Production of composite coatings based on zirconium dioxide

2020 ◽  
Author(s):  
I. F. Zakirov ◽  
Yu. V. Ivanova ◽  
A. V. Shak
2021 ◽  
Vol 2124 (1) ◽  
pp. 012016
Author(s):  
I Goncharov ◽  
M Kovaleva ◽  
M Yapryntsev ◽  
V Sirota

Abstract In this article, new composite coatings ZrB2-35MoSi2-15Al were deposited on the surface of a carbon-carbon composite using a multi-chamber detonation accelerator. The evolution of the phase composition of ZrB2-35MoSi2-15Al coatings was analyzed with differential scanning calorimeter (DSC) and X-ray diffractometry (in situ HT-XRD) at temperatures from room temperature (∼ 25°C) to 1400°C (normal atmosphere and pressure). The coating before annealing according to X-ray diffractometry data is tetragonal (t-ZrO2) and monocline (m-ZrO2) zirconium dioxide, monocline silicon oxide (m-SiO2), hexagonal zirconium diboride (h-ZrB2), tetragonal molybdenum disilicide (t-MoSi2), cubic aluminum (c-Al) and cubic yttrium oxide (c-Y2O3). It was found that the coating crystallizes in m-ZrO2 at 460ºC, and then mullite with rhombic crystal lattice appears at 960ºC. When the temperature reaches 1050ºC the m-ZrO2, ZrSiO4, t-ZrO2, m-SiO2 and mullite phases formed in the coating. At 1400 º C, cubic zirconium dioxide appears in the coating. Experimental results can become the basis for the application of ceramic coating ZrB2-35MoSi2-15Al, which can improve the properties of carbon-carbon composites in an oxygen-containing environment at elevated temperatures.


2018 ◽  
Vol 17 (5) ◽  
pp. 378-389 ◽  
Author(s):  
V. A. Okovity ◽  
F. I. Panteleenko ◽  
V. V. Okovity ◽  
V. M. Astashinsky ◽  
V. V. Uglov ◽  
...  

The paper presents results of studying structure and properties of multilayer composite coatings optimized for their composition based on zirconium dioxide materials used for deposition of plasma coatings on the models of elements for anti-meteor shielding screens. The influence of plasma jet parameters (current, distance of sputtering, consumption of plasma-forming nitrogen gas) and fractional composition of an initial powder on characteristics of two-layer composite coatings based on nickel-chromium-aluminum-yttrium and zirconium dioxide on the elements of protective screens has been analyzed in the paper. Optimization has been carried out on the basis of obtaining maximum coefficient of powder utilization. The investigations have made it possible to ascertain specific features of elemental and phase composition, surface morphology, microstructure multilayer composite coatings on the basis of a solid layer of metal oxides and a viscous transition sub-layer subjected to compression plasma flows. The investigations have been executed with the help of scanning electron microscopy, energy dispersive x-ray spectral microanalysis, and x-ray diffraction analysis. It has been shown on the basis of the obtained results that the effect of compression plasma flows on multilayer composite coatings leads to a modification of a near-surface layer with a thickness up to 15 μm that presupposes its melting and subsequent high-speed crystallization which together provide an increase in its density, decrease in porosity while maintaining the initial phase state. Liquid-phase processes in the molten phase of the near-surface layer permit to modify morphological properties of the surface which are associated with its smoothing and lowering of roughness.


Author(s):  
R.A. Ploc

Samples of low-nickel Zircaloy-2 (material MLI-788-see(1)), when anodically polarized in neutral 5 wt% NaCl solutions, were found to be susceptible to pitting and stress corrosion cracking. The SEM revealed that pitting of stressed samples was occurring below a 2000Å thick surface film which behaved differently from normal zirconium dioxide in that it did not display interference colours. Since the initial film thickness was approximately 65Å, attempts were made to examine the product film by transmission electron microscopy to deduce composition and how the corrosion environment could penetrate the continuous layer.


2014 ◽  
Vol 29 (10) ◽  
pp. 1093 ◽  
Author(s):  
ZHOU Wei ◽  
XIAO Peng ◽  
LI Yang ◽  
LUO Heng ◽  
HONG Wen

2008 ◽  
Author(s):  
Ruiquan Kang ◽  
Mingxing Ma ◽  
Wenjin Liu ◽  
Minlin Zhong ◽  
Yide Kan ◽  
...  

2016 ◽  
Vol 58 (10) ◽  
pp. 864-869
Author(s):  
Orkut Sancakoğlu ◽  
Erdal Çelik
Keyword(s):  

2016 ◽  
Vol 53 (3) ◽  
pp. 144-160
Author(s):  
D. Dietrich ◽  
A. Eilert ◽  
D. Nickel ◽  
T. Lampke

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