which an analytical function is present in the literature. Moreover, based on the same model a microcanonical algorithm which monitor zero-point energy of products, and eventually modifies tra- jectories, was recently proposed. We have thus compared classical and quantum rate constant with these different models. QTB seems to correctly reproduce some quantum features, in particular the difference between classical and quantum activation energies, making it a promising method to study unimolecular fragmentation of much complex systems with molecular simulations. The role of QTB thermostat on rotational degrees of freedom is also analyzed and discussed. </p> </div> </div> </div>


2008 ◽  
Vol 44 (3) ◽  
pp. 223-236 ◽  
Author(s):  
K. Ērglis ◽  
L. Alberte ◽  
A. Cēbers

Author(s):  
Serge Reynaud ◽  
Astrid Lambrecht

The Casimir force is an effect of quantum vacuum field fluctuations, with applications in many domains of physics. The ideal expression obtained by Casimir, valid for perfect plane mirrors at zero temperature, has to be modified to take into account the effects of the optical properties of mirrors, thermal fluctuations, and geometry. After a general introduction to the Casimir force and a description of the current state of the art for Casimir force measurements and their comparison with theory, this chapter presents pedagogical treatments of the main features of the theory of Casimir forces for one-dimensional model systems and for mirrors in three-dimensional space.


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