Eyring equation and fluctuation–dissipation far away from equilibrium

2020 ◽  
Vol 153 (24) ◽  
pp. 244116
Author(s):  
I. Santamaría-Holek ◽  
A. Pérez-Madrid
Keyword(s):  
Fluctuation Dissipation ◽  
Eyring Equation

scholarly journals Theory of the deformation of aligned polyethylene

2015 ◽  
Vol 471 (2180) ◽  
pp. 20150171 ◽  
Author(s):  
A. Hammad ◽  
T. D. Swinburne ◽  
H. Hasan ◽  
S. Del Rosso ◽  
L. Iannucci ◽  
...  
Keyword(s):  
Load Transfer ◽  
Tensile Load ◽  
Equation Of Motion ◽  
Dislocation Dynamics ◽  
Viscoelastic Deformation ◽  
Transfer Length ◽  
Soliton Dynamics ◽  
Fluctuation Dissipation ◽  
Pull Out ◽  
Definition Of

Solitons are proposed as the agents of plastic and viscoelastic deformation in aligned polyethylene. Interactions between straight, parallel molecules are mapped rigorously onto the Frenkel–Kontorova model. It is shown that these molecular interactions distribute an applied load between molecules, with a characteristic transfer length equal to the soliton width. Load transfer leads to the introduction of tensile and compressive solitons at the chain ends to mark the onset of plasticity at a well-defined yield stress, which is much less than the theoretical pull-out stress. Interaction energies between solitons and an equation of motion for solitons are derived. The equation of motion is based on Langevin dynamics and the fluctuation–dissipation theorem and it leads to the rigorous definition of an effective mass for solitons. It forms the basis of a soliton dynamics in direct analogy to dislocation dynamics. Close parallels are drawn between solitons in aligned polymers and dislocations in crystals, including the configurational force on a soliton. The origins of the strain rate and temperature dependencies of the viscoelastic behaviour are discussed in terms of the formation energy of solitons. A failure mechanism is proposed involving soliton condensation under a tensile load.

scholarly journals The Response to Stratospheric Forcing and Its Dependence on the State of the Troposphere

2009 ◽  
Vol 66 (7) ◽  
pp. 2107-2115 ◽  
Author(s):  
Cegeon J. Chan ◽  
R. Alan Plumb
Keyword(s):  
Time Scale ◽  
Equilibrium Temperature ◽  
Intrinsic Variability ◽  
Winter Solstice ◽  
Fluctuation Dissipation ◽  
Fluctuation Dissipation Theorem ◽  
Order Of Magnitude ◽  
Leading Mode ◽  
Set Up ◽  
Hemisphere Winter

Abstract In simple GCMs, the time scale associated with the persistence of one particular phase of the model’s leading mode of variability can often be unrealistically large. In a particularly extreme example, the time scale in the Polvani–Kushner model is about an order of magnitude larger than the observed atmosphere. From the fluctuation–dissipation theorem, one implication of these simple models is that responses are exaggerated, since such setups are overly sensitive to any external forcing. Although the model’s equilibrium temperature is set up to represent perpetual Southern Hemisphere winter solstice, it is found that the tropospheric eddy-driven jet has a preference for two distinct regions: the subtropics and midlatitudes. Because of this bimodality, the jet persists in one region for thousands of days before “switching” to another. As a result, the time scale associated with the intrinsic variability is unrealistic. In this paper, the authors systematically vary the model’s tropospheric equilibrium temperature profile, one configuration being identical to that of Polvani and Kushner. Modest changes to the tropospheric state to either side of the parameter space removed the bimodality in the zonal-mean zonal jet’s spatial distribution and significantly reduced the time scale associated with the model’s internal mode. Consequently, the tropospheric response to the same stratospheric forcing is significantly weaker than in the Polvani and Kushner case.

Standard fluctuation-dissipation process from a deterministic mapping

1993 ◽  
Vol 47 (3) ◽  
pp. 1510-1519 ◽  
Author(s):  
Marco Bianucci ◽  
Riccardo Mannella ◽  
Ximing Fan ◽  
Paolo Grigolini ◽  
Bruce J. West
Keyword(s):  
Dissipation Process ◽  
Fluctuation Dissipation
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